物理化学学报 >> 1999, Vol. 15 >> Issue (09): 794-798.doi: 10.3866/PKU.WHXB19990905

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YTaO4：Gd,Eu体系光致发光中的能量传递

李博, 顾镇南, 林建华, 苏勉曾   

  1. 北京大学化学系；稀土材料化学与应用国家重点实验室，北京 100871
  • 收稿日期:1998-11-27 修回日期:1999-02-09 发布日期:1999-09-15
  • 通讯作者:

Energy Transfer in the Luminescence Process of YTaO4：Gd,Eu

Li Bo, Gu Zhen-Nan, Lin Jian-Hua, Su Mian-Zeng   

  1. Chemistry Department,Peking University,Beijing 100871;State Key Laboratory of Rare Earth Materials-chemistry and Applications,Peking University,Beijing 100871
  • Received:1998-11-27 Revised:1999-02-09 Published:1999-09-15
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摘要：

用高温固相反应法合成了钆、铕离子双掺杂的正钽酸盐化合物YTaO4 :Gd ,Eu ,研究了该体系在紫外光激发下的发光性能 .对该体系激发、发射及漫反射光谱的研究表明 ,Gd3+ 离子在发光过程中可以作为能量传递的中介 ,该体系在发光过程中存在钽酸根到Eu3+ 离子 ,或者钽酸根到Gd3+离子、再到Eu3+离子的能量传递.

关键词: 发光, 但酸盐, 稀土

Abstract:

Yttrium orthotantalate co doped by Eu 3+ and Gd 3+ has been synthesized by solid state method. The emission and excitation spectra of YTaO4: Gd, Eu are studied in detail. In the excitation spectra of Eu 3+5D 0→ 7F2 transition emission in YTaO4:Gd, Eu, there appear excitations of Gd3+ and TaO43- group, which indicate energy transfer from Gd 3+ and TaO4 3-  group to Eu 3+ in the process of luminescence. The excitation spectra of Gd 3+ emission(λ=312 5 nm) including strong excitation of charge transfer of group show energy transfer from host lattice to Gd 3+ . So there are two ways of energy transfer in YTaO4:Gd,Eu system. The strong evidences from excitation spectra, emission spectra and diffusive reflection spectra of this system show that Gd 3+ can play an intermediate role in the process of luminescence. There is energy transfer from TaO 3- 4 to Gd 3+ and finally to Eu 3+ via the charge transfer state and spectral overlap. The energy transfer from TaO 3- 4 to Gd 3+ is a dominating process in this system. 

Key words: Luminescence, Tantalate, Rare earth