以无机硫为原料制备硫化铅量子点及其表征

doi:10.3866/PKU.WHXB20110513

物理化学学报 >> 2011, Vol. 27 >> Issue (05): 1239-1243.doi: 10.3866/PKU.WHXB20110513

以无机硫为原料制备硫化铅量子点及其表征

岳栋^1,2, 张建文¹, 张敬波², 林原²

1. 北京化工大学流体力学与传热研究室, 北京 100029;
2. 中国科学院化学研究所光化学重点实验室, 北京分子科学国家实验室, 北京 100190

收稿日期:2011-01-14 修回日期:2011-03-08 发布日期:2011-04-28
通讯作者: 张建文, 张敬波 E-mail:zhangjw@mail.buct.edu.cn; jbzhang@iccas.ac.cn
基金资助:
国家自然科学基金(20873162)和污染控制与资源化研究国家重点实验室开放课题(PCRRF09006)资助项目

Preparation of PbS Quantum Dots Using Inorganic Sulfide as Precursor and Their Characterization

YUE Dong^1,2, ZHANG Jian-Wen¹, ZHANG Jing-Bo², LIN Yuan²

1. Laboratory of Computational Fluid Dynamics and Heat Transfer, Beijing University of Chemical Technology, Beijing 100029, P. R. China;
2. Beijing National Laboratory for Molecular Sciences, Key Laboratory of Photochemistry, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China

Received:2011-01-14 Revised:2011-03-08 Published:2011-04-28
Contact: ZHANG Jian-Wen, ZHANG Jing-Bo E-mail:zhangjw@mail.buct.edu.cn; jbzhang@iccas.ac.cn
Supported by:
The project was supported by the National Natural Science Foundation of China (20873162) and State Key Laboratory of Pollution Control and Resource Reuse Foundation of China (PCRRF09006).

摘要/Abstract

摘要：

根据高温下快速成核低温下慢速生长的量子点制备原理, 采用胶体化学的方法成功制备了不同粒径的硫化铅半导体量子点. 这种方法的特点是以无味和低毒的硫化钠作为制备硫化铅量子点硫的前驱物, 因此这是一种量子点的绿色化学合成方法. 油酸作为稳定剂控制硫化铅的粒径. 采用X射线衍射和高分辨透射电镜表征了量子点的晶体结构、形貌和粒径, 采用可见-近红外吸收光谱研究了硫化铅量子点的量子尺寸效应. 通过降低油酸的添加量可以促进量子点的生长, 得到较大粒径量子点. 并探讨了量子点的生长机理.

关键词: 量子点, 硫化铅, 硫化钠, 绿色合成, 粒径分布

Abstract:

PbS semiconductor quantum dots with different particle sizes were successfully prepared by the colloidal chemistry method according to the theory of fast nucleation at high temperature and slow growth at low temperature. Sodium sulfide was used as a sulfur precursor because it is odorless and is less noxious, which allows it to be classified as a green precursor. Oleic acid was used as a stabilizing agent to control the particle growth and it thus assisted in the formation of monodisperse PbS quantum dots. The crystalline structures, morphology, and particle size of the quantum dots were characterized by powder X-ray diffraction and high-resolution transmission electron microscopy. The quantum size effect of the PbS nanoparticles was analyzed by visible near-infrared (Vis-NIR) absorption spectroscopy. The mean size of the PbS quantum dots increased with a decrease in the concentration of oleic acid. A possible growth mechanism for the PbS nanoparticles was also discussed.

Key words: Quantum dots, Lead sulfide, Sodium sulfide, Green synthesis, Size distribution

岳栋, 张建文, 张敬波, 林原. 以无机硫为原料制备硫化铅量子点及其表征[J]. 物理化学学报, 2011, 27(05): 1239-1243.

YUE Dong, ZHANG Jian-Wen, ZHANG Jing-Bo, LIN Yuan. Preparation of PbS Quantum Dots Using Inorganic Sulfide as Precursor and Their Characterization[J]. Acta Phys. -Chim. Sin., 2011, 27(05): 1239-1243.

