In2O3修饰三维纳米花MoSx构建S型异质结用于高效光催化产氢

doi:10.3866/PKU.WHXB202201037

Abstract

Abstract:

Morphology regulation and the improvement of carrier separation efficiency are important strategies for the preparation of photocatalysts with excellent performance. MoS_x with a three-dimensional (3D) nanoflower morphology formed by nanosheet stacking was prepared by a simple hydrothermal method, and MoS_x/In₂O₃ with good hydrogen evolution activity was obtained by coupling with In₂O₃. The preparation of the three-dimensional nanoflower morphology combined with the construction of an S-scheme heterojunction improves the electron accumulation at the active site for hydrogen evolution reaction. The UV diffuse reflection test showed that the issue of poor light absorption of In₂O₃ was improved. The rapid separation and transfer of electrons were effectively confirmed by characterization methods such as fluorescence spectroscopy and electrochemical tests. The most intuitively manifestation of the performance improvement of the composite material is that the optimal hydrogen evolution rate reached 6704.2 μmol∙g⁻¹∙h⁻¹, which is 1.8 times that of pure MoS_x. Therefore, in this study, a new idea for the development of molybdenum-based sulfides for photocatalytic hydrogen production is provided.

Key words: Photocatalysis, Heterojunction, MoS_x, In₂O₃, Hydrogen production

Hongying Li, Haiming Gong, Zhiliang Jin. In₂O₃-Modified Three-Dimensional Nanoflower MoS_x Form S-scheme Heterojunction for Efficient Hydrogen Production[J]. Acta Phys. -Chim. Sin. 2022, 38(12), 2201037. doi: 10.3866/PKU.WHXB202201037

