硬模板法合成磁性石墨化介孔碳及在中药废水吸附处理中的应用

doi:10.3866/PKU.WHXB201212123

Abstract

Abstract:

Magnetically graphitic mesoporous carbon (Fe/GMC) was synthesized, using SBA-15 as a template and sucrose as a carbon source, with the assistance of ferric nitrate impregnation. The properties of the products were characterized using powder X-ray diffraction (XRD), transmission electron microscopy (TEM), N₂ adsorption-desorption (BET), and Raman spectroscopy. The impregnation of Fe³⁺ promoted the partial graphitization of ordered mesoporous carbon at low temperature (900℃), and resulted in the production of magnetic Fe₃O₄ particles. These complex materials possessed an ordered mesoporous pore structure, large surface area, and magnetic properties. The adsorption properties of Fe/GMC for traditional Chinese medicine wastewater were studied in detail using UV-Vis spectroscopy. The results showed that the Fe/GMC materials displayed rapid adsorption, and had a high adsorption capacity. Fe/GMC could be used as an absorbent for the highly efficient removal of pigments from Carthamus tinctorius flowers via rapid solid-liquid magnetic separation.

Key words: SBA-15, Hard template, Mesoporous carbon, Graphitization, Magnetic Fe₃O₄

HONG Zhou-Qin, LI Jin-Xia, ZHANG Fang, ZHOU Li-Hui. Synthesis of Magnetically Graphitic Mesoporous Carbon from Hard Templates and Its Application in the Adsorption Treatment of Traditional Chinese Medicine Wastewater[J]. Acta Phys. -Chim. Sin. 2013, 29(03), 590-596. doi: 10.3866/PKU.WHXB201212123

References

(1) Xing,W.; Bai, P.; Li, Z. E.; Yu, R. J.; Yan, Z. F.; Lu, G. Q.; Lu,L. M. Electrochim. Acta 2006, 51, 4626. doi: 10.1016/j.electacta.2006.01.008
(2) Su, F. B.; Zhao, X. S.;Wang, Y.; Zeng, J. H.; Zhou, Z. C.; Lee,J. Y. J. Phys. Chem. B 2005, 109 (43), 20200. doi: 10.1021/jp0541967
(3) Wang, H.; Lam, F. L. Y.; Hu, X. J.; Ng, K. M. Langmuir 2006,22 (10), 4583. doi: 10.1021/la052615l
(4) Gaslain, F. O. M.; Parmenfier, J.; Valtehev, V. P.; Patarin, J.Chem. Commun. 2006, 991.
(5) Gu, Z. M.; Deng, B. L.; Yang, J. Microporous Mesoporous Mat.2007, 102, 265. doi: 10.1016/j.micromeso.2007.01.011
(6) Xu, D. P.; Yoon, S. H.; Mochida, I.; Qiao,W. M.;Wang, Y. G.;Ling, L. C. Microporous Mesoporous Mat. 2008, 115, 461. doi: 10.1016/j.micromeso.2008.02.021
(7) Li, H.; Xi, H. A.; Zhu, S.Wen, Z. Y.;Wang, R. D. MicroporousMesoporous Mat. 2006, 96 (1/3), 357.
(8) Marsh, H.; Crawford, D.; Taylor, D.W. Carbon 1983, 21, 81.doi: 10.1016/0008-6223(83)90160-4
(9) Oya, A.; Yoshida, S.; Alcaniz-Monje, J.; Linares-Solano, A.Carbon 1995, 33, 1085. doi: 10.1016/0008-6223(95)00054-H
(10) Lee, J.W.; Jin, S. M.; Hwang, Y. S.; Park, J. G.; Park, H. M.;Hyeon, T. H. Carbon 2005, 43, 2536. doi: 10.1016/j.carbon.2005.05.005
(11) Lei, Z. B.; Xiao, Y.; Dang, L. Q.; Bai, S. Y.; An, L. Z.Microporous Mesoporous Mat. 2008, 109, 109. doi: 10.1016/j.micromeso.2007.04.035
(12) Yuan, J. Y.; Giordano, C.; Antonietti, M. Chem. Mater. 2010, 22,5003. doi: 10.1021/cm1012729
(13) Li, J. S.; Gu, J.; Ling, X. F.; Sun, X. Y.; Shen, J. Y.; Han,W. Q.;Wang, L. Q. Acta Phys. -Chim. Sin. 2011, 27, 1772. [李建生,顾娟, 凌晓风, 孙秀云, 沈锦优, 韩卫清, 王连军. 物理化学学报, 2011, 27, 1772.] doi: 10.3866/PKU.WHXB20110613
(14) Maldonado-Hodar, F. J.; Moreno-Castilla, C.; Rivera-Utrilla, J.;Hanzawa, Y.; Yamada, Y. Langmuir 2000, 16, 4367. doi: 10.1021/la991080r
(15) Ryoo, R.; Joo, S. H.; Jun, S. J. Phys. Chem. B 1999, 103, 7743.doi: 10.1021/jp991673a
(16) Ryoo, R.; Joo, S. H.; Kruk, M.; Jaroniec, M. Adv. Mater. 2001,13, 677. doi: 10.1002/1521-4095(200105)13:9<>1.0.CO;2-3
(17) Kaneda, M.; Tsubakiyama, T.; Carlsson, A.; Sakamato, Y.;Ohsuma, T.; Terasaki, O. J. Phys. Chem. B 2002, 106, 1256.
(18) Kruk, M.; Jaroniec, M.; Kim, T.W.; Ryoo, R. Chem. Mater.2003, 15, 2815. doi: 10.1021/cm034087+
(19) Qi, J.; Jiang, L. H.; Tang, Q.W.; Zhu, S.;Wang, S. L.; Yi, B. L.;Sun, G. Q. Carbon 2012, 2824.
(20) Wang, L. F.; Lin, S.; Lin, K. F.; Yin, C. Y.; Liang, D. S.; Di, Y.;Fan, P.W.; Jiang, D. Z.; Xiao, F. S. Microporous MesoporousMat. 2005, 85, 136. doi: 10.1016/j.micromeso.2005.06.005
(21) Jun, S.; Joo, S. H.; Ryoo, R.; Kruk, M.; Jaroniec, M.; Liu, Z.;Ohsuna, T.; Terasaki, O. J. Am. Chem. Soc. 2000, 122, 10712.doi: 10.1021/ja002261e
(22) Zhao, D. Y.; Feng, J. L.; Huo, Q. S.; Melosh, N.; Fredrickson,G. H.; Chmelka, B. F.; Stucky, G. D. Science 1998, 279, 548.doi: 10.1126/science.279.5350.548
(23) Yang, C. M.; Kalwei, M.; Schuth, F.; Chao, K. J. Appl. Catal. A:Gen. 2003, 254, 289. doi: 10.1016/S0926-860X(03)00490-3
(24) Wang, L.; Qi, T.; Zhang, Y.; Chu, J. L. Microporous MesoporousMat. 2006, 91, 156. doi: 10.1016/j.micromeso.2005.11.042
(25) Chai, S. H.; Howe, J. Y.;Wang, X. Q.; Kidder, M.; Schwartz, V.;Golden, M. L.; Overbury, S. H.; Dai, S.; Jiang, D. Carbon 2012,50, 1574. doi: 10.1016/j.carbon.2011.11.036
(26) Kurk, M.; Kohlhaas, K. M.; Dufour, B.; Celer, E. B.; Jaronicc,M.; Mat, K.; Ruoff, R. S.; Kowalcwaki, T. MicroporousMesoporous Mat. 2007, 102, 178. doi: 10.1016/j.micromeso.2006.12.027

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Synthesis of Magnetically Graphitic Mesoporous Carbon from Hard Templates and Its Application in the Adsorption Treatment of Traditional Chinese Medicine Wastewater

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