合金元素Nd对Pb-Ag阳极在H2SO4溶液中电化学行为的影响

doi:10.3866/PKU.WHXB201312301

Abstract

Abstract:

Anodic layers and oxygen evolution reaction (OER) of Pb-Ag and Pb-Ag-Nd anodes were investigated by cyclic voltammetry, linear sweep voltammetry (LSV), electrochemical impedance spectroscopy (EIS), and environmental scanning electron microscopy (ESEM). Alloying with Nd promoted the formation of Pb/PbO_n/PbSO₄ (1≤n<2). Nd facilitated the transformation of PbO_n and PbSO₄ to α-PbO₂ and β-PbO₂, at potential above 1.2 V vs Hg/Hg₂SO₄ (saturated K₂SO₄ solution). ESEM and LSV indicated that the anodic layer formed on the Pb-Ag-Nd anode was thicker and more compact than that formed on the Pb-Ag anode. Consequently, the anodic layer on the Pb-Ag-Nd anode could provide better protection for metallic substrates. EIS indicated that the OER was determined by the formation and adsorption of intermediates. Nd enhanced the OER reactivity, because of a smaller adsorption resistance and larger coverage of intermediates at the anodic layer/electrolyte interface. In summary, alloying with Nd can enhance the corrosion resistance and reduce the energy consumption of Pb-Ag anode due to lower anodic potential.

Key words: Electrowinning, Anodic layer, Passivation, Oxygen evolution, Corrosion resistance

ZHONG Xiao-Cong, GUI Jun-Feng, YU Xiao-Ying, LIU Fang-Yang, JIANG Liang-Xing, LAI Yan-Qing, LI Jie, LIU Ye-Xiang. Influence of Alloying Element Nd on the Electrochemical Behavior of Pb-Ag Anode in H₂SO₄ Solution[J]. Acta Phys. -Chim. Sin. 2014, 30(3), 492-499. doi: 10.3866/PKU.WHXB201312301

References

(1) (a) Lai, Y. Q.; Jiang, L. X.; Li, J.; Zhong, S. P.; Lv, X. J.; Peng, H. Z.; Liu, Y. X. Hydrometallurgy 2010, 102 (1-4), 73. doi: 10.1016/j.hydromet.2010.02.012
(b) Newnham, R. H. J. Appl. Electrochem. 1992, 22 (2), 116.
(c) Petrova, M.; Noncheva, Z.; Dobrev, T.; Rashkov, Kunchev, N.; Petrov, D.; Vlaev, S.; Mihnev, V.; Zarev, S. Hydrometallurgy 1996, 40 (3), 319. doi: 10.1016/0304-386X(95)00010-E
(4) Clancy, M.; Bettles, C. J.; Stuart, A.; Birbilis, N. Hydrometallurgy 2013, 131-132, 144.
(5) Hong, B.; Jiang, L. X.; Lv, X. J.; Ni, H. F.; Lai, Y. Q.; Li, J.; Liu, Y. X. T. Nonferr. Metal Soc. 2012, 22 (4), 1126. [洪波, 蒋良兴, 吕晓军, 倪恒发, 赖延清, 李劼, 刘业翔. 中国有色金属学报, 2012, 22 (4), 1126.]
(6) (a) Pavlov, D.; Poulieff, C.; Klaja, E.; Iordanov, N. J. Electrochem. Soc. 1969, 116, 316. doi: 10.1149/1.2411836
(b) Monahov, B.; Pavlov, D. J. Appl. Electrochem. 1993, 23 (12), 1244.
(c) Ho, J.; Simpraga, R.; Conway, B. J. Electroanal. Chem. 1994, 366 (1), 147.
(d) Li, H.; Guo,W. X.; Chen, H. Y.; Finlow, D. E.; Zhou, H.W.; Dou, C. L.; Xiao, G. M.; Peng, S. G.;Wei,W.W.;Wang, H. J. Power Sources 2009, 191 (1), 111.
(7) Burbank, J. J. Electrochem. Soc. 1959, 106, 369. doi: 10.1149/1.2427362
(8) (a) Babi , R.; Metiko -Hukovi , M.; Lajqy, N.; Brini , S. J. Power Sources 1994, 52 (1), 17. doi: 10.1016/0378-7753(94)01925-8
(b) Dobrev, T.; Valchanova, I.; Stefanov, Y.; Magaeva, S. Trans. Inst. Met. Finish. 2009, 87 (3), 136.
(c) Ijomah, M. J. Electrochem. Soc. 1987, 134 (12), 2960.
(d) Buchanan, J.; Peter, L. Electrochim. Acta 1988, 33 (1), 127.
(e) Ijomah, M. J. Appl. Electrochem. 1988, 18 (1), 142.
(f) Varela, F.; Gassa, L.; Vilche, J. Electrochim. Acta 1992, 37 (6), 1119.
(9) Sharpe, T. F. J. Electrochem. Soc. 1977, 124 (2), 168. doi: 10.1149/1.2133259
(10) Czerwinski, A.; Zelazowska, M.; Grden, M.; Kuc, K.; Milewski, J.; Nowacki, A.;Wojcik, G.; Kopczyk, M. J. Power Sources 2000, 85 (1), 49. doi: 10.1016/S0378-7753(99)00381-X
(11) Guo, Y. L. J. Electrochem. Soc. 1991, 138 (5), 1222. doi: 10.1149/1.2085763
(12) Sun, Q. J.; Guo, Y. L. J. Electroanal. Chem. 2000, 493 (1), 123.
(13) Hu, J. M.; Zhang, J. Q.; Cao, C. N. Int. J. Hydrog. Energy 2004, 29 (8), 791. doi: 10.1016/j.ijhydene.2003.09.007
(14) Rerolle, C.;Wiart, R. Electrochim. Acta 1995, 40 (8), 939. doi: 10.1016/0013-4686(95)00026-B
(15) (a) Yang, C. J.; Ko, Y.; Park, S. M. Electrochim. Acta 2012, 78, 615. doi: 10.1016/j.electacta.2012.06.055
(b) Conway, B. E.; Liu, T., Langmuir 1990, 6 (1), 268.
(c) Li,W.; Chen, H.; Long, X.;Wu, F.;Wu, Y.; Yan, J.; Zhang, C. J. Power Sources 2006, 158 (2), 902.
(d) Zhang,W.; Houlachi, G. Hydrometallurgy 2010, 104 (2), 129.
(e) Ye, Z. G.; Meng, H. M.; Sun, D. B. Electrochim. Acta 2008, 53 (18), 5639.
(16) (a) Palmas, S.; Polcaro, A.; Ferrara, F.; Ruiz, J. R.; Delogu, F.; Bonatto-Minella, C.; Mulas, G. J. Appl. Electrochem. 2008, 38 (7), 907. doi: 10.1007/s10800-008-9494-6
(b) Cao, C. N. Electrochim. Acta 1990, 35 (5), 831.
(17) (a) Alves, V.; Da Silva, L.; Boodts, J. Electrochim. Acta 1998, 44 (8-9), 1525. doi: 10.1016/S0013-4686(98)00276-X
(b) Franco, D. V.; Silva, L. M. D.; Jardim,W. F.; Boodts, J. F. J. Brazil. Chem. Soc. 2006, 17 (4), 446.
(18) Brug, G. J.; van den Eeden, A. L. G.; Sluyters-Rehbach, M.; Sluyters, J. H. J. Electroanal. Chem. Interfacial Electrochem. 1984, 176 (1-2), 275.
(19) Martelli, G. N.; Ornelas, R.; Faita, G. Electrochim. Acta 1994, 39 (11-12), 1551.
(20) Lai, Y. Q.; Li, Y.; Jiang, L. X.; Xu,W.; Lv, X. J.; Li, J.; Liu, Y. X. J. Electroanal. Chem. 2012, 671, 16. doi: 10.1016/j.jelechem.2012.02.011

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Influence of Alloying Element Nd on the Electrochemical Behavior of Pb-Ag Anode in H₂SO₄ Solution

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Influence of Alloying Element Nd on the Electrochemical Behavior of Pb-Ag Anode in H2SO4 Solution

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Influence of Alloying Element Nd on the Electrochemical Behavior of Pb-Ag Anode in H₂SO₄ Solution