Acta Phys. -Chim. Sin. ›› 2026, Vol. 42 ›› Issue (8): 100323.doi: 10.1016/j.actphy.2026.100323

• ARTICLE • Previous Articles     Next Articles

Constructing selenium-vacancy-rich SiC@CoSe2−x nanocomposites to boost dipole and interfacial polarization for electromagnetic wave absorption

Zhongning Tian1, Jinyuan Liu1, Meng Zhang1,*(), Qianqian Jia1, Mingbo Liu1, Zhenjiang Li1,*(), Ting Wang2, Wenjie Zhao3, Dongwei Ma4, Xueli Qi5,*()   

  1. 1 College of Materials Science and Engineering, Qingdao University of Science and Technology, Qingdao 266042, Shandong Province, China
    2 College of Chemical Engineering, Qingdao University of Science and Technology, Qingdao 266042, Shandong Province, China
    3 Sino-German College of Technology, Qingdao University of Science and Technology, Qingdao 266061, Shandong Province, China
    4 School of Automotive Materials, Hubei University of Automotive Technology, Shiyan 442002, Hubei Province, China
    5 Shandong Industrial Ceramic Research & Design institute Co., Ltd., Zibo 255000, Shandong Province, China
  • Received:2026-03-21 Revised:2026-05-08 Accepted:2026-05-11 Published:2026-06-11
  • Contact: Email: mengzhang@qust.edu.cn (Meng Zhang)zhenjiangli@qust.edu.cn (Zhenjiang Li)qi-xl@163.com (Xueli Qi)

Abstract:

Material hybridization and defect engineering are two effective strategies for tailoring electromagnetic wave absorption performance. In this work, to address the imbalanced impedance matching and weak absorption capability arising from the silicon carbide (SiC) nanowires, cobalt oxide (Co3O4) nanoparticles were successfully anchored onto the SiC nanowire surfaces via hydrothermal synthesis followed by one-step calcination. Subsequently, the synthesized Co3O4 was transformed into SiC@CoSe2 and SiC@CoSe2−x respectively through secondary hydrothermal strategy and followed reduction treatment, which endows the SiC@CoSe2−x nanocomposite with excellent electromagnetic wave absorption performances. Under the combined effect of conductive loss, polarization loss, and magnetic loss, the optimized nanocomposite exhibits a minimum reflection loss (RLmin) of −50.23 dB at a thickness of 1.9 mm and an effective absorption bandwidth (EAB) of 7.84 GHz at a thickness of 2.03 mm, covering portions of the X-band and the entire Ku-band. The electromagnetic attenuation mechanisms were systematically elucidated, revealing the promising potential of CoSe2-based nanomaterials in electromagnetic wave absorption applications.

Key words: Selenium vacancies, CoSe2, Electromagnetic wave attenuation, Dielectric loss, Dipole polarization