氧化石墨烯对水中内分泌干扰物双酚A的吸附性能

doi:10.3866/PKU.WHXB201301211

物理化学学报 >> 2013, Vol. 29 >> Issue (04): 829-836.doi: 10.3866/PKU.WHXB201301211

氧化石墨烯对水中内分泌干扰物双酚A的吸附性能

徐婧¹, 朱永法^1,2

1 清华大学化学系, 北京 100084;
2 南京信息工程大学, 大气环境监测与污染控制高技术研究重点实验室, 南京 210044

收稿日期:2012-10-31 修回日期:2013-01-18 发布日期:2013-03-25
通讯作者: 朱永法 E-mail:zhuyf@tsinghua.edu.cn
基金资助:
国家重点基础研究发展计划(973) (2013CB632403), 国家高技术研究发展计划(863) (2012AA062701), 科技部创新方法工作专项(2009IM030500)及江苏省大气环境监测与污染控制高技术研究重点实验室开放基金(AEMPC201103)资助项目

Elimination of Bisphenol A from Water via Graphene Oxide Adsorption

XU Jing¹, ZHU Yong-Fa^1,2

1 Department of Chemistry, Tsinghua University, Beijing 100084, P.R. China;
2 Jiangsu Key Laboratory of Atmospheric Environment Monitoring and Pollution Control, Nanjing University of Information Science and Technology, Nanjing 210044, P.R. China

Received:2012-10-31 Revised:2013-01-18 Published:2013-03-25
Supported by:
The project was supported by the National Key Basic Research Program of China (973) (2013CB632403), National High Technology Research and Development Program of China (863) (2012AA062701), Special Project on Innovative Method from the Ministry of Science and Technology of China (2009IM030500), and Atmospheric Environment Monitoring & Pollution Control Program of Jiangsu Province, China (AEMPC201103).

摘要/Abstract

摘要：

以氧化石墨烯(GO)为吸附剂, 内分泌干扰物双酚A (BPA)为目标污染物, 考察了GO对水中BPA的吸附性能. 结果表明: GO对BPA的最大吸附量(q_m)约为87.80 mg·g^-1 (25℃), 30 min左右即可达到吸附平衡, 远快于活性碳; 吸附动力学和等温线数据分别符合准二级动力学模型和Langmuir 吸附模型; 在溶液接近中性和低温的条件下有利于吸附的进行, 在溶液中存在电解质的条件下不利于吸附的进行. GO具有优异的循环吸附性能, 经过多次循环使用后依然可以保持良好的吸附能力. GO对BPA的吸附机理主要是由于GO本身的片状结构以及表面的含氧极性基团, 会与BPA之间产生π-π色散作用和氢键作用. 虽然GO对BPA的吸附能力不如石墨烯, 但是相比于石墨烯, GO表面含有大量极性基团, 具有良好的亲水性, 且GO合成方法相对简单, 可批量生产用于工业污水处理. 因此, 在水处理领域, GO有能力成为新型高效的吸附剂.

关键词: 吸附, 氧化石墨烯, 双酚A, 内分泌干扰物, 水处理

Abstract:

The elimination of bisphenol A (BPA) from aqueous solution by adsorption on graphene oxide (GO) was investigated. The maximum adsorption capacity (q_m) of GO for BPA estimated from the Langmuir isotherm was 87.80 mg·g^-1 at 25℃. The required contact time to reach adsorption equilibrium was about 30 min, which was much shorter than that of activated carbon. The adsorption kinetics and isotherm data fitted well with the pseudo-second-order kinetic model and the Langmuir isotherm, respectively. Neutral pH and low solution temperature were favorable for adsorption, whereas the presence of NaCl in the solution was unfavorable. The GO had good recyclability and could be reused several times with a slight decline in adsorption ability. Both hydrogen bonding and π-π interaction were thought to be responsible for the adsorption of BPA on GO. The excellent adsorption capacity and high adsorption rate of GO result from its sheet-like structure and the abundant oxygen-containing groups on its surface. Although q_m of GO for BPA is lower than that of graphene, GO has the benefits of large scale production, a hydrophilic surface with plenty of oxygen-containing groups, and good dispersion in water. Therefore, GO can be regarded as a good potential adsorbent for water treatment.

