多重共振TADF分子的设计策略

doi:10.3866/PKU.WHXB202309042

物理化学学报 >> 2025, Vol. 41 >> Issue (1): 100006.doi: 10.3866/PKU.WHXB202309042

所属专题：新型光电功能材料

多重共振TADF分子的设计策略

张泽华, 于海涛*(), 祁彦宇*()

河北师范大学化学与材料科学学院, 河北省有机功能分子重点实验室, 石家庄 050024

收稿日期:2023-09-27 修回日期:2023-11-07 录用日期:2023-11-09 发布日期:2023-12-25
通讯作者: Email: haitaoyu@hebtu.edu.cn (于海涛)hbsdqyy@hebtu.edu.cn (祁彦宇)
基金资助:
国家自然科学基金(21971054); 国家自然科学基金(22002092); 河北省省级科技计划(B2022205014); 河北省省级科技计划(22567622H); 河北省教育厅科学研究项目(BJK2023014); 河北省博士后科研择优资助项目(B2023005008); 石家庄市科学技术研究与发展计划项目(241791047A); 河北师范大学科技类基金(L2022B12); 河北师范大学科技类基金(L2023T01)

Design Strategy for Thermally Activated Delayed Fluorescence Materials with Multiple Resonance Effect

Zehua Zhang, Haitao Yu*(), Yanyu Qi*()

Hebei Key Laboratory of Organic Functional Molecules, College of Chemistry and Materials Science, Hebei Normal University, Shijiazhuang 050024, China

Received:2023-09-27 Revised:2023-11-07 Accepted:2023-11-09 Published:2023-12-25
Contact: Email: haitaoyu@hebtu.edu.cn (Haitao Yu)hbsdqyy@hebtu.edu.cn (Yanyu Qi)
Supported by:
the National Natural Science Foundation of China(21971054); the National Natural Science Foundation of China(22002092); S&T Program of Hebei(B2022205014); S&T Program of Hebei(22567622H); Science Research Project of Hebei Education Department(BJK2023014); Postdoctoral Research Projects Merit-based Funding Programs of Hebei Province(B2023005008); Shijiazhuang Science and Technology Research and Development Program(241791047A); the Science Foundation of Hebei Normal University(L2022B12); the Science Foundation of Hebei Normal University(L2023T01)

摘要/Abstract

摘要：

自首例多重共振热激活延迟荧光(Multiple resonance thermal activation delayed fluorescence，MR-TADF)分子报道至今，其表现出的窄带发射、高发光量子效率等特性在有机电子学，尤其是有机发光二极管(Organic light-emitting diode，OLED)等领域引发了持续的研究热度，迅速成为重点研究对象，并涌现出了众多性能出色的分子和高性能器件。以MR-TADF分子为发光层的器件不断刷新人们对OLED的认知，其中一些采用了超荧光技术所制备的器件性能代表了当今某些光色领域OLED性能的最高值。随着人们对超高分辨率显示器需求的与日俱增，国际电信联盟(ITU)宣布了下一代色域标准，即BT.2020。此标准建立了最宽的显示色域标准，要求单色的原色波长为467、532和630 nm，这个色域非常宽。同时，在如此之宽的色域上实现高分辨率的显示，对器件基元色纯度的要求达到了可谓史无前例的严格。因此，它为显示技术树立了一个具有极大挑战难度的色纯度目标。鉴于以往传统荧光材料难以担当此攻关重任，故而BT.2020的出现给予了MR-TADF分子新的发展机遇，并在很大程度上使得该领域愈发火热起来。近年来，随着大量的研究与实践，MR-TADF分子家族得到了飞速的发展，然而大家讨论和归纳的重点基本都集中在领域整体的发展方面，专门针对分子设计策略所展开的讨论和总结依旧较少，不足以为刚涉足该领域的科研人员提供足够的参考。因此，本文从X-π-X原则，快反向系间窜越过程，窄带发射与高振子强度等方面，阐述了近三年来所报道的MR-TADF分子的设计思路，并对未来可能的设计方向进行了展望，例如将一些不同于传统MR-TADF分子的结构引入这一领域。最后，对今后MR-TADF领域的发展和产业化提出建议。

关键词: 多重共振热激活延迟荧光, 有机发光二极管, 有机光电功能材料, 电致发光, 荧光

Abstract:

