基于三维多孔石墨烯/含钛共轭聚合物复合多孔薄膜的柔性全固态超级电容器

doi:10.3866/PKU.WHXB201705089

Abstract

Abstract:

A new three-dimensional (3D) porous graphene thin film named rGO-Fe was prepared through chemical reduction from Fe³⁺ ions cross-linking graphene oxide hydrogel, and a 3D porous graphene/titanium-containing conjugated polymer composite film named rGO-Fe/P(EDOT:P3C)-1-Ti was further prepared via electrochemical polymerization on the rGO-Fe substrate. As a new composite film, rGO-Fe/P(EDOT:P3C)-1-Ti film with average thickness of 3 μm can withstand the tensile load 0.97 N which is better than that of rGO-Fe (0.76 N). We compared the electrochemical properties of these film materials, and prepared self-supporting electrodes and a flexible all-solid-state supercapacitor based on rGO-Fe/P(EDOT:P3C)-1-Ti. Galvanostatic charge-discharge test results showed that the as prepared flexible supercapacitor delivered a gravimetric specific capacitance of 71.13 F·g^-1 (18.14 F·g^-1) and an area specific capacitance of 101 mF·cm^-2 (25.8 mF·cm^-²) at 0.1 A·g^-1 (0.6 A·g^-1).

Key words: Graphene, Electrochemical polymerization, Cross-linking, Porous film, Titanium-containing conjugated polymer, Flexible all-solid-state supercapacitor

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Wei-Shi DU,Yao-Kang LÜ,Zhi-Wei CAI,Cheng ZHANG. Flexible All-Solid-State Supercapacitor Based on Three-Dimensional Porous Graphene/Titanium-Containing Copolymer Composite Film[J]. Acta Phys. -Chim. Sin. 2017, 33(9), 1828-1837. doi: 10.3866/PKU.WHXB201705089

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Flexible All-Solid-State Supercapacitor Based on Three-Dimensional Porous Graphene/Titanium-Containing Copolymer Composite Film

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