超薄2D/2D NiPS3/C3N5异质结的界面工程促进光催化产氢

doi:10.3866/PKU.WHXB202305043

物理化学学报 >> 2024, Vol. 40 >> Issue (5): 2305043.doi: 10.3866/PKU.WHXB202305043

超薄2D/2D NiPS₃/C₃N₅异质结的界面工程促进光催化产氢

胡佳伟¹, 夏楷¹, 杨奥¹, 张志豪¹, 肖雯¹, 刘超¹^,²^,*(), 张勤芳¹^,*()

¹ 盐城工学院材料科学与工程学院, 江苏盐城 224051
² 盐城工学院江苏省生态环境材料重点实验室, 江苏盐城 224051

收稿日期:2023-05-22 修回日期:2023-07-12 录用日期:2023-07-12 发布日期:2023-07-19
通讯作者: Email: cliu@ycit.edu.cn (刘超)qfangzhang@gmail.com (张勤芳)
基金资助:
国家自然科学基金(51902282); 国家自然科学基金(12274361); 江苏高校青蓝工程; 江苏省自然科学基金(BK20211361); 江苏省高校自然科学研究项目(20KJA430004); 江苏省生态环境材料重点实验室开放课题资助项目

Interfacial Engineering of Ultrathin 2D/2D NiPS₃/C₃N₅ Heterojunctions for Boosting Photocatalytic H₂ Evolution

Jiawei Hu¹, Kai Xia¹, Ao Yang¹, Zhihao Zhang¹, Wen Xiao¹, Chao Liu¹^,²^,*(), Qinfang Zhang¹^,*()

¹ School of Materials Science and Engineering, Yancheng Institute of Technology, Yancheng 224051, Jiangsu Province, China
² Jiangsu Provincial Key Laboratory of Eco-Environmental Materials, Yancheng Institute of Technology, Yancheng 224051, Jiangsu Province, China

Received:2023-05-22 Revised:2023-07-12 Accepted:2023-07-12 Published:2023-07-19
Contact: Email: cliu@ycit.edu.cn (Chao Liu)qfangzhang@gmail.com (Qinfang Zhang)
Supported by:
the National Natural Science Foundation of China(51902282); the National Natural Science Foundation of China(12274361); Qinglan Project of Jiangsu of China; Natural Science Foundation of Jiangsu Province, China(BK20211361); College Natural Science Research Project of Jiangsu Province, China(20KJA430004); Open Project of Jiangsu Provincial Key Laboratory of Eco-Environmental Materials, China

1. WHXB202305043-SI-8p-R5.pdf(2940KB)

摘要/Abstract

摘要：

探索高效水分解光催化剂具有获得氢能源的巨大潜力。调控异质结界面可以有效地促进电荷载流子的分离和太阳能的利用，从而提高光催化活性。本工作使用了一种机械混合辅助自组装方法来构建NiPS₃ (NPS)纳米片(NSs)/C₃N₅ (CN) NSs (NPS/CN)异质结，即在二维(2D) CN NSs表面紧密沉积2D NPS NSs以形成2D/2D异质结构。在可见光下，通过在去离子水和海水中分解水生成氢气来评价样品的光催化性能。与CN NSs和NPS NSs相比，NPS/CN复合材料显示出较高的光催化产氢(PHE)活性，这是由于光捕获能力增加和异质结形成的协同作用所致。然而，过量的NPS NSs沉积在CN NSs表面会降低NPS/CN中CN NSs组分的光吸收，从而降低NPS/CN复合材料的PHE活性。这表明，NPS/CN复合材料要获得良好的光催化活性，需要两个组分之间适当的质量比。优化后的光催化剂(3-NPS/CN)具有良好的结构稳定性，在可见光下PHE效率最高，为47.71 μmol∙h⁻¹，是CN NSs的2385.50倍。此外，3-NPS/CN在海水中也表现出良好的PHE活性，反应速率为8.99 μmol∙h⁻¹。采用光电化学、稳态光致发光(PL)、时间分辨光致发光(TR-PL)、稳态表面光电压(SPV)和时间分辨表面光电压(TPV)技术研究了不同光催化剂上的电荷分离和迁移。根据表征结果提出了一种可能的PHE机理。在NPS/CN光催化剂中，由于CN NSs和NPS NSs之间的电位差和强的界面电子耦合，光生电子从CN NSs的导带迅速迁移到NPS NSs的导带。然后，聚积在NPS NSs组份导带上的光生电子可以有效地还原质子生成氢气分子。同时，在三乙醇胺(TEOA)分子存在下，CN NSs和NPS NSs的价带上的光生空穴被消耗。本研究提供了一种简单的2D/2D异质结构光催化剂制备方法，该方法对于构建高效二维异质结光催化剂在能源领域中的应用具有重要价值。

