物理化学学报 >> 2007, Vol. 23 >> Issue (04): 459-465.doi: 10.1016/S1872-1508(07)60030-8

研究论文 上一篇    下一篇

结构规整有序的寡聚噻吩修饰9,9'-螺二芴衍生物的光物理性质及其电化学聚合

金卫红; 倪菁; LAI Yee-Hing; 裴坚   

  1. 北京大学化学与分子工程学院, 北京 100871; 新加坡材料研究与工程研究院,新加坡国立大学化学系, 新加坡 117602; 浙江海洋学院海洋科学学院, 浙江舟山 316004
  • 收稿日期:2006-11-13 修回日期:2006-12-11 发布日期:2007-04-05
  • 通讯作者: 裴坚 E-mail:jianpei@pku.edu.cn

Photophysical Properties and Electropolymerization of Regioregular Head-to-Tail Oligothiophenes-Functionalized 9,9'-spirobifluorene Derivatives

JIN Wei-Hong; NI Jing; LAI Yee-Hing; PEI Jian   

  1. College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P. R. China; Institute of Materials Research and Engineering, and Department of Chemistry, National University of Singapore, Singapore 117602, Singapore; College of Marine Science and Technology, Zhejiang Ocean University, Zhoushan 316004, Zhejiang Province, P. R. China
  • Received:2006-11-13 Revised:2006-12-11 Published:2007-04-05
  • Contact: PEI Jian E-mail:jianpei@pku.edu.cn

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摘要： 研究了结构规整有序的寡聚噻吩修饰的9,9'-螺二芴衍生物在溶液中和在固体膜状态下的光物理性质, 发现在四氢呋喃的稀溶液中, 随着有效共轭长度的增加这些化合物的最大吸收峰和发射峰发生了明显的红移. 实验结果表明, 9,9'-螺二芴骨架中的9位螺碳原子明显地阻断了二个共轭片段的共轭效应, 使它们成为了二个独立的共轭链节. 此外, 还进一步研究了这些化合物的电化学聚合性质.

关键词: 寡聚噻吩, 9,9'-螺二芴, 光物理性质, 电化学聚合

Abstract: The photophysical properties of oligothiophenes-functionalized 9,9'-spirobifluorene derivatives in solution and in solid state were investigated in detail. The enhanced red-shift was observed from the absorption and the photoluminescence (PL) spectra of these derivatives in dilute THF solution with the increase of thiophene unit at one branch of 9,9'-spirobifluorene identical with the increased π-electron delocalization and the more effective conjugation length of the whole molecular system. The investigation of the photophysical properties of these compounds further demonstrated that the sp3-hybrid carbon at the spiro-center completely obstructed the correlation between two branches of the 9,9'-spirobifluorene system and made every branch become an independent chromophore. The electrochemical polymerization of 6b as a representative was also investigated.

Key words: Oligothiophene, 9,9-Spirobifluorene, Photophysical property, Electrochemical polymerization