基于氧化石墨烯-聚四氟乙烯氢键分子间作用的抗蠕变性能增强研究

doi:10.1016/j.actphy.2026.100315

物理化学学报 >> 2026, Vol. 42 >> Issue (8): 100315.doi: 10.1016/j.actphy.2026.100315

基于氧化石墨烯-聚四氟乙烯氢键分子间作用的抗蠕变性能增强研究

刘柯¹^,²^,³, 高琪⁴, 李海丰², 刁立鹏¹^,³^,⁴^,*(), 陈学刚¹^,³^,⁴^,*(), 李道浩¹, 吴广磊¹^,*()

¹ 青岛大学材料科学与工程学院, 生物多糖纤维成形与生态纺织国家重点实验室, 山东青岛 266071
² 湖北汽车工业学院汽车材料学院, 湖北十堰 442002
³ 宁波永基精密科技有限公司, 浙江宁波 315400
⁴ 青岛汉兴新材料有限公司, 山东青岛 266109

收稿日期:2026-01-31 修回日期:2026-05-04 录用日期:2026-05-06 发布日期:2026-06-11
通讯作者: Email: diaolipeng@qdhanxing.com (刁立鹏)chenxuegang.cool@163.com (陈学刚)wuguanglei@qdu.edu.cn/wuguanglei@mail.xjtu.edu.cn (吴广磊)

Hydrogen-bonding intermolecular interaction between graphene oxide and polytetrafluoroethylene enhanced creep resistance

Ke Liu¹^,²^,³, Qi Gao⁴, Haifeng Li², Lipeng Diao¹^,³^,⁴^,*(), Xuegang Chen¹^,³^,⁴^,*(), Daohao Li¹, Guanglei Wu¹^,*()

¹ State Key Laboratory of Bio-fibers and Eco-textiles, College of Materials Science and Engineering, Qingdao University, Qingdao 266071, Shandong Province, China
² School of Automotive Materials, Hubei University of Automotive Technology, Shiyan 442002, Hubei Province, China
³ Ningbo Yokey Precision Technology Co., Ltd, Ningbo 315400, Zhejiang Province, China
⁴ Qingdao Hanxing New Material Co., Ltd, Qingdao 266109, Shandong Province, China

Received:2026-01-31 Revised:2026-05-04 Accepted:2026-05-06 Published:2026-06-11
Contact: Email: diaolipeng@qdhanxing.com (Lipeng Diao)chenxuegang.cool@163.com (Xuegang Chen)wuguanglei@qdu.edu.cn/wuguanglei@mail.xjtu.edu.cn (Guanglei Wu)

摘要/Abstract

摘要：

聚四氟乙烯(PTFE)因具备优异的热稳定性、电绝缘性及低摩擦特性被广泛应用。然而，其显著的蠕变行为极大地限制了自身的应用范围。无机填料可有效改善聚四氟乙烯基材料的抗蠕变性能，且填料与聚四氟乙烯基体间的相互作用力对改性效果起着关键作用。本研究采用二维单层氧化石墨烯(GO)作为增强填料，制备得到氧化石墨烯-聚四氟乙烯(GO-PTFE)复合材料，实现了材料抗蠕变性能的显著提升。氧化石墨烯表面富含含氧官能团，可与聚四氟乙烯基体中的氟原子形成强界面氢键作用。理论计算与分子动力学模拟结果表明，GO-PTFE复合材料中存在强烈的分子间相互作用，该作用能够有效限制聚四氟乙烯分子链的运动，减缓其在外力作用下的滑移与变形，进而降低材料的蠕变程度。

关键词: 氢键作用, 填充改性, 聚四氟乙烯, 抗蠕变

Abstract:

Polytetrafluoroethylene (PTFE) is widely used due to its excellent thermal stability, electrical insulation, and low friction characteristics. However, its significant creep behavior greatly limits its application range. Inorganic fillers can effectively improve the creep resistance of PTFE-based materials, and the interaction between the filler and the PTFE matrix plays a key role in the modification effect. This study employs two-dimensional monolayer graphene oxide (GO) as a reinforcing filler to prepare graphene oxide-polytetrafluoroethylene (GO-PTFE) composites, achieving a significant enhancement in creep resistance. The surface of graphene oxide is rich in oxygen-containing functional groups, which can form strong interfacial hydrogen bonds with fluorine atoms in the PTFE matrix. Theoretical calculations and molecular dynamics simulations indicate that there is a strong intermolecular interaction in GO-PTFE composites. This interaction effectively restricts the movement of PTFE molecular chains, reduces their slippage and deformation under external forces, and thereby decreases the material's creep extent.

Key words: Hydrogen bonding, Filling modification, Polytetrafluoroethylene, Creep resistance

刘柯, 高琪, 李海丰, 刁立鹏, 陈学刚, 李道浩, 吴广磊. 基于氧化石墨烯-聚四氟乙烯氢键分子间作用的抗蠕变性能增强研究[J]. 物理化学学报, 2026, 42(8), 100315. doi: 10.1016/j.actphy.2026.100315

Ke Liu, Qi Gao, Haifeng Li, Lipeng Diao, Xuegang Chen, Daohao Li, Guanglei Wu. Hydrogen-bonding intermolecular interaction between graphene oxide and polytetrafluoroethylene enhanced creep resistance[J]. Acta Phys. -Chim. Sin. 2026, 42(8), 100315. doi: 10.1016/j.actphy.2026.100315