关键词: C₃N₅纳米片, NiPS₃纳米片, 光催化, 产氢, 异质结

Abstract:

This study focuses on exploring efficient photocatalysts for water splitting, which holds great potential for harnessing hydrogen (H₂) as a renewable energy source. Modulating the heterojunction interface is known to enhance charge carrier separation and solar energy utilization, thereby boosting photocatalytic activity. In this work, a mechanical mixing-assisted self-assembly approach was developed to construct a heterojunction between NiPS₃ (NPS) nanosheets (NSs) and C₃N₅ (CN) NSs. Specifically, two-dimensional (2D) NPS NSs were tightly deposited on 2D CN NSs surface to gain a 2D/2D heterostructure. The photocatalytic performance of the synthesized photocatalysts was determined by their ability to generate H₂ through water splitting, both in deionized (DI) water and seawater, under visible light. The resulting NPS NSs/CN NSs (NPS/CN) composites possessed boosted photocatalytic hydrogen evolution (PHE) activity related to CN NSs and NPS NSs. This improvement was assigned to the synergistic effect of increased light-harvesting capacity and heterojunction formation. Nevertheless, an excessive amount of deposited NPS NSs on the surface of CN NSs was found to reduce the light absorption of the CN NSs component in the NPS/CN composites, resulting in decreased PHE activity. Therefore, it was determined that an appropriate mass ratio between the two components is necessary to achieve excellent photocatalytic activity for the NPS/CN composites. The optimized photocatalyst, referred to as 3-NPS/CN, demonstrated the highest visible-light-driven PHE efficiency of 47.71 μmol∙h⁻¹, which was 2385.50 times higher than that of CN NSs. Moreover, 3-NPS/CN also exhibited excellent PHE activity in seawater, with a rate of 8.99 μmol∙h⁻¹. The photoelectrochemical, steady-state photoluminescence (PL), time-resolved PL (TR-PL), steady-state surface photovoltage (SPV) and time-resolved surface photovoltage (TPV) techniques were performed to investigate the charge separation and migration behaviors of various photocatalysts. Based on the characterization results, our group proposed a reasonable PHE mechanism. In the NPS/CN photocatalysts, photo-induced electrons rapidly migrated from the conduction band (CB) of CN NSs to the CB of NPS NSs due to the potential difference and strong interfacial electronic coupling between the two materials. The photogenerated electrons accumulated on the CB of the NPS NSs component efficiently reduced protons to generate H₂ molecules. Concurrently, photogenerated holes on the valence band (VB) of CN NSs and NPS NSs were consumed with the assistance of triethanolamine (TEOA) molecules. This study presents a facile method for fabricating 2D/2D heterostructured photocatalysts, which hold promise for efficient and robust implementation in energy applications.