Key words: Adsorption, Graphene oxide, Bisphenol A, Endocrine-disrupting chemicals, Water treatment

点击下载补充材料PDF格式文件

徐婧, 朱永法. 氧化石墨烯对水中内分泌干扰物双酚A的吸附性能[J]. 物理化学学报, 2013, 29(04): 829-836.

XU Jing, ZHU Yong-Fa. Elimination of Bisphenol A from Water via Graphene Oxide Adsorption[J]. Acta Phys. -Chim. Sin., 2013, 29(04): 829-836.

链接本文: https://www.whxb.pku.edu.cn/CN/10.3866/PKU.WHXB201301211

https://www.whxb.pku.edu.cn/CN/Y2013/V29/I04/829

参考文献

(1) Snyder, S. A.;Westerhoff, P.; Yoon, Y.; Sedlak, D. L. Environ.Sci. Technol. 2003, 20, 449.
(2) Chang, H. S.; Choo, K. H.; Lee, B.; Choi, S. J. J. Hazard.Mater. 2009, 172, 1. doi: 10.1016/j.jhazmat.2009.06.135
(3) Kang, J. H.; Kondo, F.; Katayama, Y. Toxicology 2006, 226, 79.doi: 10.1016/j.tox.2006.06.009
(4) Staples, C. A.; Dorn, P. B.; Klecka, G. M.; O'Block, S. T.;Harris, L. R. Chemosphere 1998, 36, 2149. doi: 10.1016/S0045-6535(97)10133-3
(5) Staples, C. A.; Dorn, P. B.; Klecka, G. M.; O'Block, S. T.;Branson, D. R.; Harris, L. R. Chemosphere 2000, 40, 521. doi: 10.1016/S0045-6535(99)00288-X
(6) Belfroid, A.; van Velzen, M.; van der Horst, B.; Vethaak, D.Chemosphere 2002, 49, 97. doi: 10.1016/S0045-6535(02)00157-1
(7) Pan, B.; Lin, D. H.; Mashayekhi, H.; Xing, B. S. Environ. Sci.Technol. 2009, 43, 5480.
(8) Liu, G. F.; Ma, J.; Li, X. C.; Qin, Q. D. J. Hazard. Mater. 2009,164, 1275. doi: 10.1016/j.jhazmat.2008.09.038
(9) Dong, Y.;Wu, D. Y.; Chen, X. C.; Lin, Y. J. Colloid InterfaceSci. 2010, 348, 585. doi: 10.1016/j.jcis.2010.04.074
(10) Kim, Y. H.; Lee, B.; Choo, K. H.; Choi, S. J. MicroporousMesoporous Mat. 2011, 138, 184. doi: 10.1016/j.micromeso.2010.09.007
(11) El-Naas, M. H.; Al-Muhtaseb, S. A.; Makhlouf, S. J. Hazard.Mater. 2009, 164, 720. doi: 10.1016/j.jhazmat.2008.08.059
(12) Wang, R.; Ren, D.; Xia, S.; Zhang, Y.; Zhao, J. J. Hazard.Mater. 2009, 169, 926. doi: 10.1016/j.jhazmat.2009.04.036
(13) Bautista-Toledo, I.; Ferro-Garcia, M. A.; Rivera-Utrilla, J.;Moreno-Castilla, C.; Vegas Fernandez, F. J. Environ. Sci.Technol. 2005, 39, 6246. doi: 10.1021/es0481169
(14) Pan, B.; Xing, B. S. J. Agric. Food Chem. 2010, 58, 8338. doi: 10.1021/jf101346e
(15) Kuo, C. Y. Desalination 2009, 249, 976. doi: 10.1016/j.desal.2009.06.058
(16) Xu, J.;Wang, L.; Zhu, Y. F. Langmuir 2012, 28, 8418. doi: 10.1021/la301476p
(17) Yuan,W. H.; Li, B. Q.; Li, L. Acta Phys. -Chim. Sin. 2011, 27,2244. [袁文辉, 李保庆, 李莉. 物理化学学报, 2011, 27,2244.] doi: 10.3866/PKU.WHXB20110838
(18) Nakanishi, A.; Tamai, M.; Kawasaki, N.; Nakamura, T.; Tanada,S. J. Colloid Interface Sci. 2002, 252, 393. doi: 10.1006/jcis.2002.8387
(19) Asada, T.; Oikawa, K.; Kawata, K.; Ishihara, S.; Iyobe, T.;Yamada, A. J. Health Sci. 2004, 50, 588. doi: 10.1248/jhs.50.588
(20) Furhacker, M.; Scharf, S.;Weber, H. Chemosphere 2000, 41,751. doi: 10.1016/S0045-6535(99)00466-X
