缺陷工程调控石墨相氮化碳及其光催化空气净化应用进展

doi:10.3866/PKU.WHXB202011073

物理化学学报 >> 2021, Vol. 37 >> Issue (8): 2011073.doi: 10.3866/PKU.WHXB202011073

所属专题：二维光催化材料

缺陷工程调控石墨相氮化碳及其光催化空气净化应用进展

王薇¹^,², 黄宇¹^,*(), 王震宇¹

¹ 中国科学院地球环境研究所，气溶胶化学与物理重点实验室，黄土与第四纪地质国家重点实验室，西安 710061
² 中国科学院大学，北京 100049

收稿日期:2020-11-28 录用日期:2020-12-28 发布日期:2020-12-30
通讯作者: 黄宇 E-mail:huangyu@ieecas.cn
作者简介:Yu Huang is currently a full professor at Key Lab of Aerosol Chemistry & Physics, Institute of Earth Environment, Chinese Academy of Sciences. He obtained his Ph.D. degree in 2012 from The Hong Kong Polytechnic University. His research interests include atmospheric VOCs characteristics and environmental effects, indoor air quality, air pollution control research and application
基金资助:
国家重点研发计划“纳米科技重点专项”(2016YFA0203000);国家自然科学基金(51878644);国家自然科学基金(41573138);中国科学院先导专项(XDA23010300);中国科学院先导专项(XDA23010000)

Defect Engineering in Two-Dimensional Graphitic Carbon Nitride and Application to Photocatalytic Air Purification

Wei Wang¹^,², Yu Huang¹^,*(), Zhenyu Wang¹

¹ State Key Laboratory of Loess and Quaternary Geology, Key Laboratory of Aerosol Chemistry and Physics, Institute of Earth Environment, Chinese Academy of Sciences, Xi'an 710061, China
² University of Chinese Academy of Sciences, Beijing 100049, China

Received:2020-11-28 Accepted:2020-12-28 Published:2020-12-30
Contact: Yu Huang E-mail:huangyu@ieecas.cn
About author:Yu Huang, Email: huangyu@ieecas.cn; Tel.: +86-29-6233-6261
Supported by:
the National Key Research and Development Program of China(2016YFA0203000);National Nature Science Foundation of China(51878644);National Nature Science Foundation of China(41573138);Strategic Priority Research Program of the Chinese Academy of Sciences, China(XDA23010300);Strategic Priority Research Program of the Chinese Academy of Sciences, China(XDA23010000)

摘要/Abstract

摘要：

二维石墨相氮化碳(2D g-C₃N₄)由于其特殊的π-π共轭结构，较窄的禁带宽度(2.7 eV)以及比表面积大、结构稳定、绿色无毒、来源广泛等特点，在光催化领域显示出巨大的应用潜力。然而，传统g-C₃N₄由于其可见光吸收差、光生载流子复合快、量子效率低等固有缺点导致其光催化性能较差，限制其应用。迄今为止，研究人员已经设计并开发了异质结构建、缺陷工程和形貌调控等多种策略来改善g-C₃N₄光催化活性。其中，缺陷工程通过调节g-C₃N₄的表面电子结构和能级结构来提高其光捕获、光生载流子分离-迁移和目标分子吸附/活化能力，从而改善其光催化能力。本文综述了非外源因素诱导(碳空位、氮空位等)以及外源因素诱导缺陷(掺杂和功能化)修饰g-C₃N₄，调控其光电子及光催化性能的最新研究进展，并介绍了2D g-C₃N₄在光催化净化大气方面的应用进展。最后，对g-C₃N₄在光催化领域的后续研究进行了展望。这篇文章的主要目的是为全面、深入地理解缺陷调控g-C₃N₄光催化性能的机制提供思路，以期更好地指导g-C₃N₄光催化剂的后续研究及其工商业应用开发。

关键词: 石墨相氮化碳(g-C₃N₄), 缺陷工程, 光催化, 实际应用

Abstract:

Since the pioneering work on polychlorinated biphenyl photodegradation by Carey in 1976, photocatalytic technology has emerged as a promising and sustainable strategy to overcome the significant challenges posed by energy crisis and environmental pollution. In photocatalysis, sunlight, which is an inexhaustible source of energy, is utilized to generate strongly active species on the surface of the photocatalyst for triggering photo-redox reactions toward the successful removal of environmental pollutants, or for water splitting. The photocatalytic performance is related to the photoabsorption, photoinduced carrier separation, and redox ability of the semiconductor employed as the photocatalyst. Apart from traditional and noble metal oxide semiconductors such as P25, bismuth-based compounds, and Pt-based compounds, 2D g-C₃N₄ is now identified to have enormous potential in photocatalysis owing to the special π-π conjugated bond in its structure. However, some inherent drawbacks of the conventional g-C₃N₄, including the insufficient visible-light absorption ability, fast recombination of photogenerated electron-hole pairs, and low quantum efficiency, decrease its photocatalytic activity and limit its application. To date, various strategies such as heterojunction fabrication, special morphology design, and element doping have been adopted to tune the physicochemical properties of g-C₃N₄. Recent studies have highlighted the potential of defect engineering for boosting the light harvesting, charge separation, and adsorption efficiency of g-C₃N₄ by tailoring the local surface microstructure, electronic structure, and carrier concentration. In this review, we summarize cutting-edge achievements related to g-C₃N₄ modified with classified non-external-caused defects (carbon vacancies, nitrogen vacancies, etc.) and external-caused defects (doping and functionalization) for optimizing the photocatalytic performance in water splitting, removal of contaminants in the gas phase and wastewater, nitrogen fixation, etc. The distinctive roles of various defects in the g-C₃N₄ skeleton in the photocatalytic process are also summarized. Moreover, the practical application of 2D g-C₃N₄ in air pollution control is highlighted. Finally, the ongoing challenges and perspectives of defective g-C₃N₄ are presented. The overarching aim of this article is to provide a useful scaffold for future research and application studies on defect-modulated g-C₃N₄.

Key words: Graphitic carbon nitride, Defect engineering, Photocatalysis, Practical application

王薇, 黄宇, 王震宇. 缺陷工程调控石墨相氮化碳及其光催化空气净化应用进展[J]. 物理化学学报, 2021, 37(8), 2011073. doi: 10.3866/PKU.WHXB202011073

Wei Wang, Yu Huang, Zhenyu Wang. Defect Engineering in Two-Dimensional Graphitic Carbon Nitride and Application to Photocatalytic Air Purification[J]. Acta Phys. -Chim. Sin. 2021, 37(8), 2011073. doi: 10.3866/PKU.WHXB202011073