Since the initial report on multiple resonance thermally activated delayed fluorescence (MR-TADF) molecules, their narrow band emissions, high quantum yields and other characteristics have consistently fueled research interest in the realm of organic electronics, particularly organic light emitting diodes (OLED). These molecules swiftly ascended to the forefront of research, serving as a pivotal focus, giving rise to numerous high-performance devices and meticulously crafted molecules. Devices featuring MR-TADF molecules as the luminescent core continually redefine our comprehension of OLED, with some employing hyperfluorescence technology attaining peak performance in specific photochromic domains today. Presently, with the escalating demand for ultra-high-resolution displays, the international telecommunication union (ITU) has unveiled the next generation color gamut standard, BT.2020. This standard delineates the broadest display color gamut, mandating monochromatic primary color wavelengths of 467, 532, and 630 nm, constituting an exceptionally extensive color gamut. Simultaneously, achieving high-resolution displays with such an expansive color gamut imposes unprecedentedly stringent requirements on the color purity of device elements. Consequently, it imposes a formidable color purity target for display technology. In the past, traditional fluorescent materials struggled to meet these demands. The advent of BT.2020, however, has presented new opportunities for the advancement of MR-TADF molecules, leading to a surge in popularity in this field. In recent years, with copious research and practical applications, the MR-TADF molecular family has undergone rapid evolution. Nevertheless, discussions and summaries primarily centered on the field's development, with limited focus on molecular design strategies. This deficiency hinders adequate reference for researchers entering the field. Consequently, this article expounds upon the design principles of select MR-TADF molecules reported in the past three years. It delves into aspects such as the X-π-X principle, fast reverse intersystem crossing processes, narrow-band emission, and high oscillator strength. Additionally, it posits future design directions, including the incorporation of non-traditional structures into the MR-TADF domain. Finally, the article offers suggestions for the prospective development and industrialization of the MR-TADF field.

Key words: Multiple resonance thermal activateddelayed fluorescence, Organic light-emitting diode, Organic optoelectronic functional materials, Electroluminescence, Fluorescence

张泽华, 于海涛, 祁彦宇. 多重共振TADF分子的设计策略[J]. 物理化学学报, 2025, 41(1), 100006. doi: 10.3866/PKU.WHXB202309042

Zehua Zhang, Haitao Yu, Yanyu Qi. Design Strategy for Thermally Activated Delayed Fluorescence Materials with Multiple Resonance Effect[J]. Acta Phys. -Chim. Sin. 2025, 41(1), 100006. doi: 10.3866/PKU.WHXB202309042

