杂多酸/离子液体杂化材料催化苯的高选择性羟基化

doi:10.3866/PKU.WHXB201609181

Abstract

Abstract:

Aseriesof hybridmaterials ([C₄mim]_3+xPMo_12-xV_xO₄₀, x=0, 1, 2)basedonV-substitutedphosphomolybdic acidH_3+xPMo_12-xV_xO₄₀ (x=0, 1, 2) and ionic liquid 1-butyl-3-methyl imidazolium bromide ([C₄mim]Br) have been prepared by an anion-exchange method. The samples were characterized by X-ray diffraction (XRD), Fourier transform infrared spectrophotometry (FT-IR) and UV-Vis diffuse reflectance spectra (UV-Vis DRS) analysis. The catalytic performances of the samples were tested in oxidation of benzene to produce phenol using H₂O₂ as the oxidant. The results showed that the hybrids[C₄mim]_3+xPMo_12-xV_xO₄₀ exhibit much higher catalytic properties than both the corresponding moieties. In particular, under the optimized conditions, 21% of benzene conversion and 99%selectivity for phenol have been obtained with[C₄mim]₅PMo₁₀V₂O₄₀. The sample also exhibits good reusability and was reused five times without a significant decrease in conversion and selectivity.

Key words: Polyoxometalate, Ionic liquid, Hybrid material, Hydroxylation of benzene

Qing MA,Jin-Hui TONG,Ling-Di SU,Wen-Hui WANG,Wen-Mei MA,Li-Li BO. Highly Selective Hydroxylation of Benzene Catalyzed by Hybrids of Polyoxometalate/Ionic Liquid[J]. Acta Phys. -Chim. Sin. 2016, 32(12), 2961-2967. doi: 10.3866/PKU.WHXB201609181

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Highly Selective Hydroxylation of Benzene Catalyzed by Hybrids of Polyoxometalate/Ionic Liquid

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