团簇尺寸对奇数和偶数磷团簇离子信号强度差异的影响

doi:10.3866/PKU.WHXB201212121

Abstract

Abstract:

Intensity difference between odd- and even-numbered cluster ions is one of the characteristics of phosphorus clusters. Generally, for the clusters with cluster ion size n>25, intensities of odd-numbered cluster ions are much higher than those of their even-numbered neighbors. In order to better understand the size effect on the phenomenon, large phosphorus clusters (n~500) were generated by laser ablation on red phosphorus in vacuum. Their intensity distributions were also analyzed. Results show that the intensity difference between odd- and even-numbered cluster ions decreases with increasing cluster size for both cations and anions. Based on the observed trends for cations and anions, it can be estimated that the observed intensity alternation of even/odd numbered clusters may vanish for cluster ions with n>1000. These results exactly reflect the function of cluster as a bridge linking atoms in the gas phase and their bulk counterpart in the bulk phase.

Key words: Phosphorus cluster, Laser ablation, Size effect, Mass spectrometry

KONG Xiang-Lei. Size Effect on the Signal Intensity Difference between Odd- and Even-Numbered Phosphorus Cluster Ions[J]. Acta Phys. -Chim. Sin. 2013, 29(03), 486-490. doi: 10.3866/PKU.WHXB201212121

References

(1) (a) Castleman, A.W., Jr.; Jena, P. Proc. Natl. Acad. Sci. U. S. A.2006, 103, 10552. doi: 10.1073/pnas.0601783103
(b) Castleman, A.W., Jr.; Jena, P. Proc. Natl. Acad. Sci. U. S. A.2006, 103, 10554.
(c) Jena, P.; Castleman, A.W., Jr. Proc. Natl. Acad. Sci. U. S. A.2006, 103, 10560.
(d) Cheng, P. Y.; Baskin, J. S.; Zewail, A. H. Proc. Natl. Acad.Sci. U. S. A. 2006, 103, 10570.
(2) (a) Kroto, H.W.; Heath, J. R.; O'Brien, S. C.; Curl, R. F.;Smalley, R. E. Nature 1985, 318, 162.
(b) Li, J.; Li, X.; Zhai, H. J.;Wang, L. S. Science 2003, 299,864.
(3) (a) Kong, X.; Li, S.; Zhang, S.; Huang, Y.; Chen. Y. J. Am. Soc.Mass Spectrom. 2011, 22, 2033. doi: 10.1007/s13361-011-0221-x
(b) Kong, X.; Huang, Y.; Chen, Y. J. Mass Spectrom. 2012, 47,523.
(4) (a) Ruck, M.; Hoppe, D.;Wahl, B.; Simon, P.;Wang, Y.; Seifert,G. Angew. Chem. Int. Edit. 2005, 44, 7616.
(b) Pfitzner, A. Angew. Chem. Int. Edit. 2006, 45, 699.
(c)Winchester, R. A. L.; Whitby, M.; Shaffer, M. S. P. Angew.Chem. 2009, 121, 3670.
(d) Russell, C. A. Angew. Chem. Int. Edit. 2009, 48, 4895.
(5) Martin, T. P. Z. Phys. D 1986, 3, 211. doi: 10.1007/BF01384809
(6) (a) Huang, R. B.; Zhang, P.; Li,W. Y.; Su, J. R.; Zheng, L. S.Acta Phys. -Chim. Sin. 1991, 7, 646. [黄荣彬, 张鹏, 李文莹, 苏剑瑞, 郑兰荪. 物理化学学报, 1991, 7, 646.] doi: 10.3866/PKU.WHXB19910602
(b) Huang, R.; Li, H.; Lin, Z.; Yang, S. J. Phys. Chem. 1995,99, 1418.
(c) Liu, Z.; Huang, R.; Zheng, L. Z. Phys. D 1996, 68, 171.
(7) (a) Bulgakov, A. V.; Bobrenok, O. F.; Kosyakov, V. I. Chem.Phys. Lett. 2000, 320, 19. doi: 10.1016/S0009-2614(00)00234-7
(b) Bulgakov, A. V.; Bobrenok, O. F.; Ozerov, I.; Marine,W.;Giorgio, S.; Lassesson, A.; Capbel, E. E. B. Appl. Phys. A 2004,79, 1369.
(8) Sladkova, K.; Houska, J.; Havel, J. Rapid Commun. MassSpectrom. 2009, 23, 3114. doi: 10.1002/rcm.v23:19
(9) Hu, C. H.; Shen, M.; Schaefer, H. F., III. Theor. Chim. Acta1994, 88, 129.
(10) (a) Chen, M. D.; Huang, R. B.; Zheng, L. S.; Zhang, Q. E.; Au,C. T. Chem. Phys. Lett. 2000, 325, 22. doi: 10.1016/S0009-2614(00)00671-0
(b) Chen, M. D.; Chen, Q. B.; Liu, J.; Zheng, L. S.; Zhang, Q.E.; Au, C. T. J. Phys. Chem. A 2007, 111, 216.
(11) Karttunen, A. J.; Linnolahti, M.; Pakkanen, T. A.ChemPhysChem 2008, 9, 2550. doi: 10.1002/cphc.v9:17
(12) Xue, T.; Luo, J.; Li, F.; Zhao, J. Chem. Phys. Lett. 2010, 485,26. doi: 10.1016/j.cplett.2009.12.019
(13) Keki, S.; Szilagyi, L. S.; Totok, J.; Deak, G.; Zsuga, M. J. Phys.Chem. B 2003, 107, 4818. doi: 10.1021/jp0274334
(14) Li, J.; Liu, J.; Chen, Y. J. Mass Spectrom. 2012, 47, 620. doi: 10.1002/jms.2994
(15) Haberland, H.; Mail, M.; Mossier, M.; Qiang, Y.; Reiners, T.;Thurner, Y. J. Vac. Sci. Technol. A 1994, 12, 2925. doi: 10.1116/1.578967