链接本文: https://www.whxb.pku.edu.cn/CN/10.3866/PKU.WHXB202309042

https://www.whxb.pku.edu.cn/CN/Y2025/V41/I1/100006

图/表 11

图1

图2

图3

图4

图5

图6

图7

图8

图9

图10

表1

Molecules	λ_abs (nm)	λ_em (nm)	ΔE_ST (eV)	PLQY (%)	FWHM (nm)	f	Ref.
Cz–B	458	477	0.14	98	25	–	25, 26
γ-Cb–B	443	460	0.14	83	23	–	25, 26
TCz–B	491	512	0.13	89	27	–	25, 26
DACz–B	540	572	0.13	87	34	–	25, 26
1	–	–	0.21	–	–	0.013	27
2	–	–	0.15	–	–	0.026	27
3	–	–	0.29	–	–	0.016	27
4	–	–	0.34	–	–	0.016	27
5	–	–	0.34	–	–	0.050	27
TOAT	408	–	0.34	–	–	0.015	28
mBDPA-TOAT	571	599	0.23	73	37	–	31
pBDPA-TOAT	563	603	0.23	57	48	–	31
DMAC-TOAT	505	656	0.08	15	105	–	31
3DPA-DiKTa	554	597	0.20	59	47	–	32
3TPA-DiKTa	494	537	0.13	44	54	–	32
BBCz-DB	453	466	0.09	93	16	–	33
BBCz-SB	468	489	0.13	98	23	–	33
BBCz-G	487	517	0.16	90	34	–	33
BBCz-Y	505	549	0.17	85	42	–	33
BBCz-R	597	615	0.07	89	21	–	33
CN-BCz-BN	–	496	–	–	21	–	34
CNCz-BNCz	–	581	0.18	90	42	–	34
m-Cz-BNCz	489	519	0.08	97	38	–	35
p-Cz-BNCz	–	477	–	–	22	0.3977	35
2CN-BN	–	–	–	–	–	0.3482	36
4CN-BN	–	–	–	–	–	0.3273	36
R-BN	629	662	0.18	100	38	0.2822	37
R-TBN	651	692	0.16	100	38	–	37
Cz-Ph-DiKTa	–	–	0.22	–	47	0.254	38
DMAC-DiKTa	–	–	0.21	–	89	0.23	38
TMCz-DiKTa	–	–	0.23	–	78	0.228	38
3Cz-DiKTa	–	–	0.11	–	53	0.212	38
3DMCz-DiKTa	–	–	0.01	–	110	0.21	38
3DMAC-DiKTa	–	–	0.01	–	116	0.02	38
Cz-DiKTa	–	–	0.2	90	54	0.215	38
NBNP	473	500	0.09	93	29	0.2302	39
NBO	466	487	0.12	92	27	0.2736	39
BOQAO	–	474	0.22	–	28	–	40
BNO1	582	605	0.25	96	32	0.3133	41
BNO2	588	609	0.27	95	32	0.3423	41
BNO3	595	616	0.26	96	33	0.3121	41
DPMX-CzDABNA	461	471	0.11	–	22	0.3	43
mBP-DABNA-Me	445	464	0.12	–	–	–	44
2F-BN	–	494	0.16	95.4	24	0.4113	45
3F-BN	–	499	0.08	90.2	24	0.3951	45
4F-BN	–	496	0.11	98.7	25	0.3937	45
BN-Y	534	567	0.12	95	34	0.382	47
BN-R	581	624	0.11	94	46	0.233	47
1-X	–	–	–	–	–	–	48
2-X	–	–	–	–	–	–	48
3-X	–	–	–	–	–	–	48
1c-X	–	–	–	–	–	–	49, 50
1d-X	–	–	–	–	–	–	49, 50
1e-X	–	–	–	–	–	–	49, 50
1f–X	–	–	–	–	–	–	49, 50
tDIDCz	241	393	0.44	60	20	–	51
BisICz	–	432	0.31	81	27	–	51
tBisICz	–	442	0.29	95	21	–	51
tPBisICz	–	448	0.27	91	21	–	51
DilCz	307	441	0.26	70	17	–	53
pBP–DABNA-Me	–	462	0.176	98	22	–	54
SBON	442	463	0.16	74	24	–	55
SBSN	460	489	0.10	76	27	–	55
DBON	491	505	0.13	98	20	–	55
DBSN	520	553	0.13	98	28	–	55
BSS	431	457	0.15	90	27	–	56
BSS-Ac	434	456	0.04	90	105	–	57
BSS-SpAc	433	456	0.07	89	101	–	57
BSS-PA	432	454	0.13	66	35	–	57
BSS-Cz	432	455	0.14	86	28	–	57
CzBO	–	445	0.15	98	26	–	58
CzBS	–	471	0.11	99	28	–	58
CzBSe	–	477	0.12	98	33	–	58
Cz-PTZ-BN	475	510	0.11	37	91	0.4079	59
2Cz-PTZ-BN	468	505	0.09	38	96	0.4698	59
BN-Se	467	502	0.08	99	42	0.2619	60
DtCzB-DPTRZ	507	521	0.18	94	24	0.2283	61
DtCzB-TPTRZ	477	501	0.11	97	27	0.2170	61
DtCzB-PPm	474	499	0.11	96	25	0.3407	61
DtCzB-CNPm	481	515	0.15	93	36	0.1900	61
BN1	439	454	0.12	–	18	–	62
BN2	450	464	0.09	–	15	–	62
BN3	444	456	0.03	–	17	–	62
CzAO	415	431	0.40	42	36	–	63
MQAO	405	447	0.31	72	61	–	63
QPXO	413	485	0.29	75	76	–	63
QPO	410	501	0.27	33	86	–	63
DtBuPhCzB	481	496	0.09	97	21	0.5693	65
DtBuCzB	467	481	0.13	91	22	0.4098	65
CzBNO	427	443	0.21	96	23	0.2611	66
DMAcBNO	434	462	0.23	99	34	0.2407	66
DPAcBNO	436	462	0.19	98	33	0.2577	66

表1

参考文献 66

1	Tang C. W. ; VanSlyke S. A. Appl. Phys. Lett. 1987, 51, 913. doi: 10.1063/1.98799
2	Wang L. X. ; Mei Q. B. ; Yan F. ; Tian B. ; Weng J. N. ; Zhang B. ; Huang W. Acta Phys. -Chim Sin. 2012, 28, 1556.
	王玲霞; 梅群波; 颜芳; 田波; 翁洁娜; 张彬; 黄维. 物理化学学报, 2012, 28, 1556. doi: 10.3866/PKU.WHXB201205043
3	Lan L. H. ; Tao H. ; Li M. L. ; Gao D. Y. ; Zou J. H. ; Xu M. ; Wang L. ; Peng J. B. Acta Phys. -Chim Sin. 2017, 33, 1548.
	蓝露华; 陶洪; 李美灵; 高栋雨; 邹建华; 徐苗; 王磊; 彭俊彪. 物理化学学报, 2017, 33, 1548. doi: 10.3866/PKU.WHXB201704283
4	Kim K. H. ; Moon C. K. ; Lee J. H. ; Kim S. Y. ; Kim J. J. Adv. Mater. 2014, 26, 3844. doi: 10.1002/adma.201305733
5	Cocchi M. ; Virgili D. ; Fattori V. ; Rochester D. L. ; Williams J. A. G. Adv. Funct. Mater. 2007, 17, 285. doi: 10.1002/adfm.200600167
6	Chan A. K. W. ; Ng M. ; Wong Y. C. ; Chan M. Y. ; Wong W. T. ; Yam V. W. W. J. Am. Chem. Soc. 2017, 139, 10750. doi: 10.1021/jacs.7b04952
7	Tang M. C. ; Lee C. H. ; Ng M. ; Wong Y. C. ; Chan M. Y. ; Yam V. W. W. Angew. Chem. Int. Ed. 2018, 57, 5463. doi: 10.1002/anie.201711846
8	Matsuo K. ; Yasuda T. Chem. Commun. 2017, 53, 8723. doi: 10.1039/c7cc04875k
9	Li J. ; Nakagawa T. ; MacDonald J. ; Zhang Q. ; Nomura H. ; Miyazaki H. ; Adachi C. Adv. Mater. 2013, 25, 3319. doi: 10.1002/adma.201300575
10	Wang S. ; Yan X. ; Cheng Z. ; Zhang H. ; Liu Y. ; Wang Y. Angew. Chem. Int. Ed. 2015, 54, 13068. doi: 10.1002/anie.201506687
11	Rajamalli P. ; Senthilkumar N. ; Gandeepan P. ; Huang P.-Y. ; Huang M.-J. ; Ren-Wu C.-Z. ; Yang C.-Y. ; Chiu M.-J. ; Chu L.-K. ; Lin H.-W. ; et al J. Am. Chem. Soc. 2016, 138, 628. doi: 10.1021/jacs.5b10950
12	Zhang Y. L. ; Ran Q. ; Wang Q. ; Liu Y. ; Hänisch C. ; Reineke S. ; Fan J. ; Liao L. S. Adv. Mater. 2019, 31, 1902368. doi: 10.1002/adma.201902368
13	Jayakumar J. ; Wu T. L. ; Huang M. J. ; Huang P. Y. ; Chou T. Y. ; Lin H. W. ; Cheng C. H. ACS Appl. Mater. Interfaces 2019, 11, 21042. doi: 10.1021/acsami.9b04664
14	Hall D. ; Suresh S. M. ; dos Santos P. L. ; Duda E. ; Bagnich S. ; Pershin A. ; Rajamalli P. ; Cordes D. B. ; Slawin A. M. Z. ; Beljonne D. ; et al Adv. Opt. Mater. 2020, 8, 1901627. doi: 10.1002/adom.201901627
15	Hsieh C. M. ; Wu T. L. ; Jayakumar J. ; Wang Y. C. ; Ko C. L. ; Hung W. Y. ; Lin T. C. ; Wu H. H. ; Lin K. H. ; Lin C. H. ; et al ACS Appl. Mater. Interfaces 2020, 12, 23199. doi: 10.1021/acsami.0c03711
16	Liu H. ; Liu Z. W. ; Li G. G. ; Huang H. N. ; Zhou C. J. ; Wang Z. M. ; Yang C. L. Angew. Chem. Int. Ed. 2021, 60, 12376. doi: 10.1002/anie.202103187
17	Ni F. ; Huang C. W. ; Tang Y. K. ; Chen Z. X. ; Wu Y. X. ; Xia S. P. ; Cao X. S. ; Hsu J. H. ; Lee W. K. ; Zheng K. L. ; et al Mater. Horiz. 2021, 8, 547. doi: 10.1039/d0mh01521k
18	Wu C. ; Liu W. Q. ; Li K. ; Cheng G. ; Xiong J. F. ; Teng T. ; Che C. M. ; Yang C. L. Angew. Chem. Int. Ed. 2021, 60, 3994. doi: 10.1002/anie.202013051
19	Huang B. ; Dai Y. ; Ban X. X. ; Jiang W. ; Zhang Z. H. ; Sun K. Y. ; Lin B. P. ; Sun Y. M. Acta Phys. -Chim Sin. 2015, 31, 1621.
	黄斌; 代钰; 班鑫鑫; 蒋伟; 张兆杭; 孙开涌; 林保平; 孙岳明. 物理化学学报, 2015, 31, 1621. doi: 10.3866/PKU.WHXB201506121
20	Endo A. ; Sato K. ; Yoshimura K. ; Kai T. ; Kawada A. ; Miyazaki H. ; Adachi C. Appl. Phys. Lett. 2011, 98, 083302. doi: 10.1063/1.3626856
21	Hatakeyama T. ; Shiren K. ; Nakajima K. ; Nomura S. ; Nakatsuka S. ; Kinoshita K. ; Ni J. ; Ono Y. ; Ikuta T. Adv. Mater. 2016, 28, 2777. doi: 10.1002/adma.201505491
22	Hu Y. X. ; Huang M. L. ; Liu H. ; Miao J. S. ; Yang C. L. Angew. Chem. Int. Ed 2023, 62, e202312666. doi: 10.1002/anie.202312666
23	Wei J. B. ; Zhang C. ; Zhang D. D. ; Zhang Y.W. ; Liu Z. Y. ; Li Z. Q. ; Yu G. ; Duan L. Angew. Chem. Int. Ed. 2021, 60, 12269. doi: 10.1002/ange.202017328
24	Jing Y. Y. ; Li N. Q. ; Cao X. S. ; Wu H. ; Miao J. S. ; Chen Z. X. ; Huang M. L. ; Wang X. Z. ; Hu Y. X. ; Zou Y. ; et al Sci. Adv. 2023, 9, eadh8296. doi: 10.1126/sciadv.adh8296
25	Qi Y. Y. ; Ning W. M. ; Zou Y. ; Cao X. S. ; Gong S. L. ; Yang C. L. Adv. Funct. Mater. 2021, 31, 2102017. doi: 10.1002/adfm.202102017
26	Yang M. ; Shikita S. ; Min H. ; Park I. S. ; Shibata H. ; Amanokura N. ; Yasuda T. Angew. Chem. Int. Ed. 2021, 60, 23142. doi: 10.1002/anie.202109335
27	Tsuchiya Y. ; Ishikawa Y. ; Lee S. H. ; Chen X. K. ; Brédas J. L. ; Nakanotani H. ; Adachi C. Adv. Opt. Mater. 2021, 9, 2002174. doi: 10.1002/adom.202002174
28	Yu Y. J. ; Feng Z. Q. ; Meng X. Y. ; Chen L. ; Liu F. M. ; Yang S. Y. ; Zhou D. Y. ; Liao L. S. ; Jiang Z. Q. Angew. Chem. Int. Ed. 2023, 62, e202310047. doi: 10.1002/anie.202310047
29	Stavrou K. ; Danos A. ; Hama T. ; Hatakeyama T. ; Monkman A. ACS Appl. Mater. Interfaces 2021, 13, 8643. doi: 10.1021/acsami.0c20619
30	Hamzehpoor E. ; Perepichka D. F. Angew. Chem. Int. Ed. 2020, 59, 9977. doi: 10.1002/anie.201913393
31	Fan X. C. ; Wang K. ; Shi Y. Z. ; Chen J. X. ; Huang F. ; Wang H. ; Hu Y. N. ; Tsuchiya Y. ; Ou X. M. ; Yu J. ; et al Adv. Opt. Mater. 2022, 10, 2101789. doi: 10.1002/adom.202101789
32	Wu S. ; Gupta A. K. ; Yoshida K. ; Gong J. Y. ; Hall D. ; Cordes D. B. ; Slawin A. M. Z. ; Samuel I. D. W. ; Colman E. Z. Angew. Chem. Int. Ed. 2022, 61, e202213697. doi: 10.1002/anie.202213697
