Acta Physico-Chimica Sinica ›› 2019, Vol. 35 ›› Issue (11): 1224-1231.doi: 10.3866/PKU.WHXB201901072
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Yanyan GONG,Haichun LIU,Duo ZHANG,Jing TONG*()
Received:
2019-01-27
Accepted:
2019-03-08
Published:
2019-03-13
Contact:
Jing TONG
E-mail:tongjinglnu@sina.com
Supported by:
Yanyan GONG,Haichun LIU,Duo ZHANG,Jing TONG. Thermodynamic Properties of the Ether-Based Functionalized Ionic Liquids [MOEMIm]Cl and [EOEMIm]Cl[J]. Acta Physico-Chimica Sinica 2019, 35(11), 1224-1231. doi: 10.3866/PKU.WHXB201901072
Table 1
Values of ρ, γ and nD for [MOEMIm]Cl and [EOEMIm]Cl at T = 288.15–328.15 K and p = 0.1 MPa."
ILs | T/K | ρ/(g·cm-3) | γ/(mJ·m-2) | nD |
[MOEMIm]Cl | 288.15 | 1.16860 + 0.00007 | 49.6 + 0.31 | 1.5201 + 0.0003 |
293.15 | 1.16546 + 0.00007 | 49.2 + 0.31 | 1.5185 + 0.0003 | |
298.15 | 1.16231 + 0.00007 | 48.7 + 0.31 | 1.5160 + 0.0003 | |
303.15 | 1.15917 + 0.00007 | 48.4 + 0.31 | 1.5142 + 0.0003 | |
308.15 | 1.15604 + 0.00007 | 48.0 + 0.31 | 1.5121 + 0.0003 | |
313.15 | 1.15291 + 0.00007 | 47.6 + 0.31 | 1.5103 + 0.0003 | |
318.15 | 1.14978 + 0.00007 | 47.1 + 0.31 | 1.5083 + 0.0003 | |
323.15 | 1.14663 + 0.00007 | 46.7 + 0.31 | 1.5069 + 0.0003 | |
328.15 | 1.14327 + 0.00007 | 46.2 + 0.31 | 1.5046 + 0.0003 | |
[EOEMIm]Cl | 288.15 | 1.14313 + 0.00007 | 47.8 + 0.31 | 1.5269 + 0.0003 |
293.15 | 1.13998 + 0.00007 | 47.3 + 0.31 | 1.5255 + 0.0003 | |
298.15 | 1.13683 + 0.00007 | 46.9 + 0.31 | 1.5240 + 0.0003 | |
303.15 | 1.13369 + 0.00007 | 46.5 + 0.31 | 1.5225 + 0.0003 | |
308.15 | 1.13057 + 0.00007 | 46.0 + 0.31 | 1.5206 + 0.0003 | |
313.15 | 1.12745 + 0.00007 | 45.6 + 0.31 | 1.5184 + 0.0003 | |
318.15 | 1.12437 + 0.00007 | 45.2 + 0.31 | 1.5159 + 0.0003 | |
323.15 | 1.12128 + 0.00007 | 44.8 + 0.31 | 1.5142 + 0.0003 | |
328.15 | 1.11821 + 0.00007 | 44.3 + 0.31 | 1.5119 + 0.0003 |
Table 2
The predicted volumetric properties of the ILs at 298.15 K."
ILs | ρ/(g·cm-3) | Vm/(nm3) | 104V/(m3·mol-1) | S0/(J·K-1·mol-1) | ΔUPOT/(kJ·mol-1) |
[C22O1IM][DCA] | 1.1136022 | 1.987 | 0.3300 | 441 | 443 |
[C22O1IM][OAC] | 1.1923823 | 1.797 | 0.2985 | 402 | 455 |
[C22O1IM][SCN] | 1.12210723 | 1.901 | 0.3158 | 423 | 448 |
[C22O1IM][TfO] | 1.35588623 | 2.244 | 0.3728 | 494 | 430 |
[C22O1IM][NTF2] | 1.46312723 | 2.976 | 0.4944 | 646 | 401 |
[MOEMIm]Cl | 1.16231 | 1.520 | 0.2524 | 344 | 475 |
[EOEMIm]Cl | 1.13683 | 1.677 | 0.2786 | 377 | 463 |
Table 3
Values of gs, s, h and gs(pre) for [MOEMIm]Cl and [EOEMIm]Cl at T = 288.15–328.15 K."
