298.15 K时斯蒂芬酸钾盐和铯盐在水和DMF中的溶解热

doi:10.3866/PKU.WHXB201212202

Abstract

Abstract:

The dissolution and thermochemical properties of potassium styphnate [K₂(TNR)(H₂O)]_n and cesium styphnate [Cs₂(TNR)(H₂O)₂]_n in water and N,N-dimethylformamide (DMF) at 298.15 K were studied by calorimetry. The processes are endothermic in water, and exothermic in DMF because of the different molecular structure and polarity of the solutes and solvents. Empirical formulas for the solution enthalpies (Δ_solH), relative apparent molar solution enthalpies (ФL_i), relative partial molar enthalpies (L_i), and dilution enthalpies (Δ_dilH_1,2) are deduced by polynomial expressions, and standard solution enthalpies (Δ_solH_m^θ) are also calculated.

Key words: Dissolving process, Thermochemistry, 2,4,6-Trinitro-resorcinol, Solution enthalpy, Dilution enthalpy

LIU Ying, TONG Wen-Chao, YANG Li, ZHANG Tong-Lai, FENG Chang-Gen. Solution Heat of Potassium Styphnate and Caesium Styphnate in Water and DMF at 298.15 K[J]. Acta Phys. -Chim. Sin. 2013, 29(03), 467-472. doi: 10.3866/PKU.WHXB201212202

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Solution Heat of Potassium Styphnate and Caesium Styphnate in Water and DMF at 298.15 K

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