33	Yang M. L. ; Park I. S. ; Yasuda T. J. Am. Chem. Soc 2020, 142, 19468. doi: 10.1021/jacs.0c10081
34	Liu Y. ; Xiao X. ; Ran Y. ; Bin Z. Y. ; You J. S. Chem. Sci. 2021, 12, 9408. doi: 10.1039/d1sc02042k
35	Xu Y. C. ; Li C. L. ; Li Z. Q. ; Wang Q. Y. ; Cai X. L. ; Wei J. B. ; Wang Y. Angew. Chem. Int. Ed. 2020, 59, 17442. doi: 10.1002/anie.202007210
36	Xu Y. C. ; Wang Q. Y. ; Cai X. L. ; Li C. L. ; Wang Y. Adv. Mater. 2021, 33, 2100652. doi: 10.1002/adma.202100652
37	Zhang Y. W. ; Zhang D. D. ; Huang T. Y. ; Gillett A. J. ; Liu Y. ; Hu D. P. ; Cui L. S. ; Bin Z. Y. ; Li G. M. ; Wei J. B. ; et al Angew. Chem. Int. Ed. 2021, 60, 20498. doi: 10.1002/anie.202107848
38	Wu S. ; Li W. ; Yoshida K. ; Hall D. ; Suresh S. M. ; Sayner T. ; Gong J. ; Beljonne D. ; Olivier Y. ; Samuelb I. D. W. ; et al ACS Appl. Mater. Interfaces 2022, 14, 22341. doi: 10.1021/acsami.2c02756
39	Luo X. F. ; Ni H. X. ; Ma H. L. ; Qu Z. Z. ; Wang J. ; Zheng Y. X. ; Zuo J. L. Adv. Opt. Mater. 2022, 10, 2102513. doi: 10.1002/adom.202102513
40	Yu Y. J. ; Zou S. N. ; Peng C. C. ; Feng Z. Q. ; Qu Y. K. ; Yang S. Y. ; Jiang Z. Q. ; Liao L. S. J. Mater. Chem. C 2022, 10, 4941. doi: 10.1039/d1tc05711a
41	Zou Y. ; Hu J. H. ; Yu M. X. ; Miao J. S. ; Xie Z. Y. ; Qiu Y. T. ; Cao X. S. ; Yang C. L. Adv. Mater. 2022, 34, 2201442. doi: 10.1002/adma.202201442
42	Qiu Y. T. ; Xia H. ; Miao J. S. ; Huang Z. Y. ; Li N. Q. ; Cao X. S. ; Han J. M. ; Zhou C. J. ; Zhong C. ; Yang C. L. ACS Appl. Mater. Interfaces 2021, 13, 59035. doi: 10.1021/acsami.1c18704
43	Hu Y. N. ; Fan X. C. ; Huang F. ; Shi Y. Z. ; Wang H. ; Cheng Y. C. ; Chen M. Y. ; Wang K. ; Yu J. ; Zhang X. H. Adv. Opt. Mater. 2022, 11, 2202267. doi: 10.1002/adom.202202267
44	Cheon H. J. ; Shin Y. S. ; Park N. H. ; Lee J. H. ; Kim Y. H. Small 2022, 18, 2107574. doi: 10.1002/smll.202107574
45	Zhang Y. W. ; Zhang D. D. ; Wei J. B. ; Liu Z. Y. ; Lu Y. ; Duan L. Angew. Chem. Int. Ed. 2019, 131, 17068. doi: 10.1002/ange.201911266
46	Lee Y. T. ; Chan C. Y. ; Tanaka M. ; Mamada M. ; Balijapalli U. ; Tsuchiya Y. ; Nakanotani H. ; Hatakeyama T. ; Adachi C. Adv. Electron. Mater. 2021, 7, 2001090. doi: 10.1002/aelm.202001090
47	Cai X. L. ; Xu Y. C. ; Pan Y. ; Li L. J. ; Pu Y. X. ; Zhuang X. M. ; Li C. L. ; Wang Y. Angew. Chem. Int. Ed. 2023, 62, e202216473. doi: 10.1002/anie.202216473
48	Pratik S. M. ; Coropceanu V. ; Brédas J. L. ACS Mater. Lett. 2022, 4, 440. doi: 10.1021/acsmaterialslett.1c00809
49	Oda S. ; Kawakami B. ; Kawasumi R. ; Okita R. ; Hatakeyama T. Org. Lett. 2019, 21, 9311. doi: 10.1021/acs.orglett.9b03342