Figures/Tables 13

References 53

1	Zhang P. ; Wang J. ; Li Y. ; Jiang L. ; Wang Z. ; Zhang G. Acta Phys. -Chim. Sin. 2021, 37, 2009102.
	张鹏; 王继全; 李源; 姜丽莎; 王壮壮; 张高科; 物理化学学报, 2021, 37, 2009102. doi: 10.3866/PKU.WHXB202009102
2	Xue Y. ; Huang B. ; Yi Y. ; Guo Y. ; Zuo Z. ; Li Y. ; Jia Z. ; Liu H. ; Li Y. Nat. Commun. 2018, 9, 1460. doi: 10.1038/s41467-018-03896-4
3	Hui L. ; Xue Y. ; Yu H. ; Liu Y. ; Fang Y. ; Xing C. ; Huang B. ; Li Y. J. Am. Chem. Soc. 2019, 141, 10677. doi: 10.1021/jacs.9b03004
4	Jiang Z. ; Chen Q. ; Zheng Q. ; Shen R. ; Zhang P. ; Li X. Acta Phys. -Chim. Sin. 2021, 37, 2010059.
	姜志民; 陈晴; 郑巧清; 沈荣晨; 张鹏; 李鑫; 物理化学报, 2021, 37, 2010059. doi: 10.3866/PKU.WHXB202010059
5	Hui L. ; Zhang X. ; Xue Y. ; Chen X. ; Fang Y. ; Xing C. ; Liu Y. ; Zheng X. ; Du Y. ; Zhang C. ; et al J. Am. Chem. Soc. 2022, 144, 1921. doi: 10.1021/jacs.1c12310
6	Li Y. ; Yang T. ; Li H. ; Tong R. ; Peng S. ; Han X. J. Colloid Interface Sci. 2020, 578, 273. doi: 10.1016/j.jcis.2020.05.124
7	Hu S. ; Shi J. ; Luo B. ; Ai C. ; Jing D. J. Colloid Interface Sci. 2022, 608, 2058. doi: 10.1016/j.jcis.2021.10.136
8	Karunadasa H. I. ; Montalvo E. ; Sun Y. Science 2012, 335, 698. doi: 10.1126/science.1215868
9	Wang L. ; Xu Z. ; Wang W. J. Am. Chem. Soc. 2014, 136, 6693. doi: 10.1021/ja501686w
10	Zhou X. ; Zhao W. ; Pan J. ; Fang Y. ; Wang F. ; Huang F. Chem. Commun. 2018, 54, 12714. doi: 10.1039/C8CC06714G
11	Kozlova M. N. ; Enyashin A. N. ; Grayfer E. D. ; Kuznetsov V. A. ; Plyusnin P. E. ; Nebogatikova N. A. ; Zaikovskii V. I. ; Fedorov V. E. J. Mater. Chem. C 2017, 5, 6601. doi: 10.1039/C7TC01320E
12	Tiwari R. K. ; Yang J. ; Saeys M. ; Joachim C. Surf. Sci. 2008, 602, 2628. doi: 10.1016/j.susc.2008.06.006
13	Yan Y. ; Xia B. ; Ge X. ; Liu Z. ; Wang J. ; Wang X. ACS Appl. Mater. Interfaces 2013, 5, 12794. doi: 10.1021/am404843b
14	Yin J. ; Cao H. Inorg. Chem. 2012, 51, 6529. doi: 10.1021/ic300005c
15	Chen R. ; Li D. ; Fang Z. ; Huang Y. ; Luo B. ; Shi W. Acta Phys. -Chim. Sin. 2020, 36, 1903047.
	陈锐杰; 李锑; 方振远; 黄元勇; 罗必富; 施伟东; 物理化学学报, 2020, 36, 1903047. doi: 10.3866/PKU.WHXB201903047
16	Reyes-Gil K. R. ; Reyes-García E. A. ; Raftery D. J. Phys. Chem. C 2007, 111, 14579. doi: 10.1021/jp072831y
