卤化物钙钛矿的单双向离子迁移

doi:10.3866/PKU.WHXB202311011

物理化学学报 >> 2024, Vol. 40 >> Issue (11): 2311011.doi: 10.3866/PKU.WHXB202311011

卤化物钙钛矿的单双向离子迁移

李睿¹^,²^,†, 刘欢¹^,²^,†, 焦忆楠²^,†, 秦胜建², 孟婕¹^,², 宋佳钰¹^,², 闫融融¹^,², 苏航¹^,², 陈恒彬¹^,², 尚子璇¹, 赵晋津¹^,*()

¹ 河北省能量转换材料与器件技术创新中心, 河北省无机纳米材料重点实验室, 薄膜太阳能电池材料与器件河北省工程研究中心, 河北师范大学化学与材料科学学院, 石家庄 050024
² 石家庄铁道大学材料科学与工程学院, 石家庄 050043

收稿日期:2023-11-08 修回日期:2023-12-17 录用日期:2024-01-08 发布日期:2024-01-12
通讯作者: Email: jinjinzhao2012@163.com; jinjinzhao2023@hebtu.edu.cn (赵晋津)
作者简介:
^†These authors contribute equally to this work.
基金资助:
国家自然科学基金(U2130128); 河北省自然科学基金-燕赵青年科学家专项(B2023205040); 京津冀基础研究合作专项(H2022205047); 京津冀基础研究合作专项(22JCZXJC00060); 京津冀基础研究合作专项(E3B33911DF); 中央引导地方科技发展资金(216Z4302G); 河北省市场监管局科技计划(2023ZC03); 河北省创新能力提升计划(22567604H); 河北师范大学博士科研启动基金(L2023B18)

Emerging Irreversible and Reversible Ion Migrations in Perovskites

Rui Li¹^,², Huan Liu¹^,², Yinan Jiao², Shengjian Qin², Jie Meng¹^,², Jiayu Song¹^,², Rongrong Yan¹^,², Hang Su¹^,², Hengbin Chen¹^,², Zixuan Shang¹, Jinjin Zhao¹^,*()

¹ Hebei Technology Innovation Center for Energy Conversion Materials and Devices, Hebei Key Laboratory of Inorganic Nanomaterials, Engineering Research Center of Thin Film Solar Cell Materials and Devices, Hebei Province, College of Chemistry and Materials Science, Hebei Normal University, Shijiazhuang 050024, China
² School of Materials Science and Engineering, Shijiazhuang Tiedao University, Shijiazhuang 050043, China

Received:2023-11-08 Revised:2023-12-17 Accepted:2024-01-08 Published:2024-01-12
Contact: Email: jinjinzhao2012@163.com; jinjinzhao2023@hebtu.edu.cn (Jinjin Zhao)
Supported by:
the National Natural Science Foundation of China(U2130128); Yanzhao Young Scientist Project from Natural Science Foundation of Hebei Province(B2023205040); Basic Research Cooperation Special Foundation of Beijing-Tianjin-Hebei Region(H2022205047); Basic Research Cooperation Special Foundation of Beijing-Tianjin-Hebei Region(22JCZXJC00060); Basic Research Cooperation Special Foundation of Beijing-Tianjin-Hebei Region(E3B33911DF); Central Government Guiding Local Science and Technology Development Project(216Z4302G); Hebei Administration for Market Supervision Science and Technology Project List(2023ZC03); Innovation Capability Improvement Plan Project of Hebei Province(22567604H); Ph.D Scientific Research Start-up Fund of Hebei Normal University(L2023B18)

摘要/Abstract

摘要：

卤化物钙钛矿材料以其卓越的可见光吸收、光电转换特性、可调的能级结构以及低能耗等特点，在薄膜太阳能电池、发光显示和生物医药领域具有广泛应用的潜力。然而，钙钛矿中复杂的离子迁移过程是导致器件能量转换效率低和稳定性差的关键因素，从而限制了其商业化进程。近年来，科学家们对钙钛矿中离子迁移条件和抑制离子迁移的方法进行了大量研究。本文从能量势垒角度创新性地探讨离子迁移问题，全面综述了钙钛矿材料中不可逆的单向离子迁移和可逆的双向离子迁移的基本概念和形成机制。随后，分析了不可逆的单向离子迁移导致钙钛矿降解的机理。进一步解析了在外加力、电场、光场和热场等外场作用下的双向可逆离子迁移现象，并探讨了调控离子迁移的策略。最后，从能级的角度揭示了钙钛矿中离子迁移作用，通过有效调控离子迁移提升钙钛矿器件的光电转换性能，为促进钙钛矿光电器件的商业化应用提供参考。促进其商业化应用。

关键词: 卤化物钙钛矿, 太阳能电池, 离子迁移, 单向不可逆离子迁移, 双向可逆离子迁移

Abstract:

Metal halide perovskite (MHP) materials show great prospects in applications such as solar cells, luminescent displays, and biomedicines, owing to their outstanding visible light absorption, photoelectric conversion, adjustable energy level structure, and low energy consumption. Their exceptional properties, such as high visible light absorption, efficient photoelectric conversion, adjustable energy level structure, and low energy consumption, have attracted significant attention. However, the presence of ion migration in MHPs has been identified as a critical challenge, leading to reduced energy conversion efficiency and device instability. Overcoming this obstacle is crucial for the commercialization of perovskite-based technologies. In recent years, extensive research has been conducted to understand the conditions and mechanisms of ion migration in perovskite materials, as well as develop strategies to mitigate its adverse effects. This paper adopts a dialectical perspective on ion migration, with a specific focus on energy barriers. A comprehensive review is provided, covering the fundamental concepts and formation mechanisms of both irreversible unidirectional and reversible bidirectional ion migrations. This paper begins by presenting a detailed summary of the degradation processes caused by irreversible unidirectional ion migrations phenomena induced by external fields, including illumination, stress/strain, thermal and electrical fields. Understanding the underlying mechanisms of such degradation is essential to address the stability concerns associated with perovskite devices. Moreover, the overview of bidirectional reversible ion migration phenomena in perovskite is presented. The cyclic formation and restoration of Schottky barriers at the interface can significantly influence the photoelectrical properties and impact the overall performance of perovskite devices. Various strategies for regulating ion migrations under external fields are discussed, aiming to enhance device stability and performance. By understanding the energy landscape and migration pathways, researchers can develop effective strategies to control and optimize ion migrations, ultimately improving the photoelectric conversion performance of perovskite devices. This paper provides comprehensive analysis of ion migration in perovskite materials, addressing fundamental concepts, ion migration mechanisms, and strategies for regulating ion migrations. By providing a clear understanding of the challenges associated with ion migration, this work contributes to the advancement of perovskite-based technologies and facilitates their commercialization. Ultimately, the optimization of ion migration control will lead to improved performance and stability of perovskite devices, enabling their widespread adoption in various applications.

