物理化学学报 >> 2000, Vol. 16 >> Issue (03): 258-262.doi: 10.3866/PKU.WHXB20000313

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自组装膜修饰悬汞电极的制备及电化学特性

蒋殿录, 杨卫华, 童汝亭   

  1. 河北师范大学化学系，石家庄 050016
  • 收稿日期:1999-06-21 修回日期:1999-08-26 发布日期:2000-03-15
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The Preparation and Electrochemical Characterization of Self-assembled Membrane Modified Hangning Mercury Drop Electrod

Jiang Dian-Lu, Yang Wei-Hua, Tong Ru-Ting   

  1. Department of Chemistry,Hebei Normal University,Shijiazhuang 050016
  • Received:1999-06-21 Revised:1999-08-26 Published:2000-03-15
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关键词: 悬汞电极, 单层膜, 双层膜

Abstract:

The electrochemical behavior of self-assembled n-dodecanethiol monolayer and n-dodecanethiol/phosphatidylcholine hybrid bilayer modified HMDE in different concentration of Fe(CN)63-/4- solutions has been studied by using cyclic voltammetry and electrochemical impedance spectroscopy measurements. The equivalent circuit of different system have been put forward. We also calculate the normal electron tunneling rate constant k0 and the apparent thickness d of the membrane.

Key words: Hanging mercury drop electrode(HMDE), Self-assembled monolayer, Self-assembled bilayer