物理化学学报 >> 2000, Vol. 16 >> Issue (10): 952-955.doi: 10.3866/PKU.WHXB20001016

研究简报 上一篇    下一篇

从高放废液中提取铯的新型环境材料

张惠源, 王淑兰, 王榕树, 林灿生, 张先业, 王孝荣   

  1. 天津大学化工学院 天津 300072|中国原子能科学研究院 北京 102413
  • 收稿日期:2000-01-03 修回日期:2000-05-07 发布日期:2000-10-15
  • 通讯作者: 王榕树

New Ecomaterial Zireonyl Molybopyrophosphate for Cesium Removal from HLLW

Zhang Hui-Yuan, Wang Shu-Lan, Wang Rong-Shu, Lin Can-Sheng, Zhang Xian-Ye, Wang Xiao-Rong   

  1. School of Chemical engineering and Technology,Tianjin University,Tianjin 300072|Chinese Institute of Atomic Energy,Beijing 102413
  • Received:2000-01-03 Revised:2000-05-07 Published:2000-10-15
  • Contact: Wang Rong-Shu

关键词: 铯137Cs, 高放废液, 焦磷钼酸锆, 离子交换

Abstract:

Six kinds of pyrophosphate were synthesized. The investigation on ion exchange properties showed that zireonyl molybopyrophosphate exhibited large exchange capacity and high distribution coefficient for cesium in the medium of 3 mol• L- 1 HNO3.Preliminary study of its properties indicated that this material is a bifunctional inorganic ion exchanger with good thermal and chemical stabilities. ZMPP might be suitable for removing cesium directly from strong acidic HLLW.

Key words: Cesium, HLLW, Zireonyl molybopyrophosphate, Ion exchange