Key words: Halide perovskite, Solar cells, Ion migration, Irreversible unidirectional ion migration, Reversible bidirectional ion migration

李睿, 刘欢, 焦忆楠, 秦胜建, 孟婕, 宋佳钰, 闫融融, 苏航, 陈恒彬, 尚子璇, 赵晋津. 卤化物钙钛矿的单双向离子迁移[J]. 物理化学学报, 2024, 40(11), 2311011. doi: 10.3866/PKU.WHXB202311011

Rui Li, Huan Liu, Yinan Jiao, Shengjian Qin, Jie Meng, Jiayu Song, Rongrong Yan, Hang Su, Hengbin Chen, Zixuan Shang, Jinjin Zhao. Emerging Irreversible and Reversible Ion Migrations in Perovskites[J]. Acta Phys. -Chim. Sin. 2024, 40(11), 2311011. doi: 10.3866/PKU.WHXB202311011

链接本文: https://www.whxb.pku.edu.cn/CN/10.3866/PKU.WHXB202311011

https://www.whxb.pku.edu.cn/CN/Y2024/V40/I11/2311011

图/表 10

图1

图2

表1

表2

图3

图4

图5

图6

图7

图8

参考文献 137

1	https://www.nrel.gov/pv/cell-efficiency.html (accessed on Nov 7, 2023).
2	Chen C.; Zhang S.; Liu T.; Wu S.; Yang Z.; Chen W.; Chen R.; Chen W. Rare Met. 2020, 39(2), 131. doi: 10.1007/s12598-019-01341-z
3	Zhao J.; Kong G.; Chen S.; Li Q.; Huang B.; Liu Z.; San X.; Wang Y.; Wang C.; Zhen Y. Sci. Bull. 2017, 62(17), 1173. doi: 10.1016/j.scib.2017.08.022
4	Zhao J.; Wei L.; Jia C.; Tang H.; Su X.; Ou Y.; Liu Z.; Wang C.; Zhao X.; Jin H. J. Mater. Chem. A 2018, 6(41), 20224. doi: 10.1039/C8TA05282D
5	Zhao J.; Su X.; Mi Z.; Zhang Y.; Hu Y.; Guo H.; Jiao Y.; Zhang Y.; Shi Y.; Hao W-Z.; et al Rare Met. 2022, 41(1), 96. doi: 10.1007/s12598-021-01800-6
6	Burschka J.; Pellet N.; Moon S.-J.; Humphry-Baker R.; Gao P.; Nazeeruddin M. K.; Grätzel M. Nature 2013, 499(7458), 316. doi: 10.1038/nature12340
7	Yang M.; Li Z.; Reese M. O.; Reid O. G.; Kim D. H.; Siol S.; Klein T. R.; Yan Y.; Berry J. J.; Van Hest M. F. Nat. Energy 2017, 2(5), 17038. doi: 10.1038/nenergy.2017.38
8	Green M. A.; Ho-Baillie A.; Snaith H. J. Nat. Photon. 2014, 8(7), 506. doi: 10.1038/nphoton.2014.134
9	Stranks S. D.; Eperon G. E.; Grancini G.; Menelaou C.; Alcocer M. J.; Leijtens T.; Herz L. M.; Petrozza A.; Snaith H. J. Science 2013, 342(6156), 341. doi: 10.1126/science.1243982
10	Dong Q.; Fang Y.; Shao Y.; Mulligan P.; Qiu J.; Cao L.; Huang J. Science 2015, 347(6225), 967. doi: 10.1126/science.aaa5760
11	Shi D.; Adinolfi V.; Comin R.; Yuan M.; Alarousu E.; Buin A.; Chen Y.; Hoogland S.; Rothenberger A.; Katsiev K. Science 2015, 347(6221), 519. doi: 10.1126/science.aaa2725
12	Wehrenfennig C.; Eperon G. E.; Johnston M. B.; Snaith H. J.; Herz L. M. Adv. Mater. 2014, 26(10), 1584. doi: 10.1002/adma.201305172
13	Li S.; Cao Y.; Li W.; Bo Z. Rare Met. 2021, 40, 1. doi: 10.1007/s12598-020-01691-z
14	Qiu L.; Si G.; Bao X.; Liu J.; Guan M.; Wu Y.; Qi X.; Xing G.; Dai Z.; Bao Q.; Li G. Chem. Soc. Rev. 2023, 52, 212. doi: 10.1039/D2CS00218C
15	Yu S.; Zhao Z.; Zhao J.; Xiao S.; Shi Y.; Gao C.; Su X.; Hu Y.; Zhao Z.; Wang J. J. Inorg. Mater. 2020, 35(6), 623. doi: 10.15541/jim20190342
16	Meng G.; Ye Y.; Fan L.; Wang S.; Gnatyuk V.; Fang X. J. Inorg. Mater. 2020, 35(11), 1203. doi: 10.15541/jim20190394
17	Wageh S.; Al-Ghamdi A. A.; Zhao L. Acta Phys. -Chim. Sin. 2022, 38(7), 2111009. doi: 10.3866/PKU.WHXB202111009
	WagehS.; Al-GhamdiAhmed A.; 赵丽. 物理化学学报, 2022, 38(7), 2111009. doi: 10.3866/PKU.WHXB202111009
18	Chen Q.; Zhang Y.; Liu S.; Han T.; Chen X.; Xu Y.; Meng Z.; Zhang G.; Zheng X.; Zhao J. Adv. Intell. Syst. 2020, 2(9), 2000122. doi: 10.1002/aisy.202000122
19	Liu X.; Ren S.; Li Z.; Guo J.; Yi S.; Yang Z.; Hao W.; Li R.; Zhao J. Adv. Funct. Mater. 2022, 32, 2202951. doi: 10.1002/adfm.202202951
20	He C.; Meng Z.; Ren S.; Li J.; Wang Y.; Wu H.; Bu H.; Zhang Y.; Hao W.; Chen S.; et al Rare Met. 2023, 42(5), 1624. doi: 10.1007/s12598-022-02222-8
21	Bu H.; He C.; Xu Y.; Xing L.; Liu X.; Ren S.; Yi S.; Chen L.; Wu H.; Zhang G. Adv. Electron. Mater. 2022, 8(5), 2101204. doi: 10.1002/aelm.202101204
22	Chen B.; Rudd P. N.; Yang S.; Yuan Y.; Huang J. Chem. Soc. Rev. 2019, 48(14), 3842. doi: 10.1039/C8CS00853A
23	Bi E.; Song Z.; Li C.; Wu Z.; Yan Y. Trends Chem. 2021, 3(7), 575. doi: 10.1016/j.trechm.2021.04.004
24	Chen S.; Wu C.; Han B.; Liu Z.; Mi Z.; Hao W.; Zhao J.; Wang X.; Zhang Q.; Liu K.; et al Nat. Commun. 2021, 12(1), 5516. doi: 10.1038/s41467-021-25832-9
25	Huang J.; Yuan Y.; Shao Y.; Yan Y. Nat. Rev. Mater. 2017, 2(7), 1. doi: 10.1038/natrevmats.2017.42
26	Lee J.-W.; Tan S.; Seok S. I.; Yang Y.; Park N. G. Science 2022, 375(6583), eabj1186. doi: 10.1126/science.abj1186
27	Tu Q.; Kim D.; Shyikh M.; Kanatzidis M. G. Matter 2021, 4(9), 2765. doi: 10.1016/j.matt.2021.06.028
28	Liu D.; Luo D.; Iqbal A. N.; Orr K. W.; Doherty T. A.; Lu Z.-H.; Stranks S. D.; Zhang W. Nat. Mater. 2021, 20(10), 1337. doi: 10.1038/s41563-021-01097-x
29	Mela I.; Poudel C.; Anaya M.; Delport G.; Frohna K.; Macpherson S.; Doherty T. A.; Scheeder A.; Stranks S. D.; Kaminski C. F. Adv. Funct. Mater. 2021, 31(23), 2100293. doi: 10.1002/adfm.202100293
30	Eames C.; Frost J. M.; Barnes P. R.; O'regan B. C.; Walsh A.; Islam M. S. Nat. Commun. 2015, 6(1), 7497. doi: 10.1038/ncomms8497
31	Haruyama J.; Sodeyama K.; Han L.; Tateyama Y. J. Am. Chem. Soc. 2015, 137(32), 10048. doi: 10.1021/jacs.5b03615
32	Yuan Y.; Huang J. Acc. Chem. Res. 2016, 49(2), 286. doi: 10.1021/acs.accounts.5b00420
33	Chen R.; Wang J.; Liu Z.; Ren F.; Liu S.; Zhou J.; Wang H.; Meng X.; Zhang Z.; Guan X.; et al Nat. Energy 2023, 8(8), 839. doi: 10.1038/s41560-023-01288-7