Key words: C₃N₅ nanosheets, NiPS₃ nanosheets, Photocatalysis, Hydrogen production, Heterojunction

胡佳伟, 夏楷, 杨奥, 张志豪, 肖雯, 刘超, 张勤芳. 超薄2D/2D NiPS₃/C₃N₅异质结的界面工程促进光催化产氢[J]. 物理化学学报, 2024, 40(5), 2305043. doi: 10.3866/PKU.WHXB202305043

Jiawei Hu, Kai Xia, Ao Yang, Zhihao Zhang, Wen Xiao, Chao Liu, Qinfang Zhang. Interfacial Engineering of Ultrathin 2D/2D NiPS₃/C₃N₅ Heterojunctions for Boosting Photocatalytic H₂ Evolution[J]. Acta Phys. -Chim. Sin. 2024, 40(5), 2305043. doi: 10.3866/PKU.WHXB202305043

链接本文: https://www.whxb.pku.edu.cn/CN/10.3866/PKU.WHXB202305043

https://www.whxb.pku.edu.cn/CN/Y2024/V40/I5/2305043

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参考文献 71

1	Gao Y. ; Xu B. ; Cherif M. ; Yu H. ; Zhang Q. ; Vidal F. ; Wang X. ; Ding F. ; Sun Y. ; Ma D. ; et al Appl. Catal. B: Environ., 2020, 279, 119403. doi: 10.1016/j.apcatb.2020.119403
2	Liu C. ; Zhang Q. ; Zou Z. J. Mater. Sci. Technol. 2023, 139, 167. doi: 10.1016/j.jmst.2022.08.030
3	Fujishima A. ; Honda K. Nature 1972, 238, 37. doi: 10.1038/238037a0
4	Tong Z. ; Yang D. ; Xiao T. ; Tian Y. ; Jiang Z. Chem. Eng. J. 2015, 260, 117. doi: 10.1016/j.cej.2014.08.072
5	Fu C. ; Wu T. ; Sun G. ; Yin G. ; Wang C. ; Ran G. ; Song Q. Appl. Catal. B: Environ., 2023, 323, 122196. doi: 10.1016/j.apcatb.2022.122196
6	Liu C. ; Zhang Y. ; Wu J. ; Dai H. ; Ma C. ; Zhang Q. ; Zou Z. J. Mater. Sci. Technol. 2022, 114, 81. doi: 10.1016/j.jmst.2021.12.003
7	Gao Z. ; Chen K. ; Wang L. ; Bai B. ; Liu H. ; Wang Q. Appl. Catal. B: Environ. 2020, 268, 118462. doi: 10.1016/j.apcatb.2019.118462
8	Qin Y. ; Li H. ; Lu J. ; Feng Y. ; Meng F. ; Ma C. ; Yan Y. ; Meng M. Appl. Catal. B: Environ. 2020, 277, 119254. doi: 10.1016/j.apcatb.2020.119254
9	Lin B. ; Li H. ; An H. ; Hao W. ; Wei J. ; Dai Y. ; Ma C. ; Yang G. Appl. Catal. B: Environ. 2018, 220, 542. doi: 10.1016/j.apcatb.2017.08.071
10	Yin H. ; Yuan C. ; Lv H. ; Zhang K. ; Chen X. ; Zhang Y. ; Zhang Y. Powder Technol. 2023, 413, 118083. doi: 10.1016/j.powtec.2022.118083
11	Wang H. ; Li M. ; Lu Q. ; Cen Y. ; Zhang Y. ; Yao S. ACS Sustain. Chem. Eng. 2019, 7, 625. doi: 10.1021/acssuschemeng.8b04182
12	Huang L. ; Liu Z. ; Chen W. ; Cao D. ; Zheng A. J. Mater. Chem. A 2018, 6, 7168. doi: 10.1039/c8ta01458b