链接本文: https://www.whxb.pku.edu.cn/CN/10.3866/PKU.WHXB20110513

https://www.whxb.pku.edu.cn/CN/Y2011/V27/I05/1239

参考文献

(1) Henglein, A . Chem. Rev. 1989, 89, 1861.
(2) Dutta, A. K.; Ho, T.; Zhang, L.; Stroeve, P. Chem. Mater. 2000, 12, 1042.
(3) Wang, Y.; Suna, A.; Mahler, W.; Kasowski, R. J. Chem. Phys. 1987, 87, 7315.
(4) Hirata, H.; Higashiyama, K. Bull. Chem. Soc. Jpn. 1971, 44, 2420.
(5) Nair, P. K.; Gomezdaza, O.; Nair, M. T. S. Adv. Mater. Opt. Electron. 1992, 1, 139.
(6) Gadenne, P.; Yagil, Y.; Deutscher, G. J. Appl. Phys. 1989, 66, 3019.
(7) Chaudhuri, T. K.; Chatterjes, S. Proc. Int. Conf. Thermoelectr. 1992, 11, 40.
(8) Kane, R. S.; Cohen, R. E.; Silbey, R. J. J. Phys. Chem. 1996, 100, 7928.
(9) Ellingson, R. J.; Beard, M. C.; Johnson, J. C.; Yu, P.; Micic, O. I.; Nozik, A. J.; Shabaev, A.; Efros, A. L. Nano Lett. 2005, 5, 865.
(10) Zeng, Z.; Wang, S.; Yang, S. Chem. Mater. 1999, 11, 3365.
(11) Wang, S.; Yang, S. Langmuir 2000, 16, 389.
(12) Yu, D.; Wang, D.; Zhang, S. Liu, X.; Qian, Y. J. Cryst. Growth 2003, 249, 195.
(13) Trindade, T.; O′Brien, P.; Zhang, X. M.; Motevalli, M. J. Mater. Chem. 1997, 7, 1011.
(14) Wang, D.; Yu, D.; Shao, M. S. Liu, X.; Yu, W.; Qian, Y. J. Cryst. Growth 2003, 257, 384.
(15) Wang, S. F.; Gu, F.; Lu, M. K. Langmuir 2006, 22, 398.
(16) Ding, Y. H.; Liu, X. X.; Guo, R. J. Cryst. Growth 2007, 307, 145.
(17) Ding, Y. H.; Liu, X. X.; Guo, R. Colloid. Surf. A-Physicochem. Eng. Asp. 2007, 296, 8.
(18) Hines, M. A.; Scholes, G. D. Adv. Mater. 2003, 15, 1844.
(19) Rogach, A. L.; Eychmüller, A.; Hickey, S. G.; Kershaw, S. V. Small 2007, 3, 536.
(20) Hyun, B.; Zhong, Y.; Bartnik, A. C.; Sun, L.; Abruna, H. D.; Wise, F. W.; Goodreau, J. D.; Matthews, J. R.; Leslie, T. M.; Borrelli, N. F. ACS Nano 2008, 2, 2206.
(21) Leventis, H. C.; O′Mahony, F.; Akhtar, J.; Afzaal, M.; O′Brien, P.; Haque, S. A. J. Am. Chem. Soc. 2010, 132, 2743.
(22) Lee, H.; Wang, M.; Chen, P.; Gamelin, D. R.; Zakeeruddin, S. M.; Gr?tzel, M.; Nazeeruddin, M. K. Nano Lett. 2009, 9, 4221.
(23) Wang, P.; Wang, L.; Ma, B.; Li, B.; Qiu, Y. J. Phys. Chem. B 2006, 110, 14406.
(24) Yu, W. W.; Peng, X. Angew. Chem. Int. Edit. 2002, 41, 2368.
(25) Zhou, G. J.; Lu, M. K.; Xiu, Z. L.; Wang, S. F.; Zhang, H. P.; Zhou, Y. Y.; Wang, S. M. J. Phys. Chem. B 2006, 110, 6543.
(26) Wilson, A. J. C. Proc. Phys. Soc. London 1962, 80, 286.
(27) Zhao, N.; Osedach, T. P.; Chang, L. Y.; Geyer, S. M.; Wanger, D.; Binda, M. T.; Arango, A. C.; Bawendi, M. G.; Bulovic, V. ACS Nano 2010, 4, 3743.
(28) Pattantyus-Abraham, A. G.; Kramer, I. J.; Barkhouse, A. R.; Wang, X.; Konstantatos, G.; Debnath, R.; Levina, L.; Raabe, I.; Nazeeruddin, M. K.; Gr?tzel, M.; Sargent, E. H. ACS Nano 2010, 4, 3374.
(29) Ju, T.; Graham, R. L.; Zhai, G.; Rodriguez, Y. W.; Breeze, A. J.; Yang, L.; Alers, G. B.; Carter, S. A. Appl. Phys. Lett. 2010, 97, 043106.
(30) Luther, J. M.; Gao, J.; Lloyd, M. T.; Semonin, O. E.; Beard, M. C.; Nozik, A. J. Adv. Mater. 2010, 22, 3704.