34	Zhang H.; Xiang W.; Zuo X.; Gu X.; Zhang S.; Du Y.; Wang Z.; Liu Y.; Wu H.; Wang P. Angew. Chem. 2023, 135(6), e202216634. doi: 10.1002/ange.202216634
35	Zhou J.; Liu Z.; Yu P.; Tong G.; Chen R.; Ono L. K.; Chen R.; Wang H.; Ren F.; Liu S.; Huang J.; Yuan Y.; Shao Y.; Yan Y. Nat. Rev. Mater. 2017, 2(7), 1. doi: 10.1038/natrevmats.2017.42
36	Li Y.; Xie H.; Lim E. L.; Hagfeldt A.; Bi D. Adv. Energy Mater. 2022, 12(5), 2102730. doi: 10.1002/aenm.202102730
37	Divitini G.; Cacovich S.; Matteocci F.; Cinà L.; Di Carlo A.; Ducati C. Nat. Energy 2016, 1(2), 15012. doi: 10.1038/nenergy.2015.12
38	DeQuilettes D. W.; Zhang W.; Burlakov V. M.; Graham D. J.; Leijtens T.; Osherov A.; Bulović V.; Snaith H. J.; Ginger D. S.; Stranks S. D. Nat. Commun. 2016, 7(1), 11683. doi: 10.1038/ncomms11683
39	Bae S.; Kim S.; Lee S.-W.; Cho K. J.; Park S.; Lee S.; Kang Y.; Lee H.-S.; Kim D. J. Phys. Chem. Lett. 2016, 7(16), 3091. doi: 10.1021/acs.jpclett.6b01176
40	Wu S.; Chen R.; Zhang S.; Babu B. H.; Yue Y.; Zhu H.; Yang Z.; Chen C.; Chen W.; Huang Y.; et al Nat. Commun. 2019, 10(1), 1161. doi: 10.1038/s41467-019-09167-0
41	Mei A.; Sheng Y.; Ming Y.; Hu Y.; Rong Y.; Zhang W.; Luo S.; Na G.; Tian C.; Hou X. Joule 2020, 4(12), 2646. doi: 10.1016/j.joule.2020.09.010
42	Zhang G.; Xu Y.; Yang S.; Ren S.; Jiao Y.; Wang Y.; Ma X.; Li H.; Hao W.; He C. Nano Energy 2023, 106, 108074. doi: 10.1016/j.nanoen.2022.108074
43	Yang S.; Xu Y. X.; Hao Z. K.; Qin S. J.; Zhang R. P.; Han Y.; Du L. W.; Zhu Z. Y.; Du A. N.; Chen X.; et al Acta Phys. -Chim. Sin. 2023, 39(5), 2211025. doi: 10.3866/PKU.WHXB202211025
	杨帅; 徐瑜歆; 郝子坤; 秦胜建; 张润鹏; 韩钰; 杜利伟; 朱紫洢; 杜安宁; 陈欣; 等. 物理化学学报, 2023, 39(5), 2211025. doi: 10.3866/PKU.WHXB202211025
44	Jiménez-López J.; Puscher B. M.; Guldi D. M.; Palomares E. J. Am. Chem. Soc. 2019, 142(3), 1236. doi: 10.1021/jacs.9b09182
45	Moia D.; Maier J. ACS Energy Lett. 2021, 6(4), 1566. doi: 10.1021/acsenergylett.1c00227
46	Li D.; Wu H.; Cheng H.-C.; Wang G.; Huang Y.; Duan X. ACS Nano 2016, 10(7), 6933. doi: 10.1021/acsnano.6b02795
47	Wang X.; Ling Y.; Chiu Y.-C.; Du Y.; Barreda J. L.; Perez-Orive F.; Ma B.; Xiong P.; Gao H. Nano Lett. 2017, 17(8), 4831. doi: 10.1021/acs.nanolett.7b01665
48	Zhang H.; Fu X.; Tang Y.; Wang H.; Zhang C.; William W. Y.; Wang X.; Zhang Y.; Xiao M. Nat. Commun. 2019, 10(1), 1. doi: 10.1038/s41467-019-09047-7
49	Jung M.; Ji S.-G.; Kim G.; Seok S. I. Chem. Soc. Rev. 2019, 48(7), 2011. doi: 10.1039/C8CS00656C
50	Kim J.; Lee S.-H.; Lee J. H.; Hong K.-H. J. Phys. Chem. Lett. 2014, 5(8), 1312. doi: 10.1021/jz500370k
51	Yin W.-J.; Shi T.; Yan Y. Appl. Phys. Lett. 2014, 104(6), 063903. doi: 10.1063/1.4864778
52	Son D.-Y.; Kim S.-G.; Seo J.-Y.; Lee S.-H.; Shin H.; Lee D.; Park N.-G. J. Am. Chem. Soc. 2018, 140(4), 1358. doi: 10.1021/jacs.7b10430
53	Azpiroz J. M.; Mosconi E.; Bisquert J.; De Angelis F. Energy Environ. Sci. 2015, 8(7), 2118. doi: 10.1039/C5EE01265A
54	Motti S. G.; Meggiolaro D.; Barker A. J.; Mosconi E.; Perini C. A. R.; Ball J. M.; Gandini M.; Kim M.; De Angelis F.; Petrozza A. Nat. Photon. 2019, 13(8), 532. doi: 10.1038/s41566-019-0435-1
55	Meggiolaro D.; Motti S. G.; Mosconi E.; Barker A. J.; Ball J.; Perini C. A. R.; Deschler F.; Petrozza A.; De Angelis F. Energy Environ. Sci. 2018, 11(3), 702. doi: 10.1039/C8EE00124C
56	Leijtens T.; Eperon G. E.; Barker A. J.; Grancini G.; Zhang W.; Ball J. M.; Kandada A. R. S.; Snaith H. J.; Petrozza A. Energy Environ. Sci. 2016, 9(11), 3472. doi: 10.1039/C6EE01729K
57	Yang J.-H.; Yin W.-J.; Park J.-S.; Wei S.-H. J. Mater. Chem. A 2016, 4(34), 13105. doi: 10.1039/C6TA03599J
58	Henstridge M.; Först M.; Rowe E.; Fechner M.; Cavalleri A. Nat. Phys. 2022, 18(4), 457. doi: 10.1038/s41567-022-01512-3
59	Lejaeghere K.; Bihlmayer G.; Björkman T.; Blaha P.; Blügel S.; Blum V.; Caliste D.; Castelli I. E.; Clark S. J.; Dal Corso A. Science 2016, 351(6280), aad3000. doi: 10.1126/science.aad3000
60	Meggiolaro D.; Mosconi E.; De Angelis F. ACS Energy Lett. 2019, 4(3), 779. doi: 10.1021/acsenergylett.9b00247
61	Shao Y.; Fang Y.; Li T.; Wang Q.; Dong Q.; Deng Y.; Yuan Y.; Wei H.; Wang M.; Gruverman A. Energy Environ. Sci. 2016, 9(5), 1752. doi: 10.1039/C6EE00413J
62	Zhang T.; Chen H.; Bai Y.; Xiao S.; Zhu L.; Hu C.; Xue Q.; Yang S. Nano Energy 2016, 26, 620. doi: 10.1016/j.nanoen.2016.05.052
63	Futscher M. H.; Lee J. M.; McGovern L.; Muscarella L. A.; Wang T.; Haider M. I.; Fakharuddin A.; Schmidt-Mende L.; Ehrler B. Mater. Horiz. 2019, 6(7), 1497. doi: 10.1039/C9MH00445A
64	Jong U.-G.; Yu C.-J.; Ri G.-C.; McMahon A. P.; Harrison N. M.; Barnes P. R.; Walsh A. J. Mater. Chem. A 2018, 6(3), 1067. doi: 10.1039/C7TA09112E
65	Tan S.; Yavuz I.; De Marco N.; Huang T.; Lee S. J.; Choi C. S.; Wang M.; Nuryyeva S.; Wang R.; Zhao Y. Adv. Mater. 2020, 32(11), 1906995. doi: 10.1002/adma.201906995
66	Lin Y.; Bai Y.; Fang Y.; Wang Q.; Deng Y.; Huang J. ACS Energy Lett. 2017, 2(7), 1571. doi: 10.1021/acsenergylett.7b00442
67	Zhou W.; Zhao Y.; Zhou X.; Fu R.; Li Q.; Zhao Y.; Liu K.; Yu D.; Zhao Q. J. Phys. Chem. Lett. 2017, 8(17), 4122. doi: 10.1021/acs.jpclett.7b01851
68	Yang T. Y.; Gregori G.; Pellet N.; Grätzel M.; Maier J. Angew. Chem. 2015, 127(27), 8016. doi: 10.1002/ange.201500014