13	Teng M. ; Shi J. ; Qi H. ; Shi C. ; Wang W. ; Kang F. ; Eqi M. ; Huang Z. J. Colloid Interface Sci. 2022, 609, 592. doi: 10.1016/j.jcis.2021.11.060
14	Sun D. ; Zhang X. ; Shi A. ; Quan C. ; Xiao S. ; Ji S. ; Zhou Z. ; Li X. ; Chi F. ; Niu X. Appl. Surf. Sci. 2022, 601, 154186. doi: 10.1016/j.apsusc.2022.154186
15	Li K. ; Cai W. ; Zhang Z. ; Xie H. ; Zhong Q. ; Qu H. Chem. Eng. J. 2022, 435, 135017. doi: 10.1016/j.cej.2022.135017
16	Meng Q. ; Yang X. ; Wu L. ; Chen T. ; Li Y. ; He R. ; Zhu W. ; Zhu L. ; Duan T. J. Hazard. Mater. 2022, 422, 126912. doi: 10.1016/j.jhazmat.2021.126912
17	Wang R. ; Zhang K. ; Zhong X. ; Jiang F. RSC Adv. 2022, 12, 24026. doi: 10.1039/d2ra03874a
18	Wu B. ; Sun T. ; Liu N. ; Lu L. ; Zhang R. ; Shi W. ; Cheng P. ACS Appl. Mater. Interfaces 2022, 14, 26742. doi: 10.1021/acsami.2c04729
19	Liu D. ; Yao J. ; Chen S. ; Zhang J. ; Li R. ; Peng T. Appl. Catal. B: Environ., 2022, 318, 121822. doi: 10.1016/j.apcatb.2022.121822
20	Shi J. ; Wang W. ; Teng M. ; Kang F. ; E'qi M. ; Huang Z. J. Colloid Interface Sci. 2022, 608, 954. doi: 10.1016/j.jcis.2021.10.027
21	Xiong Z. ; Liang Y. ; Yang J. ; Yang G. ; Jia J. ; Sa K. ; Zhang X. ; Zeng Z. Sep. Purif. Technol. 2023, 306, 122522. doi: 10.1016/j.seppur.2022.122522
22	Zhang X. ; Zhao X. ; Wu D. ; Jing Y. ; Zhou Z. Adv. Sci. 2016, 3, 1600062. doi: 10.1002/advs.201600062
23	Wang J. ; Li X. ; Wei B. ; Sun R. ; Yu W. ; Hoh H. Y. ; Xu H. ; Li J. ; Ge X. ; Chen Z. ; et al Adv. Funct. Mater., 2020, 30, 1908708. doi: 10.1002/adfm.201908708
24	Wang F. ; Shifa T. A. ; He P. ; Cheng Z. ; Chu J. ; Liu Y. ; Wang Z. ; Wang F. ; Wen Y. ; Liang L. ; et al Nano Energy 2017, 40, 673. doi: 10.1016/j.nanoen.2017.09.017
25	Shifa T. A. ; Wang F. ; Cheng Z. ; He P. ; Liu Y. ; Jiang C. ; Wang Z. ; He J. Adv. Funct. Mater. 2018, 28, 1800548. doi: 10.1002/adfm.201800548
26	Gusmao R. ; Sofer Z. ; Sedmidubsky D. ; Huber S. ; Pumera M. ACS Catal. 2017, 7, 8159. doi: 10.1021/acscatal.7b02134
27	Cheng Z. ; Shifa T. A. ; Wang F. ; Gao Y. ; He P. ; Zhang K. ; Jiang C. ; Liu Q. ; He J. Adv. Mater. 2018, 30, 1707433. doi: 10.1002/adma.201707433
28	Barua M. ; Ayyub M. M. ; Vishnoi P. ; Pramoda K. ; Rao C. N. R. J. Mater. Chem. A 2019, 7, 22500. doi: 10.1039/c9ta06044h
29	Jenjeti R. N. ; Kumar R. ; Austeria M. P. ; Sampath S. Sci. Rep. 2018, 8, 8586. doi: 10.1038/s41598-018-26522-1
