EDTA-甘氨酸法制备SmBaCo2O5+δ阴极材料及其性能

doi:10.3866/PKU.WHXB201310142

Abstract

Abstract:

SmBaCo₂O_5+δ (SBCO) was synthesized as a cathode material for intermediate temperature solid oxide fuel cells (IT-SOFC) via the EDTA-glycine process. The structure and properties of the material were measured by thermogravimetry-differential thermal analysis (TG-DTA), X-ray diffractometry (XRD), transmission electron microscopy (TEM), scanning electron microscopy (SEM), four-probe DC method, and AC impedance spectroscopy. The results indicated that a stable perovskite phase was formed after the initial powder was calcined at 850 ℃ for 5 h. The obtained powders revealed fine particles with good dispersion and homogeneous size distribution. SBCO had excellent high temperature chemical compatibility with Sm_0.2Ce_0.8O_1.9 (SDC) electrolyte. The electrical conductivities of the SBCO reached 668-382 S·cm^-1 in the temperature range 500-800 ℃. A symmetric half cell with SDC as electrolyte and SBCO as electrode was characterized by good three-phase interface bonding and high cathode catalytic activity. A polarization resistance of 0.0688 Ω·cm² was achieved at 750 ℃ for the SBCO, far below that of SBCO synthesized by solid state reaction method (SSR), with an activation energy (E_a) of 122.21 kJ·mol^-1.

Key words: Intermediate temperature solid oxide fuel cell, SmBaCo₂O_5+δ, Double perovskite, Cathode, Electrochemical performance

HU Zhi, HUANG Xiao-Wei, CHEN Yang-Hui. Synthesis and Properties of SmBaCo₂O_5+δ Cathode Material via EDTA-Glycine Process[J]. Acta Phys. -Chim. Sin. 2013, 29(12), 2585-2591. doi: 10.3866/PKU.WHXB201310142

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Synthesis and Properties of SmBaCo₂O_5+δ Cathode Material via EDTA-Glycine Process

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Synthesis and Properties of SmBaCo₂O_5+δ Cathode Material via EDTA-Glycine Process