(21) Dikin, D. A.; Stankovich, S.; Zimney, E. J.; Piner, R. D.;Dommett, G. H. B.; Evmenenko, G.; Nguyen, S. T.; Ruoff, R. S.Nature 2007, 448, 457. doi: 10.1038/nature06016
(22) Dreyer, D. R.; Park, S.; Bielawski, C.W.; Ruoff, R. S. Chem.Soc. Rev. 2010, 39, 228. doi: 10.1039/b917103g
(23) Yang, S. T.; Chang, Y. L.;Wang, H. F.; Liu, G. B.; Chen, S.;Wang, Y.W.; Liu, Y. F.; Cao, A. N. J. Colloid Interface Sci.2010, 351, 122. doi: 10.1016/j.jcis.2010.07.042
(24) Zhang, K.; Dwivedi, V.; Chi, C. Y.;Wu, J. S. J. Hazard. Mater.2010, 182, 162. doi: 10.1016/j.jhazmat.2010.06.010
(25) Nana, Z.; Haixia, Q.; Youmiao, S.;Wei,W.; Jianping, G.Carbon 2011, 49, 827. doi: 10.1016/j.carbon.2010.10.024
(26) Fan, L.; Luo, C.; Li, X.; Lu, F.; Qiu, H.; Sun, M. J. Hazard.Mater. 2012, 215-216, 272.
(27) Zhang,W.; Zhou, C.; Zhou,W.; Lei, A.; Zhang, Q.;Wan, Q.;Zou, B. Bull. Environ. Contam. Toxicol. 2011, 87, 86. doi: 10.1007/s00128-011-0304-1
(28) Gao, Y.; Li, Y.; Zhang, L.; Huang, H.; Hu, J.; Shah, S. M.; Su,X. J. Colloid Interface Sci. 2012, 368, 540. doi: 10.1016/j.jcis.2011.11.015
(29) Hummers,W. S.; Offeman, R. E. J. Am. Chem. Soc. 1958, 80,1339. doi: 10.1021/ja01539a017
(30) Hu, Y. J.; Jin, J.; Zhang, H.;Wu, P.; Cai, C. X. ActaPhys. -Chim. Sin. 2010, 26, 2073. [胡耀娟, 金娟, 张卉,吴萍, 蔡称心. 物理化学学报, 2010, 26, 2073.] doi: 10.3866/PKU.WHXB20100812
(31) Sing, K. S.W.; Everett, D. H.; Haul, R. A.W.; Moscou, L.;Pierotti, R. A.; Rouquerol, J.; Siemieniewska, T. Pure Appl.Chem. 1985, 57, 603. doi: 10.1351/pac198557040603
(32) Everett, D. H. Basic Principles of Colloid Science; The RoyalSociety of Chemistry: London, 1988.
(33) Fan, X. B.; Peng,W. C.; Li, Y.; Li, X. Y.;Wang, S. L.; Zhang, G.L.; Zhang, F. B. Adv. Mater. 2008, 20, 4490. doi: 10.1002/adma.v20:23
(34) Ho, Y. S.; McKay, G. Water Res. 2000, 34, 735. doi: 10.1016/S0043-1354(99)00232-8
(35) Blanchard, G.; Maunaye, M.; Martin, G. Water Res. 1984, 18,1501. doi: 10.1016/0043-1354(84)90124-6
(36) Zhao, G. X.; Li, J. X.;Wang, X. K. Chem. Eng. J. 2011, 173,185. doi: 10.1016/j.cej.2011.07.072
(37) Langmuir, I. J. Am. Chem. Soc. 1916, 38, 2221. doi: 10.1021/ja02268a002
(38) Freundlich, H. J. Phys. Electrochem. 1906, 57, 385.
(39) Hameed, B. H. J. Hazard. Mater. 2008, 154, 204. doi: 10.1016/j.jhazmat.2007.10.010
(40) Radovic, L. R.; Moreno-Castilla, C.; Rivera-Utrilla, J. CarbonMaterials as Adsorbents in Aqueous Solutions. In Chemistryand Physics of Carbon; Radovic, L. R. Ed.; Marcel Dekker:New York, 2001; Vol. 27, pp 227-405.
(41) Ersoz, A.; Denizli, A.; Sener, I.; Atilir, A.; Diltemiz, S.; Say, R.Sep. Purif. Technol. 2004, 38, 173. doi: 10.1016/j.seppur.2003.11.004
(42) Chandra, V.; Park, J.; Chun, Y.; Lee, J.W.; Hwang, I. C.; Kim,K. S. ACS Nano 2010, 4, 3979. doi: 10.1021/nn1008897
(43) Coughlin, R.W.; Ezra, F. S. Environ. Sci. Technol. 1968, 2, 291.doi: 10.1021/es60016a002

[1]	吕浩亮, 王雪杰, 杨宇, 刘涛, 张留洋. 还原氧化石墨烯包覆MOF衍生In₂Se₃用于钠离子电池负极[J]. 物理化学学报, 2023, 39(3): 2210014 -0 .
[2]	何文倩, 邸亚, 姜南, 刘遵峰, 陈永胜. 石墨烯诱导水凝胶成核的高强韧人造蛛丝[J]. 物理化学学报, 2022, 38(9): 2204059 - .
[3]	毛赫南, 王晓工. 影响高浓度氧化石墨烯分散液流变行为的重要因素及群体平衡动力学分析[J]. 物理化学学报, 2022, 38(4): 2004025 - .
[4]	常明凯, 胡娜, 李遥, 鲜东帆, 周万强, 王静一, 时燕琳, 刘春立. Eu(Ⅲ)在蒙脱石上的吸附及碳酸根和磷酸根对其吸附的影响[J]. 物理化学学报, 2022, 38(3): 2003031 - .
[5]	王键, 尹波, 高天, 王星懿, 李望, 洪兴星, 汪竹青, 何海勇. 还原氧化石墨烯改性少层剥离石墨增强石墨基钾离子电池负极稳定性[J]. 物理化学学报, 2022, 38(2): 2012088 - .
[6]	陈清, 赵健, 程虎虎, 曲良体. 石墨烯三维结构组装体制备及光热水蒸发和水处理研究进展[J]. 物理化学学报, 2022, 38(1): 2101020 - .
[7]	赵康宁, 李潇, 苏东. 高熵纳米合金在电化学催化中的应用[J]. 物理化学学报, 2021, 37(7): 2009077 - .
[8]	孙建川, 王旭辉, 陈帅奇, 廖艳清, 郜阿旺, 胡雨昊, 杨涛, 徐向宇, 王颖霞, 宋家庆. 由单层薄水铝石制备的活性氧化铝处理水中氟离子[J]. 物理化学学报, 2021, 37(10): 1911009 - .
[9]	王文元, 张杰夫, 李喆, 邵翔. 单原子分散的Au/Cu(111)表面合金的表面结构与吸附性质[J]. 物理化学学报, 2020, 36(8): 1911035 - .
[10]	孙冠卿, 易宗霖, 魏涛. 胶体颗粒稳定的界面及胶体颗粒在界面的相互作用[J]. 物理化学学报, 2020, 36(10): 1910005 - .
[11]	韩萌茹,周亚男,周旋,储伟. 通过g-C₃N₄担载MNi₁₂ (Fe, Co, Cu, Zn)纳米团簇调节甲烷化[J]. 物理化学学报, 2019, 35(8): 850 -857 .
[12]	姜哲,于飞,马杰. 石墨烯基吸附剂的设计及其对水中抗生素的去除[J]. 物理化学学报, 2019, 35(7): 709 -724 .
[13]	何妍,李豪,周莉,徐婷,彭昌军,刘洪来. 新型芳香三嗪超交联多孔聚合物去除水溶液中甲基橙[J]. 物理化学学报, 2019, 35(3): 299 -306 .
[14]	谷雨星,杨娟,汪的华. CO₂熔盐电化学转化碳材料的电化学特性[J]. 物理化学学报, 2019, 35(2): 208 -214 .
[15]	彭鹏,刘洪涛,武斌,汤庆鑫,刘云圻. 氮掺杂石墨烯的p型场效应及其精细调控[J]. 物理化学学报, 2019, 35(11): 1282 -1290 .

氧化石墨烯对水中内分泌干扰物双酚A的吸附性能

Elimination of Bisphenol A from Water via Graphene Oxide Adsorption

PDF

赞

可视化

摘要/Abstract

支持信息

引用本文

使用本文

参考文献

相关文章 15

Metrics

推荐阅读 0