固相浸渍法制备NiO/CeO2催化剂及其在CO氧化反应中的应用

doi:10.3866/PKU.WHXB201309041

Abstract

Abstract:

NiO/CeO₂ catalysts with different NiO loadings were prepared by a novel solid state impregnation method. The physical and chemical properties of these catalysts were compared with those of catalysts prepared by traditional wet impregnation method. The catalysts were tested for low temperature catalytic CO oxidation and characterized by X-ray diffraction (XRD), N₂ physical adsorption, transmission electron microscopy (TEM), H₂ temperature-programmed reduction (H₂-TPR), Raman spectrum, and X-ray photoelectron spectroscopy (XPS). CO oxidation results showed that nickel-ceria catalysts were good candidates for low temperature CO oxidation, with complete oxidation achieved at temperatures below 200 ℃. The activity of the catalysts increased with nickel loading, and those prepared using the solid state impregnation method displayed higher activities than those prepared by wet impregnation method at the same nickel loading. TEM, XPS, and H₂-TPRresults showed that solid state impregnation increased the dispersion of the nickel species on the surface of catalysts and strengthened the interactions between nickel and cerium, which benefited the reduction of nickel species. Raman results showed that the 0001 concentration of oxygen vacancies in the catalysts could be increased using the solid state impregnation method, likely because of more doped nickel ions in the ceria lattice, which promote the activation of oxygen molecules to facilitate the CO oxidation.

Key words: NiO/CeO₂, CO oxidation, Solid state impregnation, Wet impregnation, Interfacial interaction

SUN Jing-Fang, GE Cheng-Yan, YAO Xiao-Jiang, CAO Yuan, ZHANG Lei, TANG Chang-Jin, DONG Lin. Preparation of NiO/CeO₂ Catalysts by Solid State Impregnation and Their Application in CO Oxidation[J]. Acta Phys. -Chim. Sin. 2013, 29(11), 2451-2458. doi: 10.3866/PKU.WHXB201309041

References

(1) Zou, H. B.; Dong, X. F.; Lin,W. M. Chem. World 2005, 6, 367.[邹汉波, 董新法, 林维明. 化学世界, 2005, 6, 367.]
(2) Grisel, R. J. H.; Nieuwenhuys, B. E. J. Catal. 2001, 199, 48.doi: 10.1006/jcat.2000.3121
(3) Liu, Y.; Meng, M.; Yao, J. S.; Zha, Y. Q. Acta Phys. -Chim. Sin.2007, 23, 641. [刘咏, 孟明, 姚金松, 査宇清. 物理化学学报, 2007, 23, 641.] doi: 10.1016/S1872-1508(07)60041-2
(4) Yu, J.;Wu, G. S.; Mao, D. S.; Lu, G. Z. Acta Phys. -Chim. Sin.2008, 24, 1751. [俞俊, 吴贵升, 毛东森, 卢冠忠. 物理化学学报, 2008, 24, 1751.] doi: 10.1016/S1872-1508(08)60071-6
(5) Kaspar, J.; Fornasiero, P.; Graziani, M. Catal. Today 1999, 50 (2), 285. doi: 10.1016/S0920-5861(98)00510-0
(6) Shan,W. J.; Luo, M. F.; Ying, P. L.; Shen,W. J.; Li, C. Appl. Catal. A: Gen. 2003, 246, 1. doi: 10.1016/S0926-860X(02)00659-2
(7) Agula, B.; Deng, Q. F.; Jia, M. L.; Liu, Y. P.; Zhaorigetu, B.;Yuan, Z. Y. Reac. Kinet. Mech. Cat. 2011, 103, 101. doi: 10.1007/s11144-011-0296-1
(8) Zhang, Y.W.;Wang, Z. H.; Zhou, J. H.; Liu, J. Z.; Cen, K. F.Int. J. Hydrog. Energy 2009, 34, 5637. doi: 10.1016/j.ijhydene.2009.05.061
(9) Yisup, N.; Cao, Y.; Feng,W. L.; Dai,W. L.; Fan, K. N. Catal. Lett. 2005, 99, 207. doi: 10.1007/s10562-005-2121-9
(10) Ertl, G.; Knozinger, H.; Schuth, F.;Weitkamp, J. Handbook of Heterogenous Catalysis;Wiley-VCH:Weinheim, Germany,2008.
(11) Jobbagy, M.; Marino, F.; Schonbrod, B.; Baronetti, G.; Laborde,M. Chem. Mater. 2006, 18, 1945. doi: 10.1021/cm052437h
(12) Schwarz, J. A.; Contescu, C.; Contescu, A. Chem. Rev. 1995, 95,477. doi: 10.1021/cr00035a002
(13) Wang, Y. M.;Wu, Z. Y.;Wang, H. L.; Zhu, J. H. Adv. Funct. Meter. 2006, 16, 2374.
(14) Li, X. B.; Quek, X. Y.; Michel Ligthart, D. A. J.; Guo, M. L.;Zhang, Y.; Li, C.; Yang, Q. H.; Hensen, E. J. M. Appl. Catal. B: Environ. 2012, 123, 424.
(15) Medina-Mendoza, A. K.; Cortés-Jácome, M. A.; Toledo-Antonio, J. A.; Angeles-Chávez, C.; López-Salinas, E.;Cuauhtémoc-López, I.; Barrera, M. C.; Escobar, J.; Navarrete,J.; Hernández, I. Appl. Catal. B: Environ. 2011, 106, 14.
(16) Lai, S.W.; Chung, D. D. J. Mater. Sci. 1994, 29, 3128. doi: 10.1007/BF00356655
(17) Liu, J.W.; Zheng, Z. X.;Wang, J. M.;Wu, Y. C.; Tang,W. M.;Lu, J. J. Alloy. Compd. 2008, 465, 239. doi: 10.1016/j.jallcom.2007.10.055
(18) de Jongh, P. E.;Wagemans, R.W. P.; Eggenhuisen, T. M.;Dauvillier, B. S.; Radstake, P. B.; Meeldijk, J. D.; Geus, J.W.;de Jong, K. P. Chem. Mater. 2007, 19, 6052. doi: 10.1021/cm702205v
(19) Tang, C. J.; Zhang, H. L.; Sun, C. Z.; Li, J. C.; Qi, L.; Quan, Y.J.; Gao, F.; Dong, L. Catal. Commun. 2011, 12, 1075. doi: 10.1016/j.catcom.2011.03.031
(20) Tang, C. J.; Sun, J. F.; Yao, X. J.; Cao, Y.; Liu, L. C.; Ge, C. Y.;Gao, F.; Dong, L. Appl. Catal. B: Environ. 2013, doi: 10.1016/j.apcatb.2013.05.060.
(21) Mohamed, M. M.; Salama, T. M.; Othman, A. I.; El-Shobaky, G.A. Appl. Catal. A: Gen. 2005, 279, 23. doi: 10.1016/j.apcata.2004.09.040
(22) Barrio, L.; Kubacka, A.; Zhou, G.; Estrella, M.; Martínez-Arias,A.; Hanson, J.C.; Fernández-García, M.; Rodriguez, J. A.J. Phys. Chem. C 2010, 114, 12689. doi: 10.1021/jp103958u
(23) Guillén-Hurtado, N.; Atribak, I.; Bueno-Lopez, A.; García-García, A. J. Mol. Catal. A: Chem. 2010, 323, 52. doi: 10.1016/j.molcata.2010.03.010
(24) Li, Y.; Zhang, B. C.; Tang, X. L.; Xu, Y. D.; Shen,W. J. Catal. Commun. 2006, 7, 380. doi: 10.1016/j.catcom.2005.12.002
(25) Wang, Y.; Zhu, A. M.; Zhang, Y. Z.; Au, C. T.; Yang, X. F. Shi,C. Appl. Catal. B: Environ. 2008, 1, 141.
(26) Wu, Z. L.; Li, M. J.; Howe, J. Langmuir 2010, 26 (21), 16595.doi: 10.1021/la101723w
(27) Du, X. J.; Zhang, D. S.; Shi, L. Y.; Gao, R. H.; Zhang, J. P.J. Phys. Chem. C 2012, 116, 10009. doi: 10.1021/jp300543r
(28) Lin, J.; Li, L.; Huang, Y. Q.; Zhang,W. S.;Wang, X. D.;Wang,A. Q.; Zhang, T. J. Phys. Chem. C 2011, 115, 16509. doi: 10.1021/jp204288h
(29) Chen, C. S.; Lin, J. H.; You, J. H.; Yang, K. H. J. Phys. Chem. A2010, 114, 3773. doi: 10.1021/jp904434e
(30) Alifanti, M.; Baps, B. Blangenois, N.; Naud, J.; Grange, P.;Delmon, B. Chem. Mater. 2003, 15, 395. doi: 10.1021/cm021274j
(31) Yao, X. J.; Yu, Q.; Ji, Z. Y.; Lv, Y. Y.; Cao, Y.; Jin, C. T.; Gao, F.;Dong, L. Appl. Catal. B: Environ. 2013, 130-131, 293.
(32) Liu, X.W.; Zhou, K.;Wang, L.;Wang, B.; Li, Y. J. J. Am. Chem. Soc. 2009, 131, 3140. doi: 10.1021/ja808433d
(33) Luo, M. F.; Song, Y. P.; Lu, J. Q.;Wang, X. Y.; Pu, Z. Y. J. Phys. Chem. C 2007, 111, 12686. doi: 10.1021/jp0733217

[1]	Chenghuan HE, Yanglong GUO, Yun GUO, Yunsong WANG, Li WANG, Wangcheng ZHAN. Catalytic Activity of Au Nanoparticles Supported on LaMnO₃ Perovskite with Different Composition and Structure [J]. Acta Physico-Chimica Sinica, 2019, 35(4): 422-430.
[2]	Xue-Hui HUANG,Xiao-Hui SHANG,Peng-Ju NIU. Surface Modification of SBA-15 and Its Effect on the Structure and Properties of Mesoporous La_0.8Sr_0.2CoO₃ [J]. Acta Phys. -Chim. Sin., 2017, 33(7): 1462-1473.
[3]	Mingshu CHEN. Toward Understanding the Nature of the Active Sites and Structure-Activity Relationships of Heterogeneous Catalysts by Model Catalysis Studies [J]. Acta Phys. -Chim. Sin., 2017, 33(12): 2424-2437.
[4]	Yong-Bing GU,Qiu-Xia CAI,Xian-Lang CHEN,Zhen-Zhan ZHUANG,Hu ZHOU,Gui-Lin ZHUANG,Xing ZHONG,Dong-Hai MEI,Jian-Guo WANG. Theoretical Insights into Role of Interface for CO Oxidation on Inverse Al₂O₃/Au(111) Catalysts [J]. Acta Phys. -Chim. Sin., 2016, 32(7): 1674-1680.
[5]	Yong-Chang JIA,Shu-Yuan WANG,Lian MENG,Ji-Qing LU,Meng-Fei LUO. Effects of Zr Addition on CO and CH₄ Catalytic Oxidation over PdO/PdO/Ce_1-xPd_xO_2-δ Catalyst [J]. Acta Phys. -Chim. Sin., 2016, 32(7): 1801-1809.
[6]	Wei-Xin HUANG,Kun QIAN,Zong-Fang WU,Shi-Long CHEN. Structure-Sensitivity of Au Catalysis [J]. Acta Phys. -Chim. Sin., 2016, 32(1): 48-60.
[7]	Xiao-Kun. LI,Dong-Dong. MA,Yan-Ping. ZHENG,Hong. ZHANG,Ding. DING,Ming-Shu. CHEN,Hui-Lin. WAN. Performance of CO Oxidation over Highly Dispersed Gold Catalyst on TiO_x/SiO₂ Composite Supports [J]. Acta Phys. -Chim. Sin., 2015, 31(9): 1753-1760.
[8]	LÜ Yong-Ge, LI Yong, TA Na, SHEN Wen-Jie. Morphology-Controlled Synthesis of Co₃O₄ Nanocubes and Their Catalytic Performance in CO Oxidation [J]. Acta Phys. -Chim. Sin., 2014, 30(2): 382-388.
[9]	LIANG Qian, ZHAO Zhen, LIU Jian, WEI Yue-Chang, JIANG Gui-Yuan, DUAN Ai-Jun. Pd Nanoparticles Deposited on Metal-Organic Framework of MIL-53(Al)：an Active Catalyst for CO Oxidation [J]. Acta Phys. -Chim. Sin., 2014, 30(1): 129-134.
[10]	LI Na, CHEN Qiu-Yan, LUO Meng-Fei, LU Ji-Qing. Kinetics Study of CO Oxidation Reaction over Pt/TiO₂ Catalysts [J]. Acta Phys. -Chim. Sin., 2013, 29(05): 1055-1062.
[11]	WANG Fang, WANG Cai-Hong, LI Da-Zhi. Novel Method of Controlling Formation of Hot-Spot over Gold Catalysts for CO Oxidation [J]. Acta Phys. -Chim. Sin., 2012, 28(06): 1455-1460.
[12]	DONG Hua-Qing, PAN Xi, XIE Qin, MENG Qiang-Qiang, GAO Jian-Rong, WANG Jian-Guo. CO Adsorption and Oxidation on Metal-Doped TiO₂ Nanotube Arrays [J]. Acta Phys. -Chim. Sin., 2012, 28(01): 44-50.
[13]	YANG Zhi-Qiang, MAO Dong-Sen, WU Ren-Chun, YU Jun, WANG Qian. Preparation of CuO-Ce_0.6Zr_0.4O₂ by Microwave Heating Decomposition and Its Catalytic Property for CO Oxidation [J]. Acta Phys. -Chim. Sin., 2011, 27(05): 1163-1168.
[14]	HU Jian-Ping, WANG Jun, TANG Dian-Yong, FU Qin-Chao, ZHANG Yuan-Qin. Reaction Mechanisms of CO Oxidation Catalyzed by Binary Copper Group Cluster Anions [J]. Acta Phys. -Chim. Sin., 2011, 27(02): 329-336.
[15]	YANG Zhi-Qiang, MAO Dong-Sen, GUO Qiang-Sheng, GU Lei. Effect of Preparation Method on the Activity of CuO/CeO₂-ZrO₂ Catalysts for Low Temperature CO Oxidation [J]. Acta Phys. -Chim. Sin., 2010, 26(12): 3278-3284.

Preparation of NiO/CeO₂ Catalysts by Solid State Impregnation and Their Application in CO Oxidation

PDF

Like

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Metrics

Recommended 0

Preparation of NiO/CeO2 Catalysts by Solid State Impregnation and Their Application in CO Oxidation

PDF

Like

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Metrics

Recommended 0

Preparation of NiO/CeO₂ Catalysts by Solid State Impregnation and Their Application in CO Oxidation