17	Ma D. ; Shi J. ; Zou Y. ; Fan Z. ; Shi J. ; Cheng L. ; Sun D. Nanoscale 2018, 10, 7860. doi: 10.1039/C8NR00170G
18	Low J. ; Yu J. ; Jaroniec M. ; Wageh S. ; Al-Ghamdi A. A. Adv. Mater. 2017, 29, 1601694. doi: 10.1002/adma.201601694
19	Huang Y. ; Mei F. ; Zhang J. ; Dai K. ; Dawson G. Acta Phys. -Chim. Sin. 2022, 38, 2108028.
	黄悦; 梅飞飞; 张金峰; 代凯; DawsonG.; 物理化学学报, 2022, 38, 2108028. doi: 10.3866/PKU.WHXB202108028
20	Gong H. ; Li Z. ; Chen Z. ; Liu Q. ; Song M. ; Huang C. ACS Appl. Nano Mater. 2020, 3, 3665. doi: 10.1021/acsanm.0c00388
21	Gong H. ; Wang G. ; Li H. ; Jin Z. ; Guo Q. Int. J. Hydrog. Energy 2020, 45, 26733. doi: 10.1016/j.ijhydene.2020.07.059
22	Zhang M. ; Hu Q. ; Ma K. ; Ding Y. ; Li C. Nano Energy. 2020, 73, 104810. doi: 10.1016/j.nanoen.2020.104810
23	Xu Q. ; Zhang L. ; Cheng B. ; Fan J. ; Yu J. Chem 2020, 6, 1543. doi: 10.1016/j.chempr.2020.06.010
24	Wang R. ; Shen J. ; Zhang W. ; Liu Q. ; Zhang M. ; Zulfiqara ; Tang H. Ceram. Int. 2020, 46, 23. doi: 10.1016/j.ceramint.2019.08.226
25	Hu T. ; Dai K. ; Zhang J. ; Zhu G. ; Liang C. Mater. Lett. 2019, 257, 126740. doi: 10.1016/j.matlet.2019.126740
26	Liu X. ; Min S. ; Xue Y. ; Lei Y. ; Chen Y. ; Wang F. ; Zhang Z. Renew. Energy 2019, 138, 562. doi: 10.1016/j.renene.2019.01.127
27	Sathish R. ; Ran D. ; Kang L. ; Mao N. ; Zhang J. Appl. Catal. B Environ. 2016, 194, 16. doi: 10.1016/j.apcatb.2016.04.007
28	Yan X. ; Wang G. ; Zhang Y. ; Guo Q. ; Jin Z. Int. J. Hydrog. Energy 2020, 45, 2578. doi: 10.1016/j.ijhydene.2019.11.227
29	Peng Y. ; Bin W. ; Liu Z. Int. J. Hydrog. Energy 2018, 43, 23109. doi: 10.1016/j.ijhydene.2018.10.215
30	Zhang Z. ; Huang L. ; Zhang J. ; Wang F. ; Xie Y. ; Shang X. ; Gu Y. ; Zhao H. ; Wang X. Appl. Catal. B Environ. 2018, 233, 112. doi: 10.1016/j.apcatb.2018.04.006
31	Massey A.T. ; Gusain R. ; Kumari S. ; Khatri O. P. Ind. Eng. Chem. Res. 2016, 55, 7124. doi: 10.1021/acs.iecr.6b01115
32	Rai P. ; Wook Yoon J. ; Hoon-Kwak C. ; Lee-Heun J. J. Mater. Chem. A 2016, 4, 264. doi: 10.1039/C5TA08873A
33	Sun L. ; Zhuang Y. ; Yuan Y. ; Zhan W. ; Wang X. ; Han X. ; Zhao Y. Adv. Energy Mater. 2019, 9, 1902839. doi: 10.1002/aenm.201902839
34	Wang F. ; He X. ; Sun L. ; Chen J. ; Wang X. ; Xu J. ; Han X. J. Mater. Chem. A 2018, 6, 2091. doi: 10.1039/C7TA09166D
35	Yan T. ; Zhang X. ; Liu H. ; Jin Z. J. Struct. Chem. 2022, 41, 2201047. doi: 10.14102/j.cnki.0254-5861.2021-0057
36	Li Y. ; Wang G. ; Wang Y. ; Jin Z. Catal. Sci. Technol. 2020, 10, 2931. doi: 10.1039/D0CY00087F
37	Zhang L. ; Hao X. ; Li Y. ; Jin Z. Appl. Surf. Sci. 2020, 499, 143862. doi: 10.1016/j.apsusc.2019.143862
38	Zhang L. ; Wang G. ; Hao X. ; Jin Z. ; Wang Y. Chem. Eng. J. 2020, 395, 125113. doi: 10.1016/j.cej.2020.125113
39	Jin Z. ; Li H. ; Gong H. ; Yang K. ; Guo Q. Catal. Sci. Technol. 2021, 11, 4749. doi: 10.1039/D1CY00683E
40	Li J. ; Luo B. ; Zheng X. ; Jing D. ; Ma L. Catal. Sci. Technol. 2021, 11, 7624. doi: 10.1039/D1CY01677F
41	Quarto F. ; Sunseri C. ; Piazza S. ; Romano M. C. J. Phys. Chem. B 1997, 101, 2519. doi: 10.1021/jp970046n
42	Li M. ; Li J. ; Jin Z. Dalton Trans. 2020, 49, 5143. doi: 10.1039/D0DT00271B
43	Li Y. ; Jin Z. ; Zhang L. ; Fan K. Chin. J. Catal. 2019, 40, 390. doi: 10.1016/S1872-2067(18)63173-0
44	Maiti R. ; Mukherjee S. ; Haldar S. ; Bhowmick D. ; Ray S. K. Carbon 2016, 104, 226. doi: 10.1016/j.carbon.2016.04.004
45	Ke L. ; Li P. ; Wu X. ; Jiang S. ; Luo M. ; Liu Y. ; Le Z. ; Sun C. ; Song S. Appl. Catal. B: Environ. 2017, 205, 319. doi: 10.1016/j.apcatb.2016.12.043
46	Hao X. ; Cui Z. ; Zhou J. ; Wang Y. ; Hu Y. ; Wang Y. ; Zou Z. Nano Energy 2018, 52, 105. doi: 10.1016/j.nanoen.2018.07.043
47	Hu Y. ; Hao X. ; Cui Z. ; Zhou J. ; Chu S. ; Wang Y. ; Zou Z. Appl. Catal. B: Environ. 2020, 260, 118131. doi: 10.1016/j.apcatb.2019.118131
48	Zhao S. ; Xu J. ; Mao M. ; Li L. ; Li X. Appl. Surf. Sci. 2020, 528, 147016. doi: 10.1016/j.apsusc.2020.147016
49	Gong H. ; Zhang X. ; Wang G. ; Liu Y. ; Li Y. ; Jin Z. Mol. Catal. 2020, 485, 110832. doi: 10.1016/j.mcat.2020.110832
50	Xia P. ; Cao S. ; Zhu B. ; Liu M. ; Shi M. ; Yu J. ; Zhang Y. Angew. Chem. Int. Ed. 2020, 59, 5218. doi: 10.1002/anie.201916012
51	Li H. ; Hao X. ; Gong H. ; Jin Z. ; Zhao T. J. Colloid Interface Sci. 2021, 586, 84. doi: 10.1016/j.jcis.2020.10.072
52	Li H. ; Gong H. ; Jin Z. Appl. Catal. B: Environ. 2022, 307, 121166. doi: 10.1016/j.apcatb.2022.121166
53	Wang J. ; Wang G. ; Cheng B. ; Yu J. ; Fan J. Chin. J. Catal. 2021, 42, 56. doi: 10.1016/S1872-2067(20)63634-8

