HAP自组装球的简易合成及其光催化增效作用

doi:10.3866/PKU.WHXB20112939

Abstract

Abstract: Hydroxyapatite (HAP) nanoribbon spheres with well-defined nanoscale structures and regular morphology were successfully synthesized using a bioactive cooperate template. The spheres are about 5-6 μm in diameter and they form from nanoribbons of 2.5 to 3 μm in length. The morphologies, structures, and surface areas of the products were studied by X-ray diffraction (XRD), transmission electron microscopy (TEM), scanning electron microscopy (SEM), Fourier transform infrared (FT-IR) spectroscopy and Brunauer-Emmett-Teller (BET) analysis. In addition, the products were used as carried materials for the synthesis of the HAP/ZnO composite catalyst. The degradation rate of rhodamine B (RhB) increased by 125% and the recovery increased by 23.1% when using the composite as a catalyst compared with the ZnO nanