有序介孔碳负载NiCo2O4电极的制备及其超电容性能

doi:10.3866/PKU.WHXB201202074

Acta Phys. -Chim. Sin. ›› 2012, Vol. 28 ›› Issue (04): 837-842.doi: 10.3866/PKU.WHXB201202074

• ELECTROCHEMISTRY AND NEW ENERGY • Previous Articles Next Articles

Preparation of Ordered Mesoporous Carbon/NiCo₂O₄ Electrode and Its Electrochemical Capacitive Behavior

CHE Qian, ZHANG Fang, ZHANG Xiao-Gang, LU Xiang-Jun, DING Bing, ZHU Jia-Jia

College of Material Science & Engneering, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, P. R. China

Received:2011-10-31 Revised:2012-02-01 Published:2012-03-21
Contact: ZHANG Xiao-Gang E-mail:azhangxg@163.com
Supported by:
The project was supported by the National Natural Science Foundation of China (20873064), Natural Science Foundation of Jiangsu Province, China (BK2011030), and Specialized Research Fund for the Doctoral Program of Higher Education of China (20060287026).

Abstract

Abstract: OMC/NiCo₂O₄ composite was prepared by co-precipitation with ordered mesoporous carbon (OMC) as a support. The crystalline structure and morphology of the composite were investigated by X-ray diffraction (XRD), Fourier-transform infrared (FT-IR) spectroscopy, and transmission electron microscopy (TEM). TEM images showed that NiCo₂O₄ was uniformly coated on the OMC. Cyclic voltammetry and galvanostatic charge-discharge were used to investigate the electrochemical performance of the OMC/ NiCo₂O₄ composite. The specific capacitances of the OMC/NiCo₂O₄ composite with a mass fraction of 40% NiCo₂O₄ were 577.0 F·g^-1 at a current density of 1 A·g^-1 and 470.8 F·g^-1 at 8 A·g^-1. The specific capacitance remains at 508.4 F·g^-1 after 2000 cycles at a current density of 2 A·g^-1, with a capacitance retention of 92.7%.

Key words: Supercapacitor, Ordered mesoporous carbon, NiCo₂O₄, Co-precipitation method

CHE Qian, ZHANG Fang, ZHANG Xiao-Gang, LU Xiang-Jun, DING Bing, ZHU Jia-Jia. Preparation of Ordered Mesoporous Carbon/NiCo₂O₄ Electrode and Its Electrochemical Capacitive Behavior[J].Acta Phys. -Chim. Sin., 2012, 28(04): 837-842.

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Preparation of Ordered Mesoporous Carbon/NiCo₂O₄ Electrode and Its Electrochemical Capacitive Behavior

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Preparation of Ordered Mesoporous Carbon/NiCo₂O₄ Electrode and Its Electrochemical Capacitive Behavior