30	Chittari B. L. ; Park Y. ; Lee D. ; Han M. ; MacDonald A. H. ; Hwang E. ; Jung J. Phys. Rev. B 2016, 94, 184428. doi: 10.1103/PhysRevB.94.184428
31	Chu J. ; Wang F. ; Yin L. ; Lei L. ; Yan C. ; Wang F. ; Wen Y. ; Wang Z. ; Jiang C. ; Feng L. ; et al Adv. Funct. Mater. 2017, 27, 1701342. doi: 10.1002/adfm.201701342
32	Fang L. ; Xie Y. ; Guo P. ; Zhu J. ; Xiao S. ; Sun S. ; Zi W. ; Zhao H. Sustain. Energy Fuels 2021, 5, 2537. doi: 10.1039/d1se00110h
33	Ran J. ; Zhang H. ; Fu S. ; Jaroniec M. ; Shan J. ; Xia B. ; Qu Y. ; Qu J. ; Chen S. ; Song L. ; et al Nat. Commun. 2022, 13, 4600. doi: 10.1038/s41467-022-32256-6
34	Li S. ; Cai M. ; Liu Y. ; Zhang J. ; Wang C. ; Zang S. ; Li Y. ; Zhang P. ; Li X. Org. Chem. Front. 2022, 9, 2479. doi: 10.1039/D2QI00317A
35	Zhang Q. ; Gu H. ; Wang X. ; Li L. ; Zhang J. ; Zhang H. ; Li Y.-F. ; Dai W. ; - L. Appl. Catal. B: Environ., 2021, 298, 120632. doi: 10.1016/j.apcatb.2021.120632
36	Liu C. ; Xiao W. ; Yu G. ; Wang Q. ; Hu J. ; Xu C. ; Du X. ; Xu J. ; Zhang Q. ; Zou Z. J. Colloid Interface Sci. 2023, 640, 851. doi: 10.1016/j.jcis.2023.02.137
37	Han L. ; Peng C. ; Huang J. ; Wang S. ; Zhang X. ; Chen H. ; Yang Y. Rsc Adv. 2021, 11, 36166. doi: 10.1039/d1ra07275g
38	Zhang J. ; Jing B. ; Tang Z. ; Ao Z. ; Xia D. ; Zhu M. ; Wang S. Appl. Catal. B: Environ. 2021, 289, 120023. doi: 10.1016/j.apcatb.2021.120023
39	Kumar P. ; Vahidzadeh E. ; Thakur U. K. ; Kar P. ; Alam K. M. ; Goswami A. ; Mahdi N. ; Cui K. ; Bernard G. M. ; Michaelis V. K. ; et al J. Am. Chem. Soc. 2019, 141, 5415. doi: 10.1021/jacs.9b00144
40	Sun Z. ; Luo E. ; Meng Q. ; Wang X. ; Ge J. ; Liu C. ; Xing W. Acta Phys. -Chim. Sin. 2022, 38, 2003035. doi: 10.3866/PKU.WHXB202003035
	孙志聪; 罗二桂; 孟庆磊; 王显; 葛君杰; 刘长鹏; 邢巍.. 物理化学学报, 2022, 38, 2003035. doi: 10.3866/PKU.WHXB202003035
41	Wang J. ; Wang T. ; Shi X. ; Wu J. ; Xu Y. ; Ding X. ; Yu Q. ; Zhang K. ; Zhou P. ; Jiang Z. J. Mater. Chem. C, 2019, 7, 14625. doi: 10.1039/c9tc04722k
42	Zhang J. ; Tao H. ; Wu S. ; Yang J. ; Zhu M. Appl. Catal. B: Environ. 2021, 296, 120372. doi: 10.1016/j.apcatb.2021.120372
43	Li S. ; Wang C. ; Cai M. ; Liu Y. ; Dong K. ; Zhang J. J. Colloid Interface Sci. 2022, 624, 219. doi: 10.1016/j.jcis.2022.05.151
44	Zhang G. ; Wang Z. ; He T. ; Wu J. ; Zhang J. ; Wu J. Chem. Eng. J. 2022, 442, 136309. doi: 10.1016/j.cej.2022.136309
45	Liu C. ; Han Z. ; Feng Y. ; Dai H. ; Zhao Y. ; Han N. ; Zhang Q. ; Zou Z. J. Colloid Interface Sci. 2021, 583, 58. doi: 10.1016/j.jcis.2020.09.018
46	Sun T. ; Li C. ; Bao Y. ; Fan J. ; Liu E. Acta Phys. -Chim. Sin. 2023, 39, 2212009. doi: 10.3866/PKU.WHXB202212009
	孙涛; 李晨曦; 鲍钰鹏; 樊君; 刘恩周.. 物理化学学报, 2023, 39, 2212009. doi: 10.3866/PKU.WHXB202212009
47	Che H. ; Wang J. ; Gao X. ; Chen J. ; Wang P. ; Liu B. ; Ao Y. J. Colloid Interface Sci. 2022, 627, 739. doi: 10.1016/j.jcis.2022.07.080
48	Zhan X. ; Zheng Y. ; Li B. ; Fang Z. ; Yang H. ; Zhang H. ; Xu L. ; Shao G. ; Hou H. ; Yang W. Chem. Eng. J. 2022, 431, 134053. doi: 10.1016/j.cej.2021.134053
49	Zhao L. ; Lei S. ; Tang C. ; Tu Q. ; Rao L. ; Liao H. ; Zeng W. ; Xiao Y. ; Cheng B. J. Colloid Interface Sci. 2022, 616, 401. doi: 10.1016/j.jcis.2022.02.089
50	Vedhanarayanan B. ; Chiu C.-C. ; Regner J. ; Sofer Z. ; Seetha Lakshmi K. C. ; Lin J.-Y. ; Lin T. ; - W. Chem. Eng. J., 2022, 430, 132649. doi: 10.1016/j.cej.2021.132649
51	Mane G. P. ; Talapaneni S. N. ; Lakhi K. S. ; Ilbeygi H. ; Ravon U. ; Al-Bahily K. ; Mori T. ; Park D.-H. ; Vinu A. Angew. Chem. Int. Ed. 2017, 56, 8481. doi: 10.1002/anie.201702386
52	Bai J. ; Chen W. ; Hao L. ; Shen R. ; Zhang P. ; Li N. ; Li X. Chem. Eng. J. 2022, 447, 137488. doi: 10.1016/j.cej.2022.137488
53	Sun H. ; Shi Y. ; Shi W. ; Guo F. Appl. Surf. Sci. 2022, 593, 153281. doi: 10.1016/j.apsusc.2022.153281
54	Chen K. ; Shi Y. ; Shu P. ; Luo Z. ; Shi W. ; Guo F. Chem. Eng. J. 2023, 454, 140053. doi: 10.1016/j.cej.2022.140053
55	Yu G. ; Zhang Y. ; Du X. ; Wu J. ; Liu C. ; Zou Z. J. Colloid Interface Sci. 2022, 623, 205. doi: 10.1016/j.jcis.2022.05.040
56	Xiong Z ; Hou Y. ; Yuan R. ; Ding Z. ; Ong W. J. ; Wang S. Acta Phys. -Chim. Sin. 2022, 38, 2111021. doi: 10.3866/PKU.WHXB202111021
	熊壮; 侯乙东; 员汝胜; 丁正新; 王伟俊; 汪思波.. 物理化学学报, 2022, 38, 2111021. doi: 10.3866/PKU.WHXB202111021
57	Yu G. ; Hu F. ; Cheng W. ; Han Z. ; Liu C. ; Dai Y. Acta Phys. -Chim. Sin. 2020, 36, 1911016. doi: 10.3866/PKU.WHXB201911016
	郁桂云; 胡丰献; 程伟伟; 韩字童; 刘超; 戴勇.. 物理化学学报, 2020, 36, 1911016. doi: 10.3866/PKU.WHXB201911016
58	Cai X. ; Du J. ; Zhong G. ; Zhang Y. ; Mao L. ; Lou Z. Acta Phys. -Chim. Sin., 2023, 39, 2302017. doi: 10.3866/PKU.WHXB202302017