链接本文: https://www.whxb.pku.edu.cn/CN/10.3866/PKU.WHXB202011073

https://www.whxb.pku.edu.cn/CN/Y2021/V37/I8/2011073

图/表 7

Fig 1

Fig 2

Fig 3

Fig 4

Fig 5

Fig 6

Fig 7

参考文献 98

1	Su J. ; Li G.-D. ; Li X.-H. ; Chen J.-S. Adv. Sci. 2019, 6 (7), 1801702. doi: 10.1002/advs.201801702
2	Xiong J. ; Di J. ; Xia J. ; Zhu W. ; Li H. Adv. Funct. Mater. 2018, 28 (39), 1801983. doi: 10.1002/adfm.201801983
3	Zheng Y. ; Liu J. ; Liang J. ; Jaroniec M. ; Qiao S. Z. Energy Environ. Sci. 2012, 5 (5), 6717. doi: 10.1039/C2EE03479D
4	Cao S. ; Yu J. J. Phys. Chem. Lett. 2014, 5 (12), 2101. doi: 10.1021/jz500546b
5	Zhao Z. ; Sun Y. ; Dong F. Nanoscale 2015, 7 (1), 15. doi: 10.1039/C4NR03008G
6	Wang Y. ; Wang X. ; Antonietti M. Angew. Chem. Int. Ed. 2012, 51 (1), 68. doi: 10.1002/anie.201101182
7	Wang Z. ; Chen M. ; Huang Y. ; Shi X. ; Zhang Y. ; Huang T. ; Cao J. ; Ho W. ; Lee S. C. Appl. Catal. B 2018, 239, 352. doi: 10.1016/j.apcatb.2018.08.030
8	Tang J.-Y. ; Kong X. Y. ; Ng B.-J. ; Chew Y.-H. ; Mohamed A. R. ; Chai S.-P. Catal. Sci. Technol. 2019, 9 (9), 2335. doi: 10.1039/C9CY00449A
9	Xue J. ; Fujitsuka M. ; Majima T. Phys. Chem. Chem. Phys. 2019, 21 (5), 2318. doi: 10.1039/C8CP06922K
10	Wu M. ; Gong Y. ; Nie T. ; Zhang J. ; Wang R. ; Wang H. ; He B. J. Mater. Chem. A 2019, 7 (10), 5324. doi: 10.1039/C8TA12076E
11	Zhang D. ; Tan G. ; Wang M. ; Li B. ; Dang M. ; Ren H. ; Xia A. Mater. Res. Bull. 2020, 122, 110685. doi: 10.1016/j.materresbull.2019.110685
12	Guo Q. ; Zhang Y. ; Zhang H.-S. ; Liu Y. ; Zhao Y.-J. ; Qiu J. ; Dong G. Adv. Funct. Mater. 2017, 27 (42), 1703711. doi: 10.1002/adfm.201703711
13	Ong W.-J. ; Tan L.-L. ; Ng Y. H. ; Yong S.-T. ; Chai S.-P. Chem. Rev. 2016, 116 (12), 7159. doi: 10.1021/acs.chemrev.6b00075
14	Martin D. J. ; Qiu K. ; Shevlin S. A. ; Handoko A. D. ; Chen X. ; Guo Z. ; Tang J. Angew. Chem. Int. Ed. 2014, 53 (35), 9240. doi: 10.1002/anie.201403375
15	Frank S. N. ; Bard A. J. J. Am. Chem. Soc. 1977, 99 (14), 4667. doi: 10.1021/ja00456a024
16	Huang Y. ; Zhu D. ; Zhang Q. ; Zhang Y. ; Cao J.-J. ; Shen Z. ; Ho W. ; Lee S. C. Appl. Catal. B 2018, 234, 70. doi: 10.1016/j.apcatb.2018.04.039
17	Huang Y. ; Liang Y. ; Rao Y. ; Zhu D. ; Cao J.-J. ; Shen Z. ; Ho W. ; Lee S. C. Environ. Sci. Technol. 2017, 51 (5), 2924. doi: 10.1021/acs.est.6b04460
18	Huang Y. ; Wang W. ; Zhang Q. ; Cao J.-J. ; Huang R.-J. ; Ho W. ; Lee S. C. Sci. Rep. 2016, 6 (1), 23435. doi: 10.1038/srep23435
19	Wang X. ; Maeda K. ; Thomas A. ; Takanabe K. ; Xin G. ; Carlsson J. M. ; Domen K. ; Antonietti M. Nat. Mater. 2009, 8 (1), 76. doi: 10.1038/nmat2317
20	Wang Y. ; Rao L. ; Wang P. ; Shi Z. ; Zhang L. Appl. Catal. B 2020, 262, 118308. doi: 10.1016/j.apcatb.2019.118308
21	Peng G. ; Wu J. ; Wang M. ; Niklas J. ; Zhou H. ; Liu C. Nano Lett. 2020, 20 (4), 2879. doi: 10.1021/acs.nanolett.0c00698
22	Wang Z. ; Huang Y. ; Ho W. ; Cao J. ; Shen Z. ; Lee S. C. Appl. Catal., B 2016, 199, 123. doi: 10.1016/j.apcatb.2016.06.027
23	Wang Z. ; Huang Y. ; Chen L. ; Chen M. ; Cao J. ; Ho W. ; Lee S. C. J. Mater. Chem. A 2018, 6 (3), 972. doi: 10.1039/C7TA09132J
24	Lei F. ; Sun Y. ; Liu K. ; Gao S. ; Liang L. ; Pan B. ; Xie Y. J. Am. Chem. Soc. 2014, 136 (19), 6826. doi: 10.1021/ja501866r
25	Wang Y. ; Shen S. Acta Phys. -Chim. Sin. 2020, 36 (3), 1905080.
	王亦清; 沈少华; 物理化学学报, 2020, 36 (3), 1905080. doi: 10.3866/PKU.WHXB201905080
26	Zhang C. ; Li Y. ; Shuai D. ; Shen Y. ; Xiong W. ; Wang L. Chemosphere 2019, 214, 462. doi: 10.1016/j.chemosphere.2018.09.137
27	Jourshabani M. ; Lee B.-K. ; Shariatinia Z. Appl. Catal. B 2020, 276, 119157. doi: 10.1016/j.apcatb.2020.119157
28	He D. ; Zhang C. ; Zeng G. ; Yang Y. ; Huang D. ; Wang L. ; Wang H. Appl. Catal. B 2019, 258, 117957. doi: 10.1016/j.apcatb.2019.117957
29	Li Y. ; Li X. ; Zhang H. ; Fan J. ; Xiang Q. J. Mater. Sci. Technol. 2020, 56, 69. doi: 10.1016/j.jmst.2020.03.033
30	Tang S. ; Zhu Y. ; Li H. ; Xu H. ; Yuan S. Int. J. Hydrog. Energy 2019, 44 (59), 30935. doi: 10.1016/j.ijhydene.2019.10.020
31	Dong G. ; Shibuya R. ; Akiba C. ; Saji S. ; Kondo T. ; Nakamura J. Science 2016, 351 (6271), 361. doi: 10.1126/science.aad0832
32	Liao J. ; Cui W. ; Li J. ; Sheng J. ; Wang H. ; Dong X. A. ; Chen P. ; Jiang G. ; Wang Z. ; Dong F. Chem. Eng. J. 2020, 379, 122282. doi: 10.1016/j.cej.2019.122282
33	Cao J. ; Pan C. ; Ding Y. ; Li W. ; Lv K. ; Tang H. J. Environ. Chem. Eng. 2019, 7 (2), 102984. doi: 10.1016/j.jece.2019.102984
34	Cao J. ; Nie W. ; Huang L. ; Ding Y. ; Lv K. ; Tang H. Appl. Catal. B 2019, 241, 18. doi: 10.1016/j.apcatb.2018.09.007
35	Huang J. ; Du J. ; Du H. ; Xu G. ; Yuan Y. Acta Phys. -Chim. Sin. 2020, 36 (7), 1905056.
	黄娟娟; 杜建梅; 杜海威; 徐更生; 袁玉鹏; 物理化学学报, 2020, 36 (7), 1905056. doi: 10.3866/PKU.WHXB201905056
36	Mo R. ; Li J. ; Tang Y. ; Li H. ; Zhong J. Appl. Surf. Sci. 2019, 476, 552. doi: 10.1016/j.apsusc.2019.01.085
37	Li H. ; Jin C. ; Wang Z. ; Liu Y. ; Wang P. ; Zheng Z. ; Whangbo M.-H. ; Kou L. ; Li Y. ; Dai Y. ; et al Chem. Eng. J. 2019, 369, 263. doi: 10.1016/j.cej.2019.03.095
38	Zhang J. ; Huang Y. ; Nie T. ; Wang R. ; He B. ; Han B. ; Wang H. ; Tian Y. ; Gong Y. Appl. Surf. Sci. 2020, 499, 143942. doi: 10.1016/j.apsusc.2019.143942
39	Wang H. ; Li M. ; Li H. ; Lu Q. ; Zhang Y. ; Yao S. Mater. Des. 2019, 162, 210. doi: 10.1016/j.matdes.2018.11.049
40	Zhou C. ; Zeng Z. ; Zeng G. ; Huang D. ; Xiao R. ; Cheng M. ; Zhang C. ; Xiong W. ; Lai C. ; Yang Y. ; et al J. Hazard. Mater. 2019, 380, 120815. doi: 10.1016/j.jhazmat.2019.120815
41	Zhang Y. ; Gao J. ; Chen Z. J. Colloid Interface Sci. 2019, 535, 331. doi: 10.1016/j.jcis.2018.10.012
42	Wu J. ; Li N. ; Fang H.-B. ; Li X. ; Zheng Y.-Z. ; Tao X. Chem. Eng. J. 2019, 358, 20. doi: 10.1016/j.cej.2018.09.208
43	Zhang X. ; Zhao R. ; Zhang N. ; Su Y. ; Liu Z. ; Gao R. ; Du C. Appl. Catal. B 2020, 263, 118316. doi: 10.1016/j.apcatb.2019.118316
44	Xie Y. ; Li Y. ; Huang Z. ; Zhang J. ; Jia X. ; Wang X.-S. ; Ye J. Appl. Catal. B 2020, 265, 118581. doi: 10.1016/j.apcatb.2019.118581
45	Ho W. ; Zhang Z. ; Lin W. ; Huang S. ; Zhang X. ; Wang X. ; Huang Y. ACS Appl. Mater. Interfaces 2015, 7 (9), 5497. doi: 10.1021/am509213x
46	Liang L. ; Shi L. ; Wang F. ; Yao L. ; Zhang Y. ; Qi W. Int. J. Hydrog. Energy 2019, 44 (31), 16315. doi: 10.1016/j.ijhydene.2019.05.001
47	Xue Y. ; Kong X. ; Guo Y. ; Liang Z. ; Cui H. ; Tian J. J. Materiomics 2020, 6 (1), 128. doi: 10.1016/j.jmat.2020.01.006
48	Wang Z. ; Huang Y. ; Chen M. ; Shi X. ; Zhang Y. ; Cao J. ; Ho W. ; Lee S. C. ACS Appl. Mater. Interfaces 2019, 11 (11), 10651. doi: 10.1021/acsami.8b21987
49	Guo S. ; Zhang H. ; Yang P. ; Chen Y. ; Yu X. ; Yu B. ; Zhao Y. ; Yang Z. ; Liu Z. Catal. Sci. Technol. 2019, 9 (10), 2485. doi: 10.1039/C8CY02509F
50	Shan X. ; Ge G. ; Zhao Z. ChemCatChem 2019, 11 (5), 1534. doi: 10.1002/cctc.201801803
51	Yang Z. ; Chu D. ; Jia G. ; Yao M. ; Liu B. Appl. Surf. Sci. 2020, 504, 144407. doi: 10.1016/j.apsusc.2019.144407
52	Tian Y. ; Zhou L. ; Zhu Q. ; Lei J. ; Wang L. ; Zhang J. ; Liu Y. Nanoscale 2019, 11 (43), 20638. doi: 10.1039/C9NR06802C
53	Liu M. ; Zhang D. ; Han J. ; Liu C. ; Ding Y. ; Wang Z. ; Wang A. Chem. Eng. J. 2020, 382, 123017. doi: 10.1016/j.cej.2019.123017
54	Liang X. ; Wang G. ; Dong X. ; Wang G. ; Ma H. ; Zhang X. ACS Appl. Nano Mater. 2019, 2 (1), 517. doi: 10.1021/acsanm.8b02089
55	Shen M. ; Zhang L. ; Wang M. ; Tian J. ; Jin X. ; Guo L. ; Wang L. ; Shi J. J. Mater. Chem. A 2019, 7 (4), 1556. doi: 10.1039/C8TA09302D
56	Jiang L. ; Li J. ; Wang K. ; Zhang G. ; Li Y. ; Wu X. Appl. Catal. B 2020, 260, 118181. doi: 10.1016/j.apcatb.2019.118181
57	Zhang Y. ; Di J. ; Ding P. ; Zhao J. ; Gu K. ; Chen X. ; Yan C. ; Yin S. ; Xia J. ; Li H. J. Colloid Interface Sci. 2019, 553, 530. doi: 10.1016/j.jcis.2019.06.012
58	Lei J. ; Chen B. ; Lv W. ; Zhou L. ; Wang L. ; Liu Y. ; Zhang J. ACS Sustain. Chem. Eng. 2019, 7 (19), 16467. doi: 10.1021/acssuschemeng.9b03678
