同、异双核卟啉-Salen型金属配合物的合成及非线性光学性质

doi:10.3866/PKU.WHXB201407171

物理化学学报 >> 2014, Vol. 30 >> Issue (10): 1801-1809.doi: 10.3866/PKU.WHXB201407171

同、异双核卟啉-Salen型金属配合物的合成及非线性光学性质

刘欢, 臧娜, 赵芳瑶, 刘坤, 李悦, 阮文娟

南开大学化学学院, 天津 300071

收稿日期:2014-04-21 修回日期:2014-07-16 发布日期:2014-09-30
通讯作者: 阮文娟 E-mail:wjruan@nankai.edu.cn
基金资助:
国家自然科学基金（20671053，21307062）和中央高校基本科研业务费（65121003）资助项目

Synthesis and Nonlinear Optical Properties of Porphyrin-Salen Type Homo- and Hetero-Binuclear Metal Complexes

LIU Huan, ZANG Na, ZHAO Fang-Yao, LIU Kun, LI Yue, RUAN Wen-Juan

Department of Chemistry, Nankai University, Tianjin 300071, P. R. China

Received:2014-04-21 Revised:2014-07-16 Published:2014-09-30
Contact: RUAN Wen-Juan E-mail:wjruan@nankai.edu.cn
Supported by:
The project was supported by the National Natural Science Foundation of China (20671053, 21307062) and Fundamental Research Funds for the Central Universities, China (65121003).

摘要/Abstract

摘要：

设计合成了两种新型卟啉-Salen 型配体5-（3-氨基-4-（3，5-二叔丁基水杨醛基）-氨基苯基）-10，15，20-三苯基卟啉（1）和5-（N，N’-二（3，5-二叔丁基水杨醛基）-3，4-二氨基苯基）-10，15，20-三苯基卟啉（2）及其同、异双核金属配合物和单金属核配合物. 采用氢核磁共振（1H NHR）谱、电喷雾质谱（ESI-MS）、傅里叶变换红外（FTIR）光谱和紫外-可见（UV-Vis）光谱等手段对各目标化合物进行了表征. 用Z扫描技术研究了配体及其金属配合物的三阶非线性光学性质. 实验结果表明：配体1和配体2具有相似的光学特征，均具有反饱和吸收的特性和自散焦效应；当不同的金属离子嵌入配体形成单、双核金属配合物后，分子的极性发生改变，他们的光学特性均受到影响.

关键词: 卟啉-Salen 型配体, 同、异双核金属配合物, 谱学性质, 三阶非线性光学性质, Z扫描

Abstract:

Two new porphyrin-Salen type ligands 5-(3-amino-4-(3,5-di-tert-butylsalicylidene)aminophenyl)- 10,15,20-triphenylporphyrin (1) and 5- (N,N'- di(3,5- di- tert- butylsalicylidene)-3,4-diaminophenyl)-10,15,20- triphenylporphyrin (2), their homo- and hetero- binuclear metal complexes and their mononuclear metal complexes were synthesized and characterized by ¹H nuclear magnetic resonance (¹H NMR) spectroscopy, electrospray ionization mass spectrometry (ESI-MS), elemental analysis, Fourier transform infrared (FTIR) spectroscopy, and ultraviolet visible (UV-Vis) spectroscopy. The third-order nonlinear optical properties of these ligands and complexes were investigated by Z scan techniques. Experimental results indicated that ligands 1 and 2 have a close strong reverse-saturable absorption and self-defocusing effect. The polarization induced by the coordinated metal ions affects the nonlinear refractive indexes of these ligands.

Key words: Porphyrin- Salen type ligand, Homo- and hetero- binuclear metal complexes, Spectrum property, Third-order nonlinear optical property, Z scan

刘欢, 臧娜, 赵芳瑶, 刘坤, 李悦, 阮文娟. 同、异双核卟啉-Salen型金属配合物的合成及非线性光学性质[J]. 物理化学学报, 2014, 30(10), 1801-1809. doi: 10.3866/PKU.WHXB201407171

LIU Huan, ZANG Na, ZHAO Fang-Yao, LIU Kun, LI Yue, RUAN Wen-Juan. Synthesis and Nonlinear Optical Properties of Porphyrin-Salen Type Homo- and Hetero-Binuclear Metal Complexes[J]. Acta Phys. -Chim. Sin. 2014, 30(10), 1801-1809. doi: 10.3866/PKU.WHXB201407171

链接本文: https://www.whxb.pku.edu.cn/CN/10.3866/PKU.WHXB201407171

https://www.whxb.pku.edu.cn/CN/Y2014/V30/I10/1801

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同、异双核卟啉-Salen型金属配合物的合成及非线性光学性质

Synthesis and Nonlinear Optical Properties of Porphyrin-Salen Type Homo- and Hetero-Binuclear Metal Complexes

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