物理化学学报 >> 2000, Vol. 16 >> Issue (06): 533-537.doi: 10.3866/PKU.WHXB20000611

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钡对氧化铝的高温热稳定作用

刘勇, 王敬先, 杨竹仙, 何阿弟, 陈晓银   

  1. 复旦大学环境科学与工程系，上海 200433
  • 收稿日期:1999-09-13 修回日期:1999-11-15 发布日期:2000-06-15
  • 通讯作者: 陈晓银 E-mail:Chenxy@fudan.edu.cn

Thermal Stabilization of Barium on the Alumina at High Tempeiature

Liu Yong, Wang Jing-Xian, Yang Zhu-Xian, He A-Di, Chen Xiao-Yin   

  1. Department of Environmental Science and Engineering,Fudan University,Shanghai 200433
  • Received:1999-09-13 Revised:1999-11-15 Published:2000-06-15
  • Contact: Chen Xiao-Yin E-mail:Chenxy@fudan.edu.cn

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关键词: 氧化铝, 热稳定性, 钡, 改性

Abstract:

The thermal stabilization mechanism of barium and the effects of preparation methods, barium content and calcination temperature were studied by BET specific surface area and powder X ray diffraction. It was found that barium can stabilize the alumina at high temperature (≥1000 ℃) and the stabilization effect was enhanced with the increase of the barium content, whereas, the overabundance weakened the stabilization effect. The preparation methods influenced the thermal stability of alumina and the stabilization effect of barium. At high temperature, the stabilization effect of barium species can be attributed to the dispersed baria and not hexaaluminate retarding the loss of specific surface area due to the sintering and α phase transformation within the initial 1 h of the calcination process.

Key words: Alumina, Thermal stability, Barium, Modification