Samples	Lifetime < τ > (ns)	Pre-exponential factor A%	Average lifetime < τ_av > (ns)	X²
EY	τ₁ = 0.14	100%	0.14	1.32
MoS_x	τ₁ = 0.11	99.61%	0.11	1.32
	τ₂ = 23.4	0.39%
In₂O₃	τ₁ = 0.15	99.72%	0.15	1.37
	τ₂ = 8.16	0.28%
10-MIO	τ₁ = 0.02	99.42%	0.02	1.46
	τ₂ = 3.84	0.58%

[1]	Chengbo Zhang, Xiaoping Tao, Wenchao Jiang, Junxue Guo, Pengfei Zhang, Can Li, Rengui Li. Microwave-Assisted Synthesis of Bismuth Chromate Crystals for Photogenerated Charge Separation [J]. Acta Phys. -Chim. Sin., 2024, 40(1): 2303034-.
[2]	Kezhen Lai, Fengyan Li, Ning Li, Yangqin Gao, Lei Ge. Identification of Charge Transfer Pathways in Metal-Organic Framework- Derived Ni-CNT/ZnIn₂S₄ Heterojunctions for Photocatalytic Hydrogen Evolution [J]. Acta Phys. -Chim. Sin., 2024, 40(1): 2304018-.
[3]	Qianwei Song, Guanchao He, Huilong Fei. Photothermal Catalytic Conversion Based on Single Atom Catalysts: Fundamentals and Applications [J]. Acta Phys. -Chim. Sin., 2023, 39(9): 2212038-0.
[4]	Yining Zhang, Ming Gao, Songtao Chen, Huiqin Wang, Pengwei Huo. Fabricating Ag/CN/ZnIn₂S₄ S-Scheme Heterojunctions with Plasmonic Effect for Enhanced Light-Driven Photocatalytic CO₂ Reduction [J]. Acta Phys. -Chim. Sin., 2023, 39(6): 2211051-.
[5]	Cheng Luo, Qing Long, Bei Cheng, Bicheng Zhu, Linxi Wang. A DFT Study on S-Scheme Heterojunction Consisting of Pt Single Atom Loaded G-C₃N₄ and BiOCl for Photocatalytic CO₂ Reduction [J]. Acta Phys. -Chim. Sin., 2023, 39(6): 2212026-.
[6]	Keyu Zhang, Yunfeng Li, Shidan Yuan, Luohong Zhang, Qian Wang. Review of S-Scheme Heterojunction Photocatalyst for H₂O₂ Production [J]. Acta Phys. -Chim. Sin., 2023, 39(6): 2212010-.
[7]	Zhongliao Wang, Jing Wang, Jinfeng Zhang, Kai Dai. Overall Utilization of Photoexcited Charges for Simultaneous Photocatalytic Redox Reactions [J]. Acta Phys. -Chim. Sin., 2023, 39(6): 2209037-.
[8]	Zhongqi Zan, Xibao Li, Xiaoming Gao, Juntong Huang, Yidan Luo, Lu Han. 0D/2D Carbon Nitride Quantum Dots (CNQDs)/BiOBr S-Scheme Heterojunction for Robust Photocatalytic Degradation and H₂O₂ Production [J]. Acta Phys. -Chim. Sin., 2023, 39(6): 2209016-.
[9]	Tao Sun, Chenxi Li, Yupeng Bao, Jun Fan, Enzhou Liu. S-Scheme MnCo₂S₄/g-C₃N₄ Heterojunction Photocatalyst for H₂ Production [J]. Acta Phys. -Chim. Sin., 2023, 39(6): 2212009-.
[10]	Xinhe Wu, Guoqiang Chen, Juan Wang, Jinmao Li, Guohong Wang. Review on S-Scheme Heterojunctions for Photocatalytic Hydrogen Evolution [J]. Acta Phys. -Chim. Sin., 2023, 39(6): 2212016-0.
[11]	Wenjie Zhou, Qihang Jing, Jiaxin Li, Yingzhi Chen, Guodong Hao, Lu-Ning Wang. Organic Photocatalysts for Solar Water Splitting: Molecular- and Aggregate-Level Modifications [J]. Acta Phys. -Chim. Sin., 2023, 39(5): 2211010-0.
[12]	Erjun Lu, Junqian Tao, Can Yang, Yidong Hou, Jinshui Zhang, Xinchen Wang, Xianzhi Fu. Carbon-Encapsulated Pd/TiO₂ for Photocatalytic H₂ Evolution Integrated with Photodehydrogenative Coupling of Amines to Imines [J]. Acta Phys. -Chim. Sin., 2023, 39(4): 2211029-0.
[13]	Yonggang Lei, Tianyu Zhao, Kim Hoong Ng, Yingzhen Zhang, Xuerui Zang, Xiao Li, Weilong Cai, Jianying Huang, Jun Hu, Yuekun Lai. Metallic Tungsten Carbide Coupled with Liquid-Phase Dye Photosensitizer for Efficient Photocatalytic Hydrogen Production [J]. Acta Phys. -Chim. Sin., 2023, 39(4): 2206006-0.
[14]	Jing Kong, Jingui Zhang, Sufen Zhang, Juqun Xi, Ming Shen. Performance Improvement and Antibacterial Mechanism of BiOI/ZnO Nanocomposites as Antibacterial Agent under Visible Light [J]. Acta Phys. -Chim. Sin., 2023, 39(12): 2212039-.
[15]	Jintao Dong, Sainan Ji, Yi Zhang, Mengxia Ji, Bin Wang, Yingjie Li, Zhigang Chen, Jiexiang Xia, Huaming Li. Construction of Z-Scheme MnO₂/BiOBr Heterojunction for Photocatalytic Ciprofloxacin Removal and CO₂ Reduction [J]. Acta Phys. -Chim. Sin., 2023, 39(11): 2212011-.

In₂O₃-Modified Three-Dimensional Nanoflower MoS_x Form S-scheme Heterojunction for Efficient Hydrogen Production

RichHTML

PDF

Like

Knowledge

Abstract

Cite this article

share this article

Figures/Tables 13

References 53

Related Articles 15

Metrics

Recommended 0

Sample	S_BET/(m²?g^?1)	Prove volume/(cm³?g^?1)	Average pore size/nm
MoS_x	14	0.07	20
In₂O₃	141	0.59	18
10-MIO	25	0.13	19

In2O3-Modified Three-Dimensional Nanoflower MoSx Form S-scheme Heterojunction for Efficient Hydrogen Production

RichHTML

PDF

Like

Knowledge

Abstract

Cite this article

share this article

Figures/Tables 13

References 53

Related Articles 15

Metrics

Recommended 0

In₂O₃-Modified Three-Dimensional Nanoflower MoS_x Form S-scheme Heterojunction for Efficient Hydrogen Production