	蔡晓燕; 杜家豪; 钟光明; 张一鸣; 毛梁; 娄在祝.. 物理化学学报, 2023, 39, 2302017. doi: 10.3866/PKU.WHXB202302017
59	Cai M. ; Liu Y. ; Wang C. ; Lin W. ; Li S. Sep. Purif. Technol. 2023, 304, 122401. doi: 10.1016/j.seppur.2022.122401
60	Liu C. ; Xu Q. ; Zhang Q. ; Zhu Y. ; Ji M. ; Tong Z. ; Hou W. ; Zhang Y. ; Xu J. J. Mater. Sci. 2019, 54, 2458. doi: 10.1007/s10853-018-2990-0
61	Xie Y. ; Zhang Q. ; Sun H. ; Teng Z. ; Su C. Acta Phys. -Chim. Sin. 2023, 39, 2301001. doi: 10.3866/PKU.WHXB202301001
	谢垚; 张启涛; 孙宏丽; 滕镇远; 苏陈良.. 物理化学学报, 2023, 39, 2301001. doi: 10.3866/PKU.WHXB202301001
62	Liu C. ; Xiao W. ; Liu X. ; Wang Q. ; Hu J. ; Zhang S. ; Xu J. ; Zhang Q. ; Zou Z. J. Mater. Sci. Technol. 2023, 161, 123. doi: 10.1016/j.jmst.2023.04.007
63	Liu C. ; Feng Y. ; Han Z. ; Sun Y. ; Wang X. ; Zhang Q. ; Zou Z. Chin. J. Catal. 2021, 42, 164. doi: 10.1016/S1872-2067(20)63608-7
64	Dang X. ; Xie M. ; Dai F. ; Guo J. ; Liu J. ; Lu X. J. Mater. Chem. A 2021, 9, 14888. doi: 10.1039/D1TA02052H
65	Zhang X. ; Hu K. ; Zhang X. ; Ali W. ; Li Z. ; Qu Y. ; Wang H. ; Zhang Q. ; Jing L. Appl. Surf. Sci. 2019, 492, 125. doi: 10.1016/j.apsusc.2019.06.189
66	Wang J. ; Qin C. ; Wang H. ; Chu M. ; Zada A. ; Zhang X. ; Li J. ; Raziq F. ; Qu Y. ; Jing L. Appl. Catal. B: Environ. 2018, 221, 459. doi: 10.1016/j.apcatb.2017.09.042
67	Li L. ; Zhang R. ; Lin Y. ; Wang D. ; Xie T. Chem. Eng. J., 2023, 453, 139970. doi: 10.1016/j.cej.2022.139970
68	Liu S. ; Wang K. ; Yang M. ; Jin Z. Acta Phys. -Chim. Sin. 2022, 38, 2109023. doi: 10.3866/PKU.WHXB202109023
	刘珊池; 王凯; 杨梦雪; 靳治良.. 物理化学学报, 2022, 38, 2109023. doi: 10.3866/PKU.WHXB202109023
69	Guo S. ; Li Y. ; Xue C. ; Sun Y. ; Wu C. ; Shao G. ; Zhang P. Chem. Eng. J. 2021, 419, 129213. doi: 10.1016/j.cej.2021.129213
70	Cheng C. ; Zhang J. ; Zeng R. ; Xing F. ; Huang C. Appl. Catal. B: Environ. 2022, 310, 121321. doi: 10.1016/j.apcatb.2022.121321
71	Zheng J. ; Lei Z. Appl. Catal. B: Environ. 2018, 237, 1. doi: 10.1016/j.apcatb.2018.05.060

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超薄2D/2D NiPS₃/C₃N₅异质结的界面工程促进光催化产氢

Interfacial Engineering of Ultrathin 2D/2D NiPS₃/C₃N₅ Heterojunctions for Boosting Photocatalytic H₂ Evolution

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