没食子酸铋锆的制备、表征及其燃烧催化作用

doi:10.3866/PKU.WHXB20130111

Abstract

Abstract:

Bismuth/zirconium gallate (Gal-BiZr) was synthesized from gallic acid, bismuth nitrate, and zirconyl nitrate firstly, and characterized by elemental analysis, X-ray fluorescence (XRF), and Fourier transform infrared (FTIR) spectroscopies. The thermal behavior and decomposition mechanism of Gal-BiZr in a temperature-programmed mode were investigated by thermogravimetric (TG) analysis, differential scanning colorimetry (DSC), and condensed phase thermolysis/FTIR techniques. The decomposition products of Gal-BiZr are Bi₂O₃, ZrO₂, and C. Samples of propellants containing Gal-BiZr were prepared by extrusion technology, and the effect of Gal-BiZr on double-base (DB) propellant combustion properties was investigated. Gal-BiZr exhibits good catalytic behavior in the combustion of DB and Hexogeon (RDX)- CMDB propellants.

Key words: Physical chemistry, Bismuth/zirconium gallate, Propellant, Thermal behavior, Decomposition mechanism, Combustion property, Catalytic action

ZHAO Feng-Qi, ZHANG Heng, AN Ting, ZHANG Xiao-Hong, YI Jian-Hua, XU Si-Yu, WANG Ying-Lei. Preparation, Characterization and Combustion Catalytic Action of Bismuth/Zirconium Gallate[J]. Acta Phys. -Chim. Sin. 2013, 29(04), 777-784. doi: 10.3866/PKU.WHXB20130111

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Preparation, Characterization and Combustion Catalytic Action of Bismuth/Zirconium Gallate

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