69	Bag M.; Renna L. A.; Adhikari R. Y.; Karak S.; Liu F.; Lahti P. M.; Russell T. P.; Tuominen M. T.; Venkataraman D. J. Am. Chem. Soc. 2015, 137(40), 13130. doi: 10.1021/jacs.5b08535
70	Leoncini M.; Giannuzzi R.; Giuri A.; Colella S.; Listorti A.; Maiorano V.; Rizzo A.; Gigli G.; Gambino S. J. Sci.: Adv. Mater. Devices. 2021, 6(4), 543. doi: 10.1016/j.jsamd.2021.07.006
71	Xing J.; Wang Q.; Dong Q.; Yuan Y.; Fang Y.; Huang J. Phys. Chem. Chem. Phys. 2016, 18(44), 30484. doi: 10.1039/C6CP06496E
72	Lin D.; Shi T.; Xie H.; Wan F.; Ren X.; Liu K.; Zhao Y.; Ke L.; Lin Y.; Gao Y. Adv. Energy Mater. 2021, 11(8), 2002552. doi: 10.1002/aenm.202002552
73	Mahapatra A.; Runjhun R.; Nawrocki J.; Lewiński J.; Kalam A.; Kumar P.; Trivedi S.; Tavakoli M. M.; Prochowicz D.; Yadav P. Phys. Chem. Chem. Phys. 2020, 22(20), 11467. doi: 10.1039/D0CP01119C
74	Zhao Y.-C.; Zhou W.-K.; Zhou X.; Liu K.-H.; Yu D.-P.; Zhao Q. Light Sci. Appl. 2017, 6(5), e16243. doi: 10.1038/lsa.2016.243
75	Sheng Y.; Liu C.; Yu L.; Yang Y.; Hu F.; Sheng C.; Di Y.; Dong L.; Gan Z. Nanoscale 2021, 13(34), 14450. doi: 10.1039/D1NR02511B
76	Scheidt R. A.; Kamat P. V. J. Chem. Phys. 2019, 151(13) doi: 10.1063/1.5120270
77	Mizusaki J.; Arai K.; Fueki K. Solid State Ion. 1983, 11(3), 203. doi: 10.1016/0167-2738(83)90025-5
78	Pazoki M.; Wolf M. J.; Edvinsson T.; Kullgren J. Nano Energy 2017, 38, 537. doi: 10.1016/j.nanoen.2017.06.024
79	Li N.; Jia Y.; Guo Y.; Zhao N. J. A. M. Adv. Mater. 2022, 2108102. doi: 10.1002/adma.202108102
80	Laidler K. J. Chemical Kinetics Harper & Row: : New York City, US., 1987, pp. 40- 45.
81	Shi J.; Xu X.; Zhang H.; Luo Y.; Li D.; Meng Q. Appl. Phys. Lett. 2015, 107(16), 163901. doi: 10.1063/1.4934633
82	Walsh A.; Stranks S. D. ACS Energy Lett. 2018, 3(8), 1983. doi: 10.1021/acsenergylett.8b00764
83	Frost J. M.; Butler K. T.; Brivio F.; Hendon C. H.; Van Schilfgaarde M.; Walsh A. Nano Lett. 2014, 14(5), 2584. doi: 10.1021/nl500390f
84	Yamilova O. R.; Danilov A. V.; Mangrulkar M.; Fedotov Y. S.; Luchkin S. Y.; Babenko S. D.; Bredikhin S. I.; Aldoshin S. M.; Stevenson K. J.; Troshin P. A. J. Phys. Chem. Lett. 2020, 11(1), 221. doi: 10.1021/acs.jpclett.9b03161
85	Lanzetta L.; Webb T.; Zibouche N.; Liang X.; Ding D.; Min G.; Westbrook R. J.; Gaggio B.; Macdonald T. J.; Islam M. S. Nat. Commun. 2021, 12(1), 2853. doi: 10.1038/s41467-021-22864-z
86	Song J.; Kong T.; Zhang Y.; Liu X.; Saliba M.; Bi D. Adv. Funct. Mater. 2023, 2304201. doi: 10.1002/adfm.202304201
87	Chen S.; Zhang X.; Zhao J.; Zhang Y.; Kong G.; Li Q.; Li N.; Yu Y.; Xu N.; Zhang J. Nat. Commun. 2018, 9(1), 4807. doi: 10.1038/s41467-018-07177-y
88	Chen S.; Zhang Y.; Zhang X.; Zhao J.; Zhao Z.; Su X.; Hua Z.; Zhang J.; Cao J.; Feng J.; et al Adv. Mater. 2022, 32, 2001107. doi: 10.1002/adma.202001107
89	Li Y.; Lim E. L.; Zhang Y.; Kong T.; Liu X.; Song J.; Xie H.; Bi D. ACS Appl. Energy Mater. 2022, 5(12), 15233. doi: 10.1021/acsaem.2c02875
90	Xue D.-J.; Hou Y.; Liu S.-C.; Wei M.; Chen B.; Huang Z.; Li Z.; Sun B.; Proppe A. H.; Dong Y.; et al Nat. Commun. 2020, 11(1), 1514. doi: 10.1038/s41467-020-15338-1
91	Wang L.; Song Q.; Pei F.; Chen Y.; Dou J.; Wang H.; Shi C.; Zhang X.; Fan R.; Zhou W.; et al Adv. Mater. 2022, 34(26), 2201315. doi: 10.1002/adma.202201315
92	Ramirez C.; Yadavalli S. K.; Garces H. F.; Zhou Y.; Padture N. P. Scripta Mater. 2018, 150, 36. doi: 10.1016/j.scriptamat.2018.02.022
93	Liu Y.; Collins L.; Proksch R.; Kim S.; Watson B. R.; Doughty B.; Calhoun T. R.; Ahmadi M.; Ievlev A. V.; Jesse S. Nat. Mater. 2018, 17(11), 1013. doi: 10.1038/s41563-018-0152-z
94	Kim M.; Jun H.; Lee H.; Nahdi H.; Tondelier D.; Bonnassieux Y.; Bourée J. É.; Geffroy B. Eur. J. Inorg. Chem. 2021, 2021(46), 4781. doi: 10.1002/ejic.202100654
95	Lu Y.; Ge Y.; Sui M. L. Acta Phys. -Chim. Sin. 2022, 38(5), 2007088. doi: 10.3866/PKU.WHXB202007088
	卢岳; 葛杨; 隋曼龄. 物理化学学报, 2022, 38(5), 2007088. doi: 10.3866/PKU.WHXB202007088
96	Zheng F.; Wen X.; Bu T.; Chen S.; Yang J.; Chen W.; Huang F.; Cheng Y.; Jia B. ACS Appl. Mater. Interfaces. 2018, 10(37), 31452. doi: 10.1021/acsami.8b13932
97	Mahapatra A.; Parikh N.; Kumari H.; Pandey M. K.; Kumar M.; Prochowicz D.; Kalam A.; Tavakoli M. M.; Yadav P. J. Appl. Phys. 2020, 127(18), 185501. doi: 10.1063/5.0005369
98	Zhao Y.; Yavuz I.; Wang M.; Weber M. H.; Xu M.; Lee J.-H.; Tan S.; Huang T.; Meng D.; Wang R. Nat. Mater. 2022, 21(12), 1396. doi: 10.1038/s41563-022-01390-3
99	Holekevi Chandrappa M. L.; Zhu Z.; Fenning D. P.; Ong S. P. Chem. Mater. 2021, 33(12), 4672. doi: 10.1021/acs.chemmater.1c01175
100	Yang W.; Ding B.; Lin Z.; Sun J.; Meng Y.; Ding Y.; Sheng J.; Yang Z.; Ye J.; Dyson P. J.; Nazeeruddin M. K. Adv. Mater. 2023, 35(35), 2302071. doi: 10.1002/adma.202302071
101	Zhang X.; Zhou W.; Chen X.; Chen Y.; Li X.; Wang M.; Zhou Y.; Yan H.; Zheng Z.; Zhang Y. Adv. Mater. 2022, 12(26), 2201105. doi: 10.1002/aenm.202201105
102	Ferdani D. W.; Pering S. R.; Ghosh D.; Kubiak P.; Walker A. B.; Lewis S. E.; Johnson A. L.; Baker P. J.; Islam M. S.; Cameron P. J. Energy Environ. Sci. 2019, 12(7), 2264. doi: 10.1039/C9EE00476A
103	Xiao X.; Dai J.; Fang Y.; Zhao J.; Zheng X.; Tang S.; Rudd P. N.; Zeng X. C.; Huang J. ACS Energy Lett. 2018, 3(3), 684. doi: 10.1021/acsenergylett.8b00047
