金属有机骨架材料MIL-53(Al)负载纳米Pd颗粒：一种CO氧化的活性催化剂

doi:10.3866/PKU.WHXB201311201

Abstract

Abstract:

Pd nanoparticles (NPs) supported on a metal-organic framework (MOF), MIL-53(Al) (MIL: Materials of Institut Lavoisier), were prepared using the incipient wetness impregnation method. The structures of the synthesized Pd/MIL-53(Al) catalysts were determined using X-ray diffraction (XRD), transmission electron microscopy (TEM), and X-ray photoelectron spectroscopy (XPS). The same peaks were observed in the XRD patterns of Pd/MIL-53(Al) before and after the catalytic reaction, confirming that the integrity of the MIL-53(Al) support was maintained. The TEM results indicated that the crystalline porous structure of MIL-53(Al) favored the formation of highly dispersed Pd NPs of average size 2.21 nm. The heterogeneous catalytic composite materials exhibited high activities for CO oxidation, with full conversion at 115 ℃. The catalytic activity and structure of Pd/MIL-53(Al) were stable after several reaction runs.

Key words: Metal-organic framework, MIL-53(Al), Palladium nanoparticle, Heterogeneous catalysis, CO oxidation

LIANG Qian, ZHAO Zhen, LIU Jian, WEI Yue-Chang, JIANG Gui-Yuan, DUAN Ai-Jun. Pd Nanoparticles Deposited on Metal-Organic Framework of MIL-53(Al)：an Active Catalyst for CO Oxidation[J]. Acta Phys. -Chim. Sin. 2014, 30(1), 129-134. doi: 10.3866/PKU.WHXB201311201

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Pd Nanoparticles Deposited on Metal-Organic Framework of MIL-53(Al)：an Active Catalyst for CO Oxidation

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