50	Pratik S. M. ; Coropceanu V. ; Brédas J. L. Chem. Mater. 2022, 34, 8022. doi: 10.1021/acs.chemmater.2c01952
51	Lee H. L. ; Chung W. J. ; Lee J. Y. Small 2020, 16, 1907569. doi: 10.1002/smll.201907569
52	Patil V. V. ; Lee H. L. ; Kim I. ; Lee K. H. ; Chung W. J. ; Kim J. ; Park S. ; Choi H. ; Son W. J. ; Jeon S. O. ; et al Adv. Sci. 2021, 8, 2101137. doi: 10.1002/advs.202101137
53	Hall D. ; Stavrou K. ; Duda E. ; Danos A. ; Bagnich S. ; Warriner S. ; Slawin A. M. Z. ; Beljonne D. ; Köhler A. ; Monkman A. ; et al Mater. Horiz. 2022, 9, 1068. doi: 10.1039/d1mh01383a
54	Cheon H. J. ; Woo S. J. ; Baek S. H. ; Lee J. H. ; Kim Y. H. Adv. Mater. 2022, 34, 2207416. doi: 10.1002/adma.202207416
55	Luo X. F. ; Ni H. X. ; Lv A.Q. ; Yao X. K. ; Ma H. L. ; Zheng Y. X. Adv. Opt. Mater. 2022, 10, 2200504. doi: 10.1002/adom.202200504
56	Chen F. ; Zhao L. ; Wang X. ; Yang Q. ; Li W. ; Tian H. ; Shao S. ; Wang L. ; Jing X. ; Wang F. Sci. China Chem. 2021, 64, 547. doi: 10.1007/s11426-020-9944-1
57	Chang Y. ; Wu Y. ; Wang X. ; Li W. ; Yang Q. ; Wang S. ; Shao S. ; Wang L. Chem. Eng. J. 2023, 451, 138545. doi: 10.1016/j.cej.2022.138545
58	Park I. S. ; Min H. ; Yasuda T. Angew. Chem. Int. Ed. 2022, 61, e202205684. doi: 10.1002/anie.202205684
59	Liu F. T. ; Cheng Z. ; Jiang Y. X. ; Gao L. ; Liu H. X. ; Liu H. ; Feng Z. J. ; Lu P ; Yang W. S. Angew. Chem. Int. Ed. 2022, 61, e202116927. doi: 10.1002/anie.202116927
60	Cao X. S. ; Pan K. ; Miao J. S. ; Lv X. L. ; Huang Z. Y. ; Ni F. ; Yin X. J. ; Wei Y. X. ; Yang C. L. J. Am. Chem. Soc. 2022, 144, 22976. doi: 10.1021/jacs.2c09543
61	Xu Y. C. ; Li C. L. ; Li Z. Q. ; Wang J. X. ; Xue J. X. ; Wang Q. Y. ; Cai X. L. ; Wang Y. CCS Chem. 2022, 4, 2065. doi: 10.31635/ccschem.021.202101033
62	Lv X. L. ; Miao J. S. ; Liu M. H. ; Peng Q. ; Zhong C. ; Hu Y. X. ; Cao X. S. ; Wu H. ; Yang Y. Y. ; Zhou C. J. ; et al Angew. Chem. Int. Ed. 2022, 61, e202201588. doi: 10.1002/anie.202201588
63	Huang J. W. ; Hsu Y. C. ; Wu X. ; Wang S. ; Gan X. Q. ; Zheng W. Q. ; Zhang H. ; Gong Y. Z. ; Hung W. Y. ; Chou P. T. ; et al J. Mater. Chem. C 2022, 10, 7866. doi: 10.1039/D1TC06165H
64	Hua T. ; Zhan L. S. ; Li N. Q. ; Huang Z. Y. ; Cao X. S. ; Xiao Z. Q. ; Gong S. L. ; Zhou C. J. ; Zhong C. ; Yang C. L. Chem. Eng. J. 2021, 426, 131169. doi: 10.1016/j.cej.2021.131169
65	Xu Y. C. ; Cheng Z. ; Li Z. Q. ; Liang B. Y. ; Wang J. X. ; Wei J. B. ; Zhang Z. L. ; Wang Y. Adv. Opt. Mater. 2020, 8, 1902142. doi: 10.1002/adom.201902142
66	Han J. M. ; Huang Z. Y. ; Lv X. L. ; Miao J. S. ; Qiu Y. T. ; Cao X. S. ; Yang C. L. Adv. Opt. Mater. 2022, 10, 2102092. doi: 10.1002/adom.202102092