104	Sutanto A. A.; Drigo N.; Queloz V. I.; Garcia-Benito I.; Kirmani A. R.; Richter L. J.; Schouwink P. A.; Cho K. T.; Paek S.; Nazeeruddin M. K. J. Mater. Chem. A 2020, 8(5), 2343. doi: 10.1039/C9TA12489F
105	Zhou T.; Lai H.; Liu T.; Lu D.; Wan X.; Zhang X.; Liu Y.; Chen Y. Adv. Mater. 2019, 31(32), 1901242. doi: 10.1002/adma.201901242
106	Jiang X.; Zhang J.; Liu Y.; Wang Z.; Liu X.; Guo X.; Li C. Nano Energy 2021, 90, 106521. doi: 10.1016/j.nanoen.2021.106521
107	Wang Y.; Wu T.; Barbaud J.; Kong W.; Cui D.; Chen H.; Yang X.; Han L. Science 2019, 365(6454), 687. doi: 10.1126/science.aax8018
108	Wei D.; Ma F.; Wang R.; Dou S.; Cui P.; Huang H.; Ji J.; Jia E.; Jia X.; Sajid S. Adv. Mater. 2018, 30(31), 1707583. doi: 10.1002/adma.201707583
109	Zhou Q.; Duan J.; Yang X.; Duan Y.; Tang Q. Angew. Chem. 2020, 132(49), 22181. doi: 10.1002/ange.202010252
110	Zhang Y.; Kong T.; Xie H.; Song J.; Li Y.; Ai Y.; Han Y.; Bi D. ACS Energy Lett. 2022, 7(3), 929. doi: 10.1021/acsenergylett.1c02545
111	Egger D. A.; Kronik L.; Rappe A. M. Angew. Chem. Int. Ed. 2015, 54(42), 12437. doi: 10.1002/anie.201502544
112	Domanski K.; Correa-Baena J.-P.; Mine N.; Nazeeruddin M. K.; Abate A.; Saliba M.; Tress W.; Hagfeldt A.; Grätzel M. ACS Nano 2016, 10(6), 6306. doi: 10.1021/acsnano.6b02613
113	Li Z.; Xiao C.; Yang Y.; Harvey S. P.; Kim D. H.; Christians J. A.; Yang M.; Schulz P.; Nanayakkara S. U.; Jiang C.-S. Energy Environ. Sci. 2017, 10(5), 1234. doi: 10.1039/C7EE00358G
114	Zhang J.; Chen R.; Wu Y.; Shang M.; Zeng Z.; Zhang Y.; Zhu Y.; Han L. Adv. Energy Mater. 2018, 8(5), 1701981. doi: 10.1002/aenm.201701981
115	Ren S. X.; Yang Z.; An S. L.; Meng J.; Liu X. M.; Zhao J. J. Acta Phys. -Chim. Sin. 2023, 39(12), 2301033. doi: 10.3866/PKU.WHXB202301033
	任书霞; 杨铮; 安帅领; 孟婕; 刘晓敏; 赵晋津. 物理化学学报, 2023, 39(12), 2301033. doi: 10.3866/PKU.WHXB202301033
116	Kamat P. V.; Kuno M. Acc. Chem. Res. 2021, 54(3), 520. doi: 10.1021/acs.accounts.0c00749
117	Hoke E. T.; Slotcavage D. J.; Dohner E. R.; Bowring A. R.; Karunadasa H. I.; McGehee M. D. Chem. Sci. 2015, 6(1), 613. doi: 10.1039/C4SC03141E
118	Wang H.; Zhang X.; Sui N.; Hu Y.; Colvin V. L.; Bai X.; Zhang Y.; Rogach A. L.; Yu W. W. J. Phys. Chem. Lett. 2020, 11(15), 6168. doi: 10.1021/acs.jpclett.0c01844
119	Samu G. F.; Janaky C.; Kamat P. V. ACS Energy Lett. 2017, 2(8), 1860. doi: 10.1021/acsenergylett.7b00589
120	Giridharagopal R.; Precht J. T.; Jariwala S.; Collins L.; Jesse S.; Kalinin S. V.; Ginger D. S. ACS nano 2019, 13(3), 2812. doi: 10.1021/acsnano.8b08390
121	Yuan Y.; Chae J.; Shao Y.; Wang Q.; Xiao Z.; Centrone A.; Huang J. Adv. Energy Mater. 2015, 5(15), 1500615. doi: 10.1002/aenm.201500615
122	Liu Y.; Ievlev A.; Collins L.; Borodinov N.; Kalinin S.; Ovchinnikova O. Microsc. Microanal. 2020, 26(S2), 2046. doi: 10.1017/S1431927620020267
123	Liu Y.; Ievlev A. V.; Borodinov N.; Lorenz M.; Xiao K.; Ahmadi M.; Hu B.; Kalinin S. V.; Ovchinnikova O. S. Adv. Funct. Mater. 2021, 31(8), 2008777. doi: 10.1002/adfm.202008777
124	Tress W.; Marinova N.; Moehl T.; Zakeeruddin S. M.; Nazeeruddin M. K.; Grätzel M. Energy Environ. Sci. 2015, 8(3), 995. doi: 10.1039/C4EE03664F
125	Deng X.; Wen X.; Lau C. F. J.; Young T.; Yun J.; Green M. A.; Huang S.; Ho-Baillie A. W. J. Mater. Chem. C 2016, 4(38), 9060. doi: 10.1039/C6TC03206K
126	Leijtens T.; Hoke E. T.; Grancini G.; Slotcavage D. J.; Eperon G. E.; Ball J. M.; De Bastiani M.; Bowring A. R.; Martino N.; Wojciechowski K. Adv. Energy Mater. 2015, 5(20), 1500962. doi: 10.1002/aenm.201500962
127	Jacobs D. L.; Scarpulla M. A.; Wang C.; Bunes B. R.; Zang L. J. Phys. Chem. C 2016, 120(15), 7893. doi: 10.1021/acs.jpcc.5b11973
128	Haque F.; Mativenga M. Jpn. J. Appl. Phys. 2020, 59(8), 081002. doi: 10.35848/1347-4065/aba5e1
129	Zhu X.; Lee J.; Lu W. D. Adv. Mater. 2017, 29(29), 1700527. doi: 10.1002/adma.201700527
130	Qian W. H.; Cheng X. F.; Zhou J.; He J. H.; Li H.; Xu Q. F.; Li N. J.; Chen D. Y.; Yao Z. G.; Lu J. M. InfoMat 2020, 2(4), 743. doi: 10.1002/inf2.12066
131	Liu Z.; Cheng P.; Li Y.; Kang R.; Zhang Z.; Zuo Z.; Zhao J. ACS Appl. Mater. Interfaces. 2021, 13(49), 58885. doi: 10.1021/acsami.1c13561
132	Liu Y.; Borodinov N.; Collins L.; Ahmadi M.; Kalinin S. V.; Ovchinnikova O. S.; Ievlev A. V. ACS Nano 2021, 15(5), 9017. doi: 10.1021/acsnano.1c02097
133	Lee H.; Gaiaschi S.; Chapon P.; Marronnier A.; Lee H.; Vanel J.-C.; Tondelier D.; Boureé J.-E.; Bonnassieux Y.; Geffroy B. ACS Energy Lett. 2017, 2(4), 943. doi: 10.1021/acsenergylett.7b00150
134	Unger E. L.; Hoke E. T.; Bailie C. D.; Nguyen W. H.; Bowring A. R.; Heumüller T.; Christoforo M. G.; McGehee M. D. Energy Environ. Sci. 2014, 7(11), 3690. doi: 10.1039/C4EE02465F
135	Wang S.; Dong X.; Xiong Y.; Sha J.; Cao Y.; Wu Y.; Li W.; Yin Y.; Wang Y. Adv. Electron. Mater. 2021, 7(5), 2100014. doi: 10.1002/aelm.202100014
136	Pavlovetc I. M.; Brennan M. C.; Draguta S.; Ruth A.; Moot T.; Christians J. A.; Aleshire K.; Harvey S. P.; Toso S.; Nanayakkara S. U. ACS Energy Lett. 2020, 5(9), 2802. doi: 10.1021/acsenergylett.0c01207
137	Lee H.; Boonmongkolras P.; Jun S.; Kim D.; Park Y.; Koh J.; Cho Y.-H.; Shin B.; Park J. Y. ACS Appl. Energy Mater. 2023, 6(3), 1565. doi: 10.1021/acsaem.2c03438