[1]	Yanpeng Fu, Changbao Zhu. Design Strategies for Sodium Electrode Materials: Solid-State Ionics Perspective [J]. Acta Phys. -Chim. Sin., 2023, 39(3): 2209002-0.
[2]	Houfu Song, Feiyu Kang. Recent Progress on Thermal Conduction of Graphene [J]. Acta Phys. -Chim. Sin., 2022, 38(1): 2101013-.
[3]	Yi Ren,Qing-Yu Liu,Yan-Xia Zhao,Qi Yang,Sheng-Gui He. C―C Coupling of Methane Mediated by Atomic Gold Cations under Multiple-Collision Conditions [J]. Acta Physico-Chimica Sinica, 2020, 36(1): 1904026-.
[4]	Qiang CHEN,Li-Xue JIANG,Hai-Fang LI,Jiao-Jiao CHEN,Yan-Xia ZHAO,Sheng-Gui HE. Thermal Activation of Methane by Diatomic Vanadium Boride Cations [J]. Acta Physico-Chimica Sinica, 2019, 35(9): 1014-1020.
[5]	Yue ZHAO,Jiatong CUI,Jichuang HU,Jiabi MA. Reactivities of VO_1–4⁺ Toward n-C_mH_2m+2 (m = 3, 5, 7) as Functions of Oxygen Content and Carbon Chain Length [J]. Acta Phys. -Chim. Sin., 2019, 35(5): 531-538.
[6]	Ning-Liang LIU,Huan SHEN. Multiphoton Dissociation and Ionization Dynamics of Allyl Chloride Using Femtosecond Laser Pulses [J]. Acta Phys. -Chim. Sin., 2017, 33(3): 500-505.
[7]	Huan-Feng TANG,Zai-Yin HUANG,Ming XIAO. Effects of Particle Size and Temperature on Surface Thermodynamic Functions of Cubic Nano-Cu₂O [J]. Acta Phys. -Chim. Sin., 2016, 32(11): 2678-2684.
[8]	FU Zhong-Hua, LONG Kai-Ming, LIU Xue-Mei, HAN Jun, TANG Lei. Analysis of Trace Thorium in Uranium Sample Using Isotope Dilution Mass Spectrometry [J]. Acta Phys. -Chim. Sin., 2015, 31(Suppl): 14-18.
[9]	LI Na, CHEN Xi, XUE Qi-Kun. Contribution of Chemical Bonding to the Force in Atomic Force Microscopy [J]. Acta Phys. -Chim. Sin., 2014, 30(2): 205-209.
[10]	ZHU Yun-Cheng, WANG Er-Qiong, MA Guo-Lin, KANG Yan-Biao, ZHAO Lin-Hong, LIU Yang-Zhong. Interaction of C-Terminal Metal-Binding Domain of Copper Transport Protein with Ag⁺ and Hg²⁺ [J]. Acta Phys. -Chim. Sin., 2014, 30(1): 1-7.
[11]	SUN Wei, ZHANG Jin-Jiang, ZHAO Jian-Wei. Molecular Dynamics Simulation of a Nanosized Device [J]. Acta Phys. -Chim. Sin., 2013, 29(09): 1931-1936.
[12]	CHEN Chen, CHU Yan-Qiu, DAI Xin-Hua, FANG Xiang, DING Chuan-Fan. Investigation of the Non-Covalent Interactions between Fragment Peptides of Bradykinin by Mass Spectrometry [J]. Acta Phys. -Chim. Sin., 2013, 29(06): 1336-1343.
[13]	LING Xing, DING Chuan-Fan. Online Electrochemistry/Electrospray Mass Spectrometry with a Coaxial Probe for Investigation of Electrochemical Derivatization of Anthracene with Dodecylamine [J]. Acta Phys. -Chim. Sin., 2012, 28(11): 2616-2624.
[14]	WANG Qing, CHU Yan-Qiu, ZHANG Kai, DAI Xin-Hua, FANG Xiang, DING Chuan-Fan. Effect of Alkali Metal Ions on the Dissociation of Glycine Pentapeptide in the Gas Phase [J]. Acta Phys. -Chim. Sin., 2012, 28(04): 971-977.
[15]	PU Peng, XU Can, XIE Shu-Yu. Influence of the Size Effect on the Chemical Shielding Tensors of SiO₂ Nanotubes [J]. Acta Phys. -Chim. Sin., 2011, 27(09): 2227-2232.

Size Effect on the Signal Intensity Difference between Odd- and Even-Numbered Phosphorus Cluster Ions

PDF

Like

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Metrics

Recommended 0