ILs | T/K | gs/(kJ·mol-1) | s/(J·mol-1·K-1) | h/(kJ·mol-1) | gs(pre)/(kJ·mol-1) |
[MOEMIm]Cl | 288.15 | 11.89 | 15.99 | 16.49 | 11.89 |
293.15 | 11.81 | 15.99 | 16.50 | 11.81 | |
298.15 | 11.71 | 15.99 | 16.48 | 11.73 | |
303.15 | 11.66 | 15.99 | 16.51 | 11.65 | |
308.15 | 11.59 | 15.99 | 16.51 | 11.57 | |
313.15 | 11.51 | 15.99 | 16.52 | 11.49 | |
318.15 | 11.41 | 15.99 | 16.50 | 11.41 | |
323.15 | 11.33 | 15.99 | 16.50 | 11.33 | |
328.15 | 11.23 | 15.99 | 16.48 | 11.25 | |
[EOEMIm]Cl | 288.15 | 12.23 | 17.81 | 17.36 | 12.22 |
293.15 | 12.13 | 17.81 | 17.35 | 12.13 | |
298.15 | 12.05 | 17.81 | 17.35 | 12.05 | |
303.15 | 11.96 | 17.81 | 17.36 | 11.96 | |
308.15 | 11.86 | 17.81 | 17.34 | 11.87 | |
313.15 | 11.78 | 17.81 | 17.35 | 11.78 | |
318.15 | 11.69 | 17.81 | 17.36 | 11.69 | |
323.15 | 11.61 | 17.81 | 17.37 | 11.60 | |
328.15 | 11.50 | 17.81 | 17.35 | 11.51 |
Table 4
Values of Rm, αp and γ(pre) for [MOEMIm]Cl and [EOEMIm]Cl at T = 288.15–328.15 K."
ILs | T/K | nD | Rm/(cm3·mol-1) | 1024αp/(cm3) | γ(pre)/(mJ·m-2) |
[MOEMIm]Cl | 288.15 | 1.5201 | 45.96 | 18.23 | 49.6 |
293.15 | 1.5185 | 45.96 | 18.23 | 49.2 | |
298.15 | 1.5160 | 45.90 | 18.20 | 48.8 | |
303.15 | 1.5142 | 45.89 | 18.20 | 48.4 | |
308.15 | 1.5121 | 45.86 | 18.19 | 47.9 | |
313.15 | 1.5103 | 45.85 | 18.18 | 47.5 | |
318.15 | 1.5083 | 45.82 | 18.17 | 47.1 | |
323.15 | 1.5069 | 45.84 | 18.18 | 46.7 | |
328.15 | 1.5046 | 45.80 | 18.16 | 46.3 | |
[EOEMIm]Cl | 288.15 | 1.5269 | 51.27 | 20.33 | 47.8 |
293.15 | 1.5255 | 51.30 | 20.34 | 47.3 | |
298.15 | 1.5240 | 51.32 | 20.35 | 46.9 | |
303.15 | 1.5225 | 51.34 | 20.36 | 46.5 | |
308.15 | 1.5206 | 51.32 | 20.35 | 46.0 | |
313.15 | 1.5184 | 51.28 | 20.34 | 45.6 | |
318.15 | 1.5159 | 51.21 | 20.31 | 45.2 | |
323.15 | 1.5142 | 51.21 | 20.31 | 44.8 | |
328.15 | 1.5119 | 51.16 | 20.29 | 44.3 |
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