Materials	Mobile ion	Crystal structure	Activation energy (eV)	Reversibility	Characterization Methods		Ref.
MAPbI₃	MA⁺	Tetragonal	0.46	Reversible	First-Principles		53
		Tetragonal	0.735		DFT		62
		Tetragonal<110>	0.57		First-Principles		31
		Tetragonal<001>	0.89
		Tetragonal (a neighboring vacant A-site cage)	0.84				30
		Tetragonal	0.9 ± 0.45		Arrhenius equation		63
		Cubic	0.39 ± 0.24
	Pb²⁺	Tetragonal	0.8		First-Principles		53
		Tetragonal<110>	2.31				30
	I⁻	Tetragonal	0.08				53
		Tetragonal	0.342		DFT		62
		Pseudo-cubic	0.55	Irreversible	First-Principles		64
		Tetragonal<100>	0.32	Reversible			31
		Tetragonal<111>	0.44
		Tetragonal (octahedron edge)	0.58				30
		Tetragonal	0.433		Nernst-Einstein relation		65
		Tetragonal	0.19		Dark	Nernst-Einstein relation	66
			0.03		25 mW∙cm⁻²	Nernst-Einstein relation	66
		Tetragonal	0.622		0.1 mW∙cm⁻²	Nernst-Einstein relation (T>250 K)	67
			0.144		5 mW∙cm⁻²	Nernst-Einstein relation (T>250 K)
			0.07		25 mW∙cm⁻²
		Cubic	0.43		Arrhenius equation		68
		Tetragonal	0.58		Arrhenius equation (T＜320)		69
		Cubic	0.229		Arrhenius equation (T＞320)
		Tetragonal	0.322		Arrhenius equation		70
			0.416		Arrhenius equation (PbSO₄)
		Tetragonal	0.29±0.06		Arrhenius equation		63
		Tetragonal (1μm grain size)	0.14		Nernst-Einstein relation(25mW∙cm⁻²)		71
		Tetragonal (0.3μm grain size)	0.08
		Tetragonal (Single crystal)	0.47
		Tetragonal (1μm grain size)	0.5		Dark; Nernst-Einstein relation
		Tetragonal (0.3μm grain size)	0.27
		Tetragonal (Single crystal)	1.05
		Tetragonal	0.37		Arrhenius equation		72
		Cubic	0.52				73
		Tetragonal	0.824		0.05 mW∙cm⁻²	Nernst-Einstein relation (Illumination; T>250 K)	74
			0.851		1 mW∙cm⁻²
			0.334		5 mW∙cm⁻²
			0.144		20 mW∙cm⁻²