[1]	姜羊林, 陈明卿, 梁民, 尧奕歌, 张燕, 王鹏, 张建平. 4′-N,N-二乙氨基-3-羟基苯并黄酮激发态分子内质子转移机制的溶剂极性效应——实验和理论研究[J]. 物理化学学报, 2025, 41(2): 100012 - .
[2]	常建桥, 许慧敏, 谢文菁, 张洋, 祁玲, 范楼珍, 李勇. 用于高灵敏快速核酸检测的荧光碳点[J]. 物理化学学报, 2023, 39(12): 2301034 - .
[3]	王晨璐, 宿素玲, 任宁, 张建军. 卤代芳香族羧酸与含氮配体合成镧系配合物的结构、热化学和荧光性质[J]. 物理化学学报, 2023, 39(1): 2206035 -0 .
[4]	樊晔, 曹崇梅, 方云, 夏咏梅. 自交联共轭亚油酸囊泡基荧光纳米点的构筑及其荧光特性[J]. 物理化学学报, 2022, 38(3): 2002032 - .
[5]	常明凯, 胡娜, 李遥, 鲜东帆, 周万强, 王静一, 时燕琳, 刘春立. Eu(Ⅲ)在蒙脱石上的吸附及碳酸根和磷酸根对其吸附的影响[J]. 物理化学学报, 2022, 38(3): 2003031 - .
[6]	杨健, 雷辰, 刘祥, 张建, 孙玉蝶, 张铖, 叶明富, 张奎. 碳量子点阳离子表面活性剂的多功能性[J]. 物理化学学报, 2022, 38(12): 2111030 - .
[7]	周孟雪, 任宁, 张建军. 2, 4, 6-三甲基苯甲酸与5, 5'-二甲基-2, 2'-联吡啶构筑的系列镧系超分子配合物的晶体结构、热分解机理和性能[J]. 物理化学学报, 2021, 37(10): 2004071 - .
[8]	黄靖, 王丹阳, 李淑花, 范红, 范楼珍. 红色荧光碳量子点用于肿瘤微酸环境诊断[J]. 物理化学学报, 2021, 37(10): 1905067 - .
[9]	覃方红, 万婷, 邱江源, 王一惠, 肖碧源, 黄在银. 基于光微热量-荧光光谱联用技术研究光催化热力学和动力学的温度效应[J]. 物理化学学报, 2020, 36(6): 1905087 - .
[10]	刘太宏, 苗荣, 彭浩南, 刘静, 丁立平, 房喻. 薄膜基荧光气体传感器中的涂层化学[J]. 物理化学学报, 2020, 36(10): 1908025 - .
[11]	薛楷, 闫敏楠, 潘飞, 田梦颖, 潘旭东, 张宏梅. C₆₀与MoO₃混合材料做空穴注入层的单层有机电致发光器件[J]. 物理化学学报, 2019, 35(8): 896 -902 .
[12]	胡超,穆野,李明宇,邱介山. 纳米碳点的制备与应用研究进展[J]. 物理化学学报, 2019, 35(6): 572 -590 .
[13]	卜佩璇,何晨晖,赵新生. OmpT在Tween-20胶束中折叠的单分子研究[J]. 物理化学学报, 2019, 35(5): 546 -554 .
[14]	曹丹丹, 吕荣, 于安池. 高光学质量氮化碳薄膜的制备和表征[J]. 物理化学学报, 2019, 35(4): 442 -450 .
[15]	夏慧芸,耿通,赵旭,李芳芳,王凤燕,高莉宁. 基于ZnS纳米粒子的有机凝胶荧光薄膜的制备及其传感性能[J]. 物理化学学报, 2019, 35(3): 337 -344 .

多重共振TADF分子的设计策略

Design Strategy for Thermally Activated Delayed Fluorescence Materials with Multiple Resonance Effect

RichHTML

PDF

赞

可视化

摘要/Abstract

引用本文

使用本文

图/表 11

参考文献 66

相关文章 15

Metrics

推荐阅读 0