物理化学学报 >> 1997, Vol. 13 >> Issue (08): 725-731.doi: 10.3866/PKU.WHXB19970809

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缔合马丁-侯状态方程I 方程的建立

南延青,侯虞钧,俞庆森   

  1. 浙江大学化学工程系，杭州 310027
  • 收稿日期:1996-07-11 修回日期:1997-04-01 发布日期:1997-08-15
  • 通讯作者:

The Associating MH Equation of State

Nan Yan-Qing,Hou Yu-Jun,Yu Qing-Sen   

  1. Department of Chemical Engineering,Zhejiang University,Hangzhou 310027
  • Received:1996-07-11 Revised:1997-04-01 Published:1997-08-15
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关键词: 马丁-侯状态方程, 缔合, 水, 醇, 羟酸

Abstract:

An associating MH equation of state (AMH EOS) is developed on the basis of the MH equation of state by incorporating the chemical association into it, a constant evaluation method is proposed for the AMH EOS. The AMH EOS is used to calculate thermodynamic properties of water, some alcohols and carboxylic acids, good results are obtained. It shows that the constant evaluation method is feasible.

Key words: MH equation of state, Association, Water;Alcohol, Carboxylic acid