Materials	Mobile ion	Crystal Structure	Activation energy (eV)	Reversibility	Characterization Methods		Ref.
MAPbBr₃	MA⁺	Tetragonal	0.56	Reversible	First-Principles		53
	Br⁻	Tetragonal	0.09				53
		Pseudo-cubic	0.58	Irreversible			64
		Cubic	0.11	Reversible	Nernst-Einstein relation (resonance frequency<50Hz)		97
			0.28		Nernst-Einstein relation (resonance frequency>50Hz)
			0.36		Nernst-Einstein relation (PbSO₄ passivation)
MAPbBr_xI_3−x	MA⁺	Cubic	0.801		DFT		62
	Br⁻		0.326
	I₁⁻ (Pb-I = 0.319 nm)		0.456
	I₂⁻ (Pb-I = 0.327 nm)		0.49
	I₃⁻ (Pb-I = 0.325 nm)		0.522
FAPbI₃	FA	Trigonal<110>	0.57		First-Principles		31
	FA⁺		0.61
	FA	Trigonal<001>	0.59
	FA⁺		0.61
	I	Trigonal<111>	0.42
	I⁻		0.48
	I	Trigonal<100>	0.5
	I⁻		0.55
	I⁻	Trigonal	0.79		Arrhenius equation		69
			0.218
AceMAPbI₃		Cubic	0.542		Nernst-Einstein relation		65
(GUAMA)PbI₃			0.36		Arrhenius equation		73
CsPbI₂Br			0.454		0.1 mW∙cm⁻²	Nernst-Einstein relation (T> 250 K)	67
			0.456		5 mW∙cm⁻²	Nernst-Einstein relation (T> 250 K)
			0.43		25 mW∙cm⁻²
CsPbBr₃	Cs⁺	Orthogonal	0.7		First-Principles		75
	Pb²⁺		0.94
	Br⁻		0.27
			0.19		Arrhenius equation		76
			0.25				77
CsPbI₃	Cs⁺	Tetragonal	0.61		DFT		78
	Pb²⁺		1.4
	I⁻		0.21
MA_xFA_1−xPbI₃		Trigonal	0.643		Arrhenius equation		69
Cs_0.05MA_0.05FA_0.9PbI₃		Cubic	0.43		Arrhenius equation		100
Cs_0.05MA_0.05FA_0.9PbI₃/BAI			0.50
Cs_0.05MA_0.05FA_0.9PbI₃/BABr			0.52
FAPbI₃/GuCl	Cl⁻	Trigonal	0.59		First-Principles		101
FAPbI₃/GuBr	Br⁻		0.62
FAPbI₃/GuI	I⁻		0.73
MAPbCl₃	Cl⁻	Pseudo-cubic	0.62	Irreversible			64