链接本文: https://www.whxb.pku.edu.cn/CN/10.1016/j.actphy.2026.100315

https://www.whxb.pku.edu.cn/CN/Y2026/V42/I8/100315

图/表 6

参考文献 48

1	O. Ayurova, V. Kornopoltsev, A. Khagleev, R. Kurbatov, U. Mishigdorzhiyn, A. Dyakonov, D. Mognonov. Lubricants 2024, 12, 29. doi: 10.3390/lubricants12020029
2	Y. Cheng, X. Liu, J. Ren, X. Xu, D. Lan, G. Wu, S. Zhang, Z. Gao, Z. Jia, G. Wu. Carbon 2025, 239, 120325. doi: 10.1016/j.Carbon2025.120325
3	H. Ren, H. Zhao, J. Ning. Mech. Mater. 2024, 189, 104871. doi: 10.1016/j.mechmat.2023.104871
4	P. T. Xie, H. K. Wu, Z. X. Cheng, M. X. Liu, Y. Liu, W. K. Pang, R. H. Fan, Y. Liu. Adv. Mater. 2026, 38, e16951. doi: 10.1002/adma.202516951
5	J. Chai, G. Wang, A. Zhang, X. Li, Z. Xu, J. Zhao, G. Zhao. Chem. Eng. J. 2023, 461, 141971. doi: 10.1016/j.cej.2023.141971
6	Y. Y. Gu, J. Shi, D. Nematov, A. Q. Liu, Y. R. Yin, H. L. Dai, L. Bi. Mater. Sci. Eng. B 2026, 327, 119260. doi: 10.1016/j.mseb.2026.119260
7	S. Yang, Y. R. Yin, S. Boulfrad, H. L. Dai, S. F. Yu, Y. Y. Gu, L. Bi. Adv. Funct. Mater. 2026, e74539. doi: 10.1002/adfm.74539
8	D. Lan, J. Wang, Y. Wang, X. Guo, D. Du, C. Zhang, G. Wu. Carbon 2026, 253, 121416. doi: 10.1016/j.Carbon2026.121416
9	S. Song, B. Zheng, L. Chen, H. Shu, D. Gao, D. Lan, T. Li, X. Liu, Y. Ma. J. Energy Storage 2025, 134, 118282. doi: 10.1016/j.est.2025.118282
10	P. Qiao, J. Dai, Z. Niu, Y. Li, D. Lan, Y. Yi, Y. Cao, Y. Wang, L. Chen. J. Polym. Res. 2026, 33, 49. doi: 10.1007/s10965-026-04773-1
11	L. Zhou, Y. R. Yin, D. Nematov, H. L. Dai, Y. Y. Gu, S. F. Yu, L. Bi. Sustain. Mater. Technol. 2026, 48, e01936. doi: 10.1016/j.susmat.2026.e01936
12	W. Lv, T. Wang, Q. Wang, K. K. Yap, F. Song, C. Wang. Polymers 2024, 16, 894. doi: 10.3390/polym16070894
13	X. Chen, C. Dai, T. Zhang, P. Xu, W. Ke, J. Wu, M. Qiu, K. Fu, Y. Fan. Chem. Eng. J. 2022, 425, 134972. doi: 10.1016/j.cej.2022.134972
14	W. H. Song, X. C. Dong, Y. R. Yin, S. F. Yu, Y. Y. Gu, L. Bi. J. Adv. Ceram. 2026, 15, 9221262. doi: 10.26599/JAC.2026.9221262
15	M. Ma, D. Lan, L. Zhang, Y. Wang, Z. Jia, Z. Gao, H. Qiu, G. Wu. J. Mater. Sci. Technol. 2026, 273, 69. doi: 10.1016/j.jmst.2026.03.014
16	A. P. Vasilev, T. S. Struchkova, L. A. Nikiforov, A. A. Okhlopkova, P. N. Grakovich, E. L. Shim, J. H. Cho. Molecules 2019, 24, 224. doi: 10.3390/molecules24020224
17	T. Zhao, X. Guo, Z. Gao, Z. Jia, D. Lan, G. Wu. Carbon 2026, 254, 121509. doi: 10.1016/j.Carbon2026.121509
18	X. Wang, B. Liu, G. Zhang, L. Liu, Q. Chen, W. Chen, X. Li. Surf. Interface Anal. 2017, 49, 112. doi: 10.1002/sia.6066
19	G. Zhao, C. Wu, L. Zhang, J. Song, Q. Ding. Polym. Adv. Technol. 2018, 29, 1487. doi: 10.1002/pat.4260
20	B. Liang, Y. Zhao, S. Wang, S. Huang, F. Zhou, C. Zhang, Y. Wang, X. Guo. Acta Phys. -Chim. Sin. 2026, 42, 100285. doi: 10.1016/j.actphy.2026.100285
21	Z. L. Cheng, X. Y. Chang, Z. Liu, D. Z. Qin. Micro Nano Lett. 2019, 14, 91. doi: 10.1049/mnl.2018.5195
22	F. Wang, J. Ci, J. Fan. Polymers 2022, 14, 3903. doi: 10.3390/polym14153093
23	Y. Lu, X. Li, C. Wu, S. J. Xu. J. Alloy. Compd. 2018, 750, 197. doi: 10.1016/j.jallcom.2018.03.301
24	X. Liu, X. Ma, L. Zhu, L. Zhu. Ind. Crops. Prod. 2021, 164, 113352. doi: 10.1016/j.indcrop.2021.113352
25	L. M. Ramaniah, C. Kamal, R. J. Kshirsagar, A. Chakrabarti, A. Banerjee. Mol. Phys. 2013, 111, 3067. doi: 10.1080/00268976.2013.770174
26	X. Gao, Y. Liu, H. Li, J. Bian, Y. Zhao, Y. Cao, Y. Mao, X. Li, Y. Xu, Y. Ozaki, et al.. Mol. Struct. 2013, 1040, 122. doi: 10.1016/j.molstruc.2013.02.017
27	S. Mao, R. Miao, D. Lan, S. Zhang, J. Zhou, X. Liu, S. Du, Z. Zhao, G. Wu. Acta Phys. -Chim. Sin. 2026, 42, 100279. doi: 10.1016/j.actphy.2026.100279
28	N. Verma, Y. Tao, E. Kraka. J. Phys. Chem. B 2021, 125, 2551. doi: 10.1021/acs.jpcb.0c11392
29	R. Delmelle, P. Ngene, B. Dam, D. Bleiner, A. Borgschulte. ChemCatChem 2016, 8, 1646. doi: 10.1002/cctc.201600168
30	A. Palov, H. Fujii, Y. Mankelevich, T. Rakhimova, M. Baklanov. Polym. Degrad. Stab. 2012, 97, 802. doi: 10.1016/j.polymdegradstab.2012.01.027
31	G. J. Zhang, K. Yang, W. B. Zhao, Z. Yan. Appl. Surf. Sci. 2006, 253, 1995. doi: 10.1016/j.apsusc.2006.03.082
32	L. Diao, Q. Gao, N. Zhang, Q. Dai, X. Zhang, D. Li, D. Yang, X. She. Compos. Commun. 2023, 39, 101533. doi: 10.1016/j.coco.2023.101533
33	J. Fan, M. Yan, J. Huang, L. Cao, Y. Chen. Ind. Eng. Chem. Res. 2019, 58, 15199. doi: 10.1021/acs.iecr.9b03028
34	M. Maroufkhani, A. Katbab, W. Liu, J. Zhang. Polymer 2017, 115, 37. doi: 10.1016/j.polymer.2017.03.025
35	Y. Liu, X. Su, D. Lan, J. Liu, W. Ma, Y. Liu. Acta Phys. -Chim. Sin. 2026, 42, 100276. doi: 10.1016/j.actphy.2026.100276
36	S. Schöche, N. Hong, M. Khorasaninejad, A. Ambrosio, E. Orabona, E. Maddalena, P. Capasso. Appl. Surf. Sci. 2017, 421, 778. doi: 10.1016/j.apsusc.2017.01.035
37	P. Kumar, M. Šilhavík, Z. A. Zafar, J. Červenka. J. Phys. Chem. C 2023, 127, 10599. doi: 10.1021/acs.jpcc.3c01534
38	A. Stefanović D. Kepić M. Momčilović J. L. Mead, M. Huskić K. Haddadi, M. Sebbache, B. T. Marković S. Jovanović. Nanomaterials 2024, 14, 912. doi: 10.3390/nano14110912
39	Y. Bu, K. Li, F. Guo, Z. Liang, J. Zhang. Appl. Surf. Sci. 2022, 606, 154920. doi: 10.1016/j.apsusc.2022.154920
40	S. W. Pattinson, R. E. Diaz, N. A. Stelmashenko, A. H. Windle, C. Ducati, E. A. Stach, K. K. K. Koziol. Chem. Mater. 2013, 25, 2921. doi: 10.1021/cm401216q
41	A. Atta, E. Abdeltwab, A. Bek. Surf. Topogr. 2021, 9, 025013. doi: 10.1088/2051-672X/abf9f5
42	W. Sun, X. Liu, K. Liu, J. Xu, Y. Lu, J. Ye. Carbon 2021, 184, 312. doi: 10.1016/j.Carbon2021.08.042
43	Z. Wang, Z. Gao, Z. Jia, D. Lan, G. Wu. Carbon 2026, 255, 121535. doi: 10.1016/j.Carbon2026.121535
44	S. Zhao, X. Guo, Z. Gao, Z. Jia, D. Lan, G. Wu. Carbon 2025, 254, 121509. doi: 10.1016/j.Carbon2026.121509
45	R. Feng, C. Fan, D. Lan, L. Liu, Q. He, Y. Wang. Acta Phys. -Chim. Sin. 2026, 42, 100301. doi: 10.1016/j.actphy.2026.100301
46	K. Endo, S. Shimada, N. Kato, T. Ida. J. Mol. Struct. 2016, 1122, 341. doi: 10.1016/j.molstruc.2016.04.087
47	K. Liu, S. Yang, W. Li, Y. Wang, C. Sun, L. Peng, H. Garcia. Fuel. 2023, 337, 126840. doi: 10.1016/j.fuel.2022.126840
48	M. Keramatinia, B. Ramezanzadeh, M. Mahdavian, G. Bahlakeh. Chem. Eng. J. 2022, 437, 135241. doi: 10.1016/j.cej.2022.135241

[1]	吴智伟, 丁伟璐, 张雅琴, 王艳磊, 何宏艳. 咪唑类离子液体与酪氨酸相互作用及机理的密度泛函理论研究[J]. 物理化学学报, 2021, 37(10): 2002021 - .
[2]	范智博,龚晓庆,逯丹凤,高然,祁志美. 基于色相算法的表面等离子体共振成像传感器对苯并芘的敏感特性[J]. 物理化学学报, 2017, 33(5): 1001 -1009 .
[3]	廖芝建,秦振立,杜思南,李思雨,陈冠侯,左芳,罗建斌. 液晶/水界面上的氢键作用诱导液晶取向转变[J]. 物理化学学报, 2015, 31(9): 1733 -1740 .
[4]	元福卿, 刘丹丹, 郭兰磊, 祝仰文, 徐志成, 黄建滨, 张磊, 张路. 支链化阳离子和甜菜碱表面活性剂对聚四氟乙烯表面润湿性的影响[J]. 物理化学学报, 2015, 31(4): 715 -721 .
[5]	胡嵩霜,张磊,徐志成,宫清涛,靳志强,张路,赵濉. 苄基取代甜菜碱对聚四氟乙烯表面润湿性的影响[J]. 物理化学学报, 2015, 31(10): 1924 -1931 .
[6]	钟金莲, 潘虹, 罗序中, 洪三国, 张宁, 黄建滨. L-苯丙氨酸衍生物与脂肪胺构筑双组分超分子凝胶[J]. 物理化学学报, 2014, 30(9): 1688 -1696 .
[7]	钱佳晟, 刘明贤, 甘礼华, 吕耀康, 陈玲艳, 叶瑞杰, 陈龙武. 基于含锌有机配位聚合物的微孔碳的合成及其电化学性能[J]. 物理化学学报, 2013, 29(07): 1494 -1500 .
[8]	丁志忠, 董永春, 李冰, 李淼. 改性PTFE纤维金属配合物的制备及其光催化降解性能[J]. 物理化学学报, 2013, 29(01): 157 -166 .
[9]	何睿, 焦艳华, 梁媛媛, 陈灿玉. 有机和生物晶体固态核磁共振参数的准确预测[J]. 物理化学学报, 2011, 27(09): 2051 -2058 .
[10]	郝平, 高云燕, 欧植泽, 李嫕, 王中丽, 王雪松. 氨基吡啶修饰碳纳米管的制备及其与辣根过氧化酶的相互作用[J]. 物理化学学报, 2011, 27(01): 233 -240 .
[11]	李芬, 徐献芝, 宋辉, 熊晋, 吴飞. 粘结剂聚四氟乙烯乳液经过乙醇预处理后对气体扩散电极性能的影响[J]. 物理化学学报, 2009, 25(11): 2205 -2210 .
[12]	郎需庆;马红钦;谭欣;朱慧铭. PTFE超细颗粒的表面活化与化学接枝[J]. 物理化学学报, 2005, 21(07): 703 -706 .
[13]	张莉;杨展澜;熊尧;彭疼疼;翁诗甫;吴瑾光. H^＋对水溶液中脱氧胆酸钠聚集体的影响[J]. 物理化学学报, 2004, 20(10): 1196 -1199 .

基于氧化石墨烯-聚四氟乙烯氢键分子间作用的抗蠕变性能增强研究

Hydrogen-bonding intermolecular interaction between graphene oxide and polytetrafluoroethylene enhanced creep resistance

RichHTML

PDF

赞

可视化

摘要/Abstract

引用本文

使用本文

图/表 6

参考文献 48

相关文章 13

Metrics

推荐阅读 0