59	Wang X. ; Wu L. ; Wang Z. ; Wu H. ; Zhou X. ; Ma H. ; Zhong H. ; Xing Z. ; Cai G. ; Jiang C. ; et al Sol. RRL 2019, 3 (4), 1800298. doi: 10.1002/solr.201800298
60	Sun H. ; Wei K. ; Wu D. ; Jiang Z. ; Zhao H. ; Wang T. ; Zhang Q. ; Wong P. K. Appl. Catal. B 2020, 264, 118480. doi: 10.1016/j.apcatb.2019.118480
61	Zhang Y. ; Wu L. ; Zhao X. ; Zhao Y. ; Tan H. ; Zhao X. ; Ma Y. ; Zhao Z. ; Song S. ; Wang Y. ; et al Adv. Energy Mater. 2018, 8 (25), 1801139. doi: 10.1002/aenm.201801139
62	Lin L. ; Yu Z. ; Wang X. Angew. Chem. Int. Ed. 2019, 58 (19), 6164. doi: 10.1002/anie.201809897
63	Wang Y. ; Rao L. ; Wang P. ; Guo Y. ; Shi Z. ; Guo X. ; Zhang L. Appl. Surf. Sci. 2020, 505, 144576. doi: 10.1016/j.apsusc.2019.144576
64	Zhou M. ; Dong G. ; Ma J. ; Dong F. ; Wang C. ; Sun J. Appl. Catal. B 2020, 273, 119007. doi: 10.1016/j.apcatb.2020.119007
65	Zhang H. ; Tang Y. ; Liu Z. ; Zhu Z. ; Tang X. ; Wang Y. Chem. Phys. Lett. 2020, 751, 137467. doi: 10.1016/j.cplett.2020.137467
66	Feng Q. J. Phys.: Condens. Matter 2020, 32 (44), 445602. doi: 10.1088/1361-648x/aba387
67	Panigrahi P. ; Kumar A. ; Karton A. ; Ahuja R. ; Hussain T. Int. J. Hydrog. Energy 2020, 45 (4), 3035. doi: 10.1016/j.ijhydene.2019.11.184
68	Wang X. ; Li D. ; Nan Z. Sep. Purif. Technol. 2019, 224, 152. doi: 10.1016/j.seppur.2019.04.088
69	Hu C. ; Wang M.-S. ; Chen C.-H. ; Chen Y.-R. ; Huang P.-H. ; Tung K.-L. J. Membr. Sci. 2019, 580, 1. doi: 10.1016/j.memsci.2019.03.012
70	Wang H. ; Bu Y. ; Wu G. ; Zou X. Dalton Trans. 2019, 48 (31), 11724. doi: 10.1039/C9DT01261C
71	Lv H. ; Huang Y. ; Koodali R. T. ; Liu G. ; Zeng Y. ; Meng Q. ; Yuan M. ACS Appl. Mater. Interfaces 2020, 12 (11), 12656. doi: 10.1021/acsami.9b19057
72	Chu K. ; Li Q.-Q. ; Liu Y.-P. ; Wang J. ; Cheng Y.-H. Appl. Catal. B 2020, 267, 118693. doi: 10.1016/j.apcatb.2020.118693
73	Li Z. ; Gu G. ; Hu S. ; Zou X. ; Wu G. Chin. J. Catal. 2019, 40 (8), 1178. doi: 10.1016/S1872-2067(19)63364-4
74	Hu X. ; Zhang W. ; Yong Y. ; Xu Y. ; Wang X. ; Yao X. Appl. Surf. Sci. 2020, 510, 145413. doi: 10.1016/j.apsusc.2020.145413
75	Iqbal W. ; Yang B. ; Zhao X. ; Rauf M. ; Mohamed I. M. A. ; Zhang J. ; Mao Y. Catal. Sci. Technol. 2020, 10 (2), 549. doi: 10.1039/C9CY02111F
76	Lin W. ; Lu K. ; Zhou S. ; Wang J. ; Mu F. ; Wang Y. ; Wu Y. ; Kong Y. Appl. Surf. Sci. 2019, 474, 194. doi: 10.1016/j.apsusc.2018.03.140
77	Zhou P. ; Meng X. ; Li L. ; Sun T. J. Alloys Compd. 2020, 827, 154259. doi: 10.1016/j.jallcom.2020.154259
78	Wang K. ; Fu J. ; Zheng Y. Appl. Catal. B 2019, 254, 270. doi: 10.1016/j.apcatb.2019.05.002
79	Chen D. ; Liu J. ; Jia Z. ; Fang J. ; Yang F. ; Tang Y. ; Wu K. ; Liu Z. ; Fang Z. J. Hazard. Mater. 2019, 361, 294. doi: 10.1016/j.jhazmat.2018.09.006