[1]	昝忠奇, 李喜宝, 高晓明, 黄军同, 罗一丹, 韩露. 0D/2D碳氮量子点(CNQDs)/BiOBr复合的S型异质结高效光催化降解和产H₂O₂[J]. 物理化学学报, 2023, 39(6): 2209016 -0 .
[2]	张明旭, 周琪森, 梅馨怡, 陈婧萱, 邱俊明, 李修志, 李霜, 于牧冰, 秦朝朝, 张晓亮. 贫PbI₂基体的胶体量子点固体用于高效红外太阳能电池[J]. 物理化学学报, 2023, 39(3): 2210002 -0 .
[3]	王成, 张弛, 黎瑞锋, 陈琪, 钱磊, 陈立桅. 量子点发光二极管中电荷累积行为[J]. 物理化学学报, 2022, 38(8): 2104030 - .
[4]	杨健, 雷辰, 刘祥, 张建, 孙玉蝶, 张铖, 叶明富, 张奎. 碳量子点阳离子表面活性剂的多功能性[J]. 物理化学学报, 2022, 38(12): 2111030 - .
[5]	吴进, 刘京, 夏雾, 任颖异, 王锋. 基于CdS和CdSe纳米半导体材料的可见光催化二氧化碳还原研究进展[J]. 物理化学学报, 2021, 37(5): 2008043 - .
[6]	郑超, 刘阿强, 毕成浩, 田建军. SCN掺杂提高CsPbI₃胶体量子点的稳定性和光探测性能[J]. 物理化学学报, 2021, 37(4): 2007084 - .
[7]	黄靖, 王丹阳, 李淑花, 范红, 范楼珍. 红色荧光碳量子点用于肿瘤微酸环境诊断[J]. 物理化学学报, 2021, 37(10): 1905067 - .
[8]	朱家瑶, 董玥, 张苏, 范壮军. 炭-/石墨烯量子点在超级电容器中的应用[J]. 物理化学学报, 2020, 36(2): 1903052 - .
[9]	黄彦捷, 连超, 周瑾艳, 黄梓宸, 康晓红, 黄振宇, 李小菁, 陈玲, 关妍. 由蚕砂制备的碳量子点在不同激发、pH、金属离子、温度及极性环境下的荧光性质研究[J]. 物理化学学报, 2019, 35(11): 1267 -1275 .
[10]	吴昊,严仲. 液相剥离法大规模制备锑烯量子点[J]. 物理化学学报, 2019, 35(10): 1052 -1057 .
[11]	薛腾,董黎路,张颖,吴海虹. 小晶粒ZSM-5沸石的绿色、经济性合成[J]. 物理化学学报, 2018, 34(8): 920 -926 .
[12]	李少海,翁波,卢康强,徐艺军. 聚胺界面修饰改善碳量子点可见光光敏化性能[J]. 物理化学学报, 2018, 34(6): 708 -718 .
[13]	贺平,袁方龙,王子飞,谭占鳌,范楼珍. 基于碳量子点的光电器件应用新进展[J]. 物理化学学报, 2018, 34(11): 1250 -1263 .
[14]	夏锐,王时茂,董伟伟,方晓东. 量子点敏化太阳能电池对电极研究进展[J]. 物理化学学报, 2017, 33(4): 670 -690 .
[15]	颜稔,赖璐,许子强,蒋风雷,刘义. 量子点与蛋白质相互作用热力学[J]. 物理化学学报, 2017, 33(12): 2377 -2387 .

以无机硫为原料制备硫化铅量子点及其表征

Preparation of PbS Quantum Dots Using Inorganic Sulfide as Precursor and Their Characterization

PDF

赞

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

Metrics

推荐阅读 0