掺铝氧化锌纳米晶的超声-水热协同控制合成及其光催化性能

doi:10.3866/PKU.WHXB201207163

Abstract

Abstract:

Aluminum doped zinc oxide (ZAO) nanocrystals approximately 20 nm in diameter and with good dispersity and crystallinity were efficiently synthesized through a synergistic combination of ultrasonic and hydrothermal methods. The morphologies, structures, and optical properties of these nanocrystals, as well as the thermochemistry of the precursor, were determined using transmission electron microscopy (TEM), powder X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy, ultraviolet-visible (UV-Vis) spectroscopy, and thermogravimetric-differential thermal analysis (TG-DTA). ZAO nanocrystals were investigated with regard to the photocatalysis of rhodamine B (RhB) in solution, including studies of degradation rates and catalysis mechanism. It was found that both the particle size and crystallinity of the material can be controlled through the ultrasonic/hydrothermal synergetic effect. The main absorption peak of the product in a typical UV-Vis spectrum appeared at ~369 nm and its energy band gap was determined to be 3.36 eV. The ZAO produced by this method exhibits enhanced photocatalytic activity; compared to catalysis by materials produced solely by ultrasonic or hydrothermal routes, the degradation time of an RhB solution is reduced by 77.8%. In addition, it was found that this ZAO photocatalyst may be recycled and used more than once.

Key words: Ultrasonic route, Hydrothermal route, Aluminum doped zinc oxide, Nanocrystal, Photocatalysis

YANG Xiao-Hong, TONG Qin, LIU Chang, LIU Jin-Ku, HE Wen-Zhi, LI Guang-Ming. Photocatalytic Properties of Aluminum Doped Zinc Oxide Nanocrystals Controlled Prepared via a Synergistic Ultrasonic/Hydrothermal Technique[J]. Acta Phys. -Chim. Sin. 2012, 28(11), 2713-2720. doi: 10.3866/PKU.WHXB201207163

References

(1) Luo, C. X.;Wang, Y.; Liu, J. K.; Lian, J. S.; Chai, C. F. Acta Phys. -Chim. Sin. 2008, 24, 1007. [罗重霄, 王燕, 刘金库,连加松, 柴春芳. 物理化学学报, 2008, 24, 1007.] doi: 10.3866/PKU.WHXB20080616
(2) Luo, C. X.; Liu, J. K.; Lu, Y.; Du, C. S. Mater. Sci. Eng. C 2012,33, 680.
(3) Zhang, L. L.; Xie, H. Z.; Zhang, M.; Liu, J. K. Nano 2012, 7,1250017.
(4) Shi, H.W.; Xie, H. Z.; Liu, J. K.;Wang, Y. Nano 2010, 5, 215.doi: 10.1142/S1793292010002128
(5) Lin, J. P.;Wu, J. M. Scripta Materialia 2009, 60, 313. doi: 10.1016/j.scriptamat.2008.10.023
(6) Lu, J.;Wang, H. Optics Express 2011, 19, 13806. doi: 10.1364/OE.19.013806
(7) Caglar, Y.; Caglar, M.; Ilican, S. Curr. Appl. Phys. 2012, 12,963. doi: 10.1016/j.cap.2011.12.017
(8) Cheng, Y. C. Appl. Surf. Sci. 2011, 258, 604. doi: 10.1016/j.apsusc.2011.07.124
(9) Mamat, M. H.; Khusaimi, Z.; Musa, M. Z.; Malek, M. F.;Rusop, M. Sensors and Actuators A: Physical 2011, 171, 241.doi: 10.1016/j.sna.2011.07.002
(10) Buonsanti, R.; Llordes, A.; Aloni, S.; Helms, B. A.; Milliron, D.J. Nano Lett. 2011, 11, 4706. doi: 10.1021/nl203030f
(11) Fouad, O. A.; Rahman, A. E.; Khder. S.; Dai, Q.; El-Shall, M. S.J. Nanopart. Res. 2011, 13, 7075. doi: 10.1007/s11051-011-0620-8
(12) Kim, K. P.; Chang, D.; Lim, S. K.; Lee, S. K.; Lyu, H. K.;Hwang, D. K. Curr. Appl. Phys. 2011, 11, 1311. doi: 10.1016/j.cap.2011.03.065
(13) Gan, L. H.; Liu, M. X.; Chen, L.W.; Hu, J.; Liu, H. L. Acta Phys. -Chim. Sin. 2010, 26, 2666. [甘礼华, 刘明贤, 陈龙武,胡军, 刘洪来. 物理化学学报, 2010, 26, 2666.] doi: 10.3866/PKU.WHXB20100933
(14) Li, Y. Y.; Yan, B.; Guo, L.; Li, Y. J. Microporous Mesoporous Mat. 2012, 148, 73. doi: 10.1016/j.micromeso.2011.07.020
(15) Zhang, J.; Hao, J.;Wei, Y. G.; Xiao, F. P.; Yin, P. C.;Wang, L. S.J. Am. Chem. Soc. 2010, 132, 5956. doi: 10.1021/ja101671q
(16) Zhang, Q.; Yan, B. Chem. Commun. 2011, 47, 5867. doi: 10.1039/c1cc11367d
(17) Zhang, L.; Shen, Y. H.; Xie, A. J. J. Mater. Chem. 2009, 19,1884. doi: 10.1039/b817071a
(18) Liu, J. K.; Luo, C. X.; Yang, X. H.; Zhang, X. Y. Mater. Lett.2009, 63, 124. doi: 10.1016/j.matlet.2008.09.029
(19) Wang, J. D.; Luo, C. X.; Liu, J. K.; Lu, Y.; Li, G. M. Nano2010, 5, 271. doi: 10.1142/S1793292010002177
(20) Xu, K.; Shen, L. F.; Mi, C. H.; Zhang, X. G. Acta Phys. -Chim. Sin. 2012, 28, 105. [徐科, 申来法, 米常焕, 张校刚. 物理化学学报, 2012, 28, 105.] doi: 10.3866/PKU.WHXB201228105
(21) Liu, J. K.; Cao, T. J.; Lu, Y.; Luo, C. X. Mater. Technol. 2009,24, 88.
(22) Liu, Y. F.; Ma, X. G.; Yi, X.; Zhu, Y. F. Acta Phys. -Chim. Sin.2012, 28, 654. [刘艳芳, 马新国, 易欣, 朱永法. 物理化学学报, 2012, 28, 654.] doi: 10.3866/PKU.WHXB201112232
(23) Major, C.; Nemeth, A.; Radnoczi, G.; Czigany, Z.; Fried, M.;Labadi, Z.; Barsony, I. Appl. Surf. Sci. 2009, 255, 8907. doi: 10.1016/j.apsusc.2009.06.088
(24) Li, Z. Q.; Xiong, Y. J.; Xie, Y. Inorg. Chem. 2003, 42, 8105. doi: 10.1021/ic034029q
(25) Han, D.; Ren, X. L.; Chen, D.; Tang, F. Q.;Wang, D.; Ren, J. Photographic Science and Photochemistry 2005, 23, 414.[韩冬, 任湘菱, 陈东, 唐芳琼, 王冬, 任俊. 感光科学与光化学, 2005, 23, 414.]
(26) Yin, X. G.; Zhang, Q. K.; Liu, J. K.; Zhong, X. H.; Chai, R.;Lian, J. S.; Chai, C. F. Acta Phys. -Chim. Sin. 2009, 25, 1443.[尹晓光, 张琪凯, 刘金库, 钟新华, 柴瑞, 连加松, 柴春芳.物理化学学报, 2009, 25, 1443.] doi: 10.3866/PKU.WHXB20090724
(27) Yang, X. H.; Liu, C.; Liu, J. K.; Zhu, Z. C. Acta Phys. -Chim. Sin. 2011, 27, 2939. [杨小红, 刘畅, 刘金库, 朱子春. 物理化学学报, 2011, 27, 2939.] doi: 10.3866/PKU.WHXB20112939
(28) Hsiao, K. C.; Liao, S. C.; Chen, Y. J. Mater. Sci. Eng. A 2007,447, 71. doi: 10.1016/j.msea.2006.10.116
(29) Zhang, L.W.; Cheng, H. Y.; Zong, R. L.; Zhu, Y. F. J. Phys. Chem. C 2009, 113, 2368. doi: 10.1021/jp807778r
(30) Wu, Y.; Gao, J.; He, Y. M.;Wu, T. H. Appl. Surf. Sci. 2012, 258,4922. doi: 10.1016/j.apsusc.2012.01.120
(31) He, Y. M.;Wang, Y. J.; Zhao, L. H.;Wu, X. T.;Wu, Y. J. Mol. Catal. A-Chem. 2011, 337, 61. doi: 10.1016/j.molcata.2011.01.015
(32) Cong, Y. Q.; Li, Z.;Wang, Q.; Zhang, Y.; Xu, Q.; Fu, F. X. Acta Phys. -Chim. Sin. 2012, 28, 1489. [丛燕青, 李哲, 王齐,张轶, 徐谦, 伏芳霞. 物理化学学报, 2012, 28, 1489.]doi: 10.3866/PKU.WHXB201203221
(33) Su, Y. L.; Li, Y.; Du, Y. X.; Lei, L. C. Acta Phys. -Chim. Sin.2011, 27, 939. [苏雅玲, 李轶, 杜瑛珣, 雷乐成. 物理化学学报, 2011, 27, 939.] doi: 10.3866/PKU.WHXB20110401
(34) Bi, D. Q.; Xu, Y. M. Acta Phys. -Chim. Sin. 2012, 28, 1777.[毕冬琴, 许宜铭. 物理化学学报, 2012, 28, 1777.] doi: 10.3866/PKU.WHXB201205113
(35) Li, H. Q.; Cui, Y. M.;Wu, X. C.; Hua, L.; Hong,W. S. Acta Phys. -Chim. Sin. 2012, 28, 1985. [李慧泉, 崔玉民, 吴兴才,华林, 洪文珊. 物理化学学报, 2012, 28, 1985.] doi: 10.3866/PKU.WHXB201205161
(36) Lin, X.; Guan, Q. F.; Li, H. B.; Li, H. J.; Ba, C. H.; Deng, H. D.Acta Phys. -Chim. Sin. 2012, 28, 1481. [林雪, 关庆丰, 李海波, 李洪吉, 巴春华, 邓海德. 物理化学学报, 2012, 28, 1481.]doi: 10.3866/PKU.WHXB201203313

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Photocatalytic Properties of Aluminum Doped Zinc Oxide Nanocrystals Controlled Prepared via a Synergistic Ultrasonic/Hydrothermal Technique

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