[1]	王震寰, 韦炜斐, 马睿杰, 罗豆, 陈展翔, 张君, 于立扬, 李刚, 罗正辉. 苯并[a]苯嗪受体的核心氰基化实现高效(19.04%)绿色溶剂加工的二元有机太阳能[J]. 物理化学学报, 2026, 42(2): 100182 - .
[2]	刘彬彬, 陈杨, 贾天赐, 陈辰, 吴章豪, 刘毓辉, 翟宇航, 马天舒, 王长擂. 羟基功能化分子工程消除二维相壁垒实现高效宽带隙及全钙钛矿叠层太阳能电池[J]. 物理化学学报, 2026, 42(1): 100128 - .
[3]	张凤英, 梅杨林, 蒋毓蔓, 郑申申, 郑凯波, 周莹. 瞬态吸收光谱在太阳能转化利用中的研究进展[J]. 物理化学学报, 2025, 41(9): 100118 - .
[4]	王毅锴, 蒋晓林, 宋浩鸣, 魏楠, 王逸凡, 徐新军, 李翠红, 路皓, 刘亚辉, 薄志山. 氰基修饰的苝二酰亚胺衍生物作为膜厚不敏感型阴极界面材料用于高效有机太阳能电池[J]. 物理化学学报, 2025, 41(3): 100027 - .
[5]	董鹏宇, 姜月, 杨正池, 刘立城, 李固, 文鑫洋, 王祯, 施信波, 周国富, 刘俊明, 高进伟. NbSe₂纳米片优化钙钛矿太阳能电池的埋底界面[J]. 物理化学学报, 2025, 41(3): 100029 - .
[6]	李尚华, 李玛琳, 迟茜文, 尹心, 罗招娣, 于吉红. 基于高离子迁移动力学的取向ZnQ分子筛保护层实现高稳定水系锌金属负极的构筑[J]. 物理化学学报, 2025, 41(1): 100003 - .
[7]	李若男, 梁世洁, 许韵华, 张翠芬, 唐正, 刘柏侨, 李韦伟. 氯取代近红外双缆共轭高分子材料与低能量损失单组分有机太阳能电池[J]. 物理化学学报, 2024, 40(8): 2307037 - .
[8]	AhmedYameen, 封想想, 高远基, 丁洋, 龙操玉, HaiderMustafa, 李恒月, 李专, 黄誓成, SaidaminovMakhsud I., 阳军亮. 离子液体界面修饰的高效稳定FAPbI₃钙钛矿太阳能电池[J]. 物理化学学报, 2024, 40(6): 2303057 - .
[9]	郭雅雯, 李大伟, 高杨, 李翠红. 非富勒烯受体有机太阳能电池稳定性研究进展[J]. 物理化学学报, 2024, 40(6): 2306050 - .
[10]	梁秋菊, 常银霞, 梁朝伟, 祝浩雷, 郭子宾, 刘剑刚. 结晶动力学策略在非富勒烯体系太阳能电池形貌调控领域的应用[J]. 物理化学学报, 2023, 39(7): 2212006 -0 .
[11]	杨帅, 徐瑜歆, 郝子坤, 秦胜建, 张润鹏, 韩钰, 杜利伟, 朱紫洢, 杜安宁, 陈欣, 吴昊, 乔冰冰, 李坚, 王艺, 孙昺晨, 闫融融, 赵晋津. 高效医学传感钙钛矿材料研究进展[J]. 物理化学学报, 2023, 39(5): 2211025 -0 .
[12]	文永涛, 李静, 高晓峰, 田聪聪, 朱昊, 余国木, 张晓俐, Park Hyesung, 黄福志. 控制碘化铅形貌两步连续刮涂法大面积制备甲脒基钙钛矿薄膜[J]. 物理化学学报, 2023, 39(2): 2203048 -0 .
[13]	任书霞, 杨铮, 安帅领, 孟婕, 刘晓敏, 赵晋津. 高效光电调控钙钛矿量子点阻变存储性能[J]. 物理化学学报, 2023, 39(12): 2301033 - .
[14]	卢岳, 葛杨, 隋曼龄. 紫外光辐照下CH₃NH₃PbI₃基钙钛矿太阳能电池失效机制[J]. 物理化学学报, 2022, 38(5): 2007088 - .
[15]	林飞宇, 杨英, 朱从潭, 陈甜, 马书鹏, 罗媛, 朱刘, 郭学益. 湿空气下制备稳定的CsPbI₂Br钙钛矿太阳电池[J]. 物理化学学报, 2022, 38(4): 2005007 - .

卤化物钙钛矿的单双向离子迁移

Emerging Irreversible and Reversible Ion Migrations in Perovskites

RichHTML

PDF

赞

可视化

摘要/Abstract

引用本文

使用本文

图/表 10

参考文献 137

相关文章 15

Metrics

推荐阅读 0