物理化学学报 >> 1992, Vol. 8 >> Issue (04): 555-557.doi: 10.3866/PKU.WHXB19920426

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光电化学方法研究嵌入反应

董庆华; 孔维和; 吴秉亮   

  1. 武汉大学化学系，武汉 430072
  • 收稿日期:1991-03-16 修回日期:1991-10-14 发布日期:1992-08-15
  • 通讯作者:

Photoelectrochemical Studies of Intercalation Reaction

Dong Qing-Hua; Kong Wei-He; Wu Bing-Liang   

  1. Department of Chemistry, Wuhan University, Wuhan 430072
  • Received:1991-03-16 Revised:1991-10-14 Published:1992-08-15
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关键词: 嵌入反应, 光电化学, 氧化铜

Abstract: The electrochemical intercalation reaction of lithium cell was investigated by photoelectrochemical technique. The experimental results show that the lithium ions inserting into the orystal lattice of the cathode, act as a donor impurities and change the semiconductor properties of the cathode matrix. From the change of photovoltage of the cathode during the discharging process of the lithium cell, the intercalation process of lithium ions could be studied in-situ.

Key words: Intercalation reaction, Photoelectrochemistry, Cupric oxide