80	Yu Y. ; Wu S. ; Gu J. ; Liu R. ; Wang Z. ; Chen H. ; Jiang F. J. Hazard. Mater. 2020, 384, 121247. doi: 10.1016/j.jhazmat.2019.121247
81	Phang S. J. ; Tan L.-L. Catal. Sci. Technol. 2019, 9 (21), 5882. doi: 10.1039/C9CY01452G
82	Dong G. ; Zhao L. ; Wu X. ; Zhu M. ; Wang F. Appl. Catal. B 2019, 245, 459. doi: 10.1016/j.apcatb.2019.01.013
83	Zhao L. ; Dong G. ; Zhang L. ; Lu Y. ; Huang Y. ACS Appl. Mater. Interfaces 2019, 11 (10), 10042. doi: 10.1021/acsami.9b00111
84	Liu J. ; Xiong C. ; Jiang S. ; Wu X. ; Song S. Appl. Catal. B 2019, 249, 282. doi: 10.1016/j.apcatb.2019.03.014
85	Li X.-H. ; Chen W.-L. ; He P. ; Wang T. ; Liu D. ; Li Y.-W. ; Li Y.-G. ; Wang E.-B. Inorg. Chem. Front. 2019, 6 (11), 3315. doi: 10.1039/C9QI01093A
86	Vu N.-N. ; Nguyen C.-C. ; Kaliaguine S. ; Do T.-O. ChemSusChem 2019, 12 (1), 291. doi: 10.1002/cssc.201802394
87	Bellamkonda S. ; Shanmugam R. ; Gangavarapu R. R. J. Mater. Chem. A 2019, 7 (8), 3757. doi: 10.1039/C8TA10580D
88	Zhang Y. ; Thomas A. ; Antonietti M. ; Wang X. J. Am. Chem. Soc. 2009, 131 (1), 50. doi: 10.1021/ja808329f
89	Ge G. ; Zhao Z. Catal. Sci. Technol. 2019, 9 (2), 266. doi: 10.1039/C8CY02006J
90	Li W. ; Guo Z. ; Jiang L. ; Zhong L. ; Li G. ; Zhang J. ; Fan K. ; Gonzalez S. ; Jin K. ; Xu C. ; et al Chem. Sci. 2020, 11 (10), 2716. doi: 10.1039/C9SC05060D
91	Xing W. ; Tu W. ; Ou M. ; Wu S. ; Yin S. ; Wang H. ; Chen G. ; Xu R. ChemSusChem 2019, 12 (9), 2029. doi: 10.1002/cssc.201801431
92	Zhou P. ; Hou X. ; Chao Y. ; Yang W. ; Zhang W. ; Mu Z. ; Lai J. ; Lv F. ; Yang K. ; Liu Y. ; et al Chem. Sci. 2019, 10 (23), 5898. doi: 10.1039/C9SC00658C
93	Zhou P. ; Lv F. ; Li N. ; Zhang Y. ; Mu Z. ; Tang Y. ; Lai J. ; Chao Y. ; Luo M. ; Lin F. ; et al Nano Energy 2019, 56, 127. doi: 10.1016/j.nanoen.2018.11.033
94	Nguyen C.-C. ; Sakar M. ; Vu M.-H. ; Do T.-O. Ind. Eng. Chem. Res. 2019, 58 (9), 3698. doi: 10.1021/acs.iecr.8b05792
95	Huang Y. ; Wang P. ; Wang Z. ; Rao Y. ; Cao J.-J. ; Pu S. ; Ho W. ; Lee S. C. Appl. Catal. B 2019, 240, 122. doi: 10.1016/j.apcatb.2018.08.078
96	Huang Y. ; Zhang J. ; Wang Z. ; Liu Y. ; Wang P. ; Cao J.-j. ; Ho W. Sol. RRL 2020, 4 (8), 2000170. doi: 10.1002/solr.202000170
97	Cao J. ; Huang Y. Sci. Technol. Rev. 2016, 17 (34) doi: 10.3981/j.issn.1000-7857.2016
98	Huang, Y.; Wang, W.; Zhang, Y.; Cao, J.; Huang, R.; Wang, X. Chapter 10—Synthesis and Applications of Nanomaterials with High Photocatalytic Activity on Air Purification. In Novel Nanomaterials for Biomedical, Environmental and Energy Applications; Wang, X., Chen, X., Eds.; Elsevier: Amsterdam, Netherlands, 2019; pp. 299-325.

