物理化学学报 >> 2008, Vol. 24 >> Issue (06): 1007-1011.doi: 10.3866/PKU.WHXB20080616

研究论文 上一篇    下一篇

导电ZAO纳米晶的超声鄄模板法合成、表征及应用

罗重霄; 王燕; 刘金库; 连加松; 柴春芳   

  1. 华东理工大学化学系, 上海 200237; 浙江超微细化工有限公司, 浙江 乐清 325611
  • 收稿日期:2007-12-03 修回日期:2008-01-29 发布日期:2008-06-03
  • 通讯作者: 刘金库 E-mail:jkliu@ecust.edu.cn

Characterizations and Application of Conductive ZAO Nanocrystals Prepared by Ultrasonic-Template Method

LUO Chong-Xiao; WANG Yan; LIU Jin-Ku; LIAN Jia-Song; CHAI Chun-Fang   

  1. Department of Chemistry, East China University of Science and Technology, Shanghai 200237, P. R. China; Zhejiang Ultrafine Powders &Chemicals Co. Ltd., Yueqing 325611, Zhejiang Province, P. R. China
  • Received:2007-12-03 Revised:2008-01-29 Published:2008-06-03
  • Contact: LIU Jin-Ku E-mail:jkliu@ecust.edu.cn

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摘要： 采用超声-模板法高效合成出了分散好、导电性能优良的白色掺铝氧化锌(ZAO)纳米晶, 通过TEM、XRD、FT-IR、TG-DTA、UV-Vis等手段对产物形貌、结构及前驱物的热性质等进行了研究, 并研究了Al2O3掺入量与ZAO的电阻率、紫外-可见光谱吸收峰位置、能带带宽之间的关系. 将制得的导电ZAO纳米晶加入到抗静电涂料体系中, 不仅使涂料具有颜色浅、易于调色及导电性好等优点, 而且还大大提高了涂料的抗紫外等性能.

关键词: 超声, 模板, 导电, 掺铝氧化锌, 涂料

Abstract: The white zinc aluminium oxide (ZAO) nanocrystals with excellent dispersity and electrical conductivity were efficiently synthesized by the ultrasonic-template method. The morphologies, structures of the ZAO nanocrystals andthe thermochemistry of the precursorwere researchedbyTEM,XRD, FT-IR, TG-DTA, and UV-Vis, etc. The relationships of Al2O3 addition quantity with the resistivity, UV-Vis absorption wavelength, and energy band gap of ZAO nanocrystals were also studied. The ZAO nanocrystals were added to the anlistatig-coatings system, and the obtained coating’s color was easy to be modulated, its electrical conductivity and UV-absorption were also obviously improved.

Key words: Ultrasonic, Template, Electric, Zinc aluminiumoxide, Coating