蒸氨法制备铜硅催化剂的二甲醚水蒸气重整制氢性能

doi:10.3866/PKU.WHXB201704263

Abstract

Abstract:

A series of xCu/SiO₂-AE catalysts with different Cu loadings was prepared by the ammonia evaporation method. The as-prepared catalysts were used for hydrogen production via steam reforming of dimethyl ether, and showed high catalytic activities. The 30Cu/SiO₂-AE catalyst (with 30% (w) Cu loading) exhibits the best catalytic performance. Our studies reveal the presence of highly dispersed Cu⁰ and copper phyllosilicate on the surface of the catalysts, which can then be reduced to Cu⁰ and Cu⁺ species, respectively. Compared with the 30Cu/SiO₂-IM catalyst prepared by the conventional impregnation method, the remarkable catalytic stability and activity of the 30Cu/SiO₂-AE catalyst are mainly ascribed to its unique lamellar structure and the cooperative effect between the surface Cu⁰ and Cu⁺ species.

Key words: Steam reforming of dimethyl ether, Hydrogen production, Copper phyllosilicate, Cu/SiO₂, Ammonia evaporation method

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Xin-Lei WANG,Kui MA,Li-Hong GUO,Tong DING,Qing-Peng CHENG,Ye TIAN,Xin-Gang LI. Catalytic Performance for Hydrogen Production through Steam Reforming of Dimethyl Ether over Silica Supported Copper Catalysts Synthesized by Ammonia Evaporation Method[J]. Acta Phys. -Chim. Sin. 2017, 33(8), 1699-1708. doi: 10.3866/PKU.WHXB201704263

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Catalytic Performance for Hydrogen Production through Steam Reforming of Dimethyl Ether over Silica Supported Copper Catalysts Synthesized by Ammonia Evaporation Method

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