[1]	陈轼逸, 付家龙, 裘建平, 常国菊, 郝仕油. 废弃医用口罩衍生的碳量子点增强BiOBr/g-C₃N₄ S型异质结光催化降解聚对苯二甲酸乙二醇酯(PET)[J]. 物理化学学报, 2026, 42(1): 100135 - .
[2]	黄火帅, 韦之栋, 严嘉玮, 池家晟, 苏千翔, 陈铭夏, 江治, 孙洋洲, 上官文峰. 揭示Zn_xCd_1−xS固溶体光催化析氢中的直接-间接带隙跃迁机制[J]. 物理化学学报, 2026, 42(1): 100141 - .
[3]	赵呈孝, 李昭霖, 吴东方, 杨小飞. SBA-15模板化共价三嗪框架增强光催化产氢[J]. 物理化学学报, 2026, 42(1): 100149 - .
[4]	陈芸, 邓代洁, 徐丽, 朱兴旺, 李赫楠, 孙成明. 共价键调控电荷转移以实现自供能电化学传感平台对重金属离子的灵敏分析[J]. 物理化学学报, 2026, 42(1): 100144 - .
[5]	韦梦兰, 欧晓霞, 王艺濛, 张梦圆, 滕飞, 王凯旋. S型异质结g-C₃N₄/Bi₂WO₆高效降解左氧氟沙星：性能、机理及降解路径[J]. 物理化学学报, 2025, 41(9): 100105 - .
[6]	李静萍, 严素定, 吴佳曦, 程强, 王楷. LiFePO₄改善无机/有机S型光催化剂的过氧化氢光合作用[J]. 物理化学学报, 2025, 41(9): 100104 - .
[7]	吴琦, 王长华, 李莹莹, 张昕彤. 增强g-C₃N₄@BN范德华异质结界面上的三重态电子转移增强光催化合成H₂O₂[J]. 物理化学学报, 2025, 41(9): 100107 - .
[8]	张凤英, 梅杨林, 蒋毓蔓, 郑申申, 郑凯波, 周莹. 瞬态吸收光谱在太阳能转化利用中的研究进展[J]. 物理化学学报, 2025, 41(9): 100118 - .
[9]	王文龙, 郝文韬, 何浪, 乔佳, 李宁, 陈朝秋, 覃勇. 碳量子点/TiO₂ S型异质结的能带和吸附工程促进光催化CO₂甲烷化[J]. 物理化学学报, 2025, 41(9): 100116 - .
[10]	袁乐汪, 彭垚垚, 管宗杰, 方煜. 二维共价有机框架作为光催化剂在有机合成中的研究进展[J]. 物理化学学报, 2025, 41(8): 100086 - .
[11]	蔡家杰, 程畅, 刘博文, 张建军, 姜传佳, 程蓓. CdS/DBTSO-BDTO S型异质结光催化制氢及其电荷转移动力学[J]. 物理化学学报, 2025, 41(8): 100084 - .
[12]	王玉, 石海洋, 陈子涵, 陈峰, 王苹, 王雪飞. 具有富电子Pt^δ−壳层的空心AgPt@Pt核壳催化剂：提升光催化H₂O₂生成选择性与活性[J]. 物理化学学报, 2025, 41(7): 100081 - .
[13]	刘方璇, 刘子妍, 周国伟, 高婷婷, 刘文宇, 孙彬. 中空结构光催化剂[J]. 物理化学学报, 2025, 41(7): 100071 - .
[14]	罗雅丹, 郑浩, 李鑫, 李锋民, 唐华, 佘希林. 调节O, S共掺杂C₃N₄中的活性氧生成以促进光催化降解微塑料[J]. 物理化学学报, 2025, 41(6): 100052 - .
[15]	宋相海, 刘晓颖, 任智祥, 刘想, 汪梅, 吴元锋, 周伟强, 朱志, 霍鹏伟. 氮掺杂显著提升BiOBr光催化还原CO₂性能研究[J]. 物理化学学报, 2025, 41(6): 100055 - .

缺陷工程调控石墨相氮化碳及其光催化空气净化应用进展

Defect Engineering in Two-Dimensional Graphitic Carbon Nitride and Application to Photocatalytic Air Purification

RichHTML

PDF

赞

可视化

摘要/Abstract

引用本文

使用本文

图/表 7

参考文献 98

相关文章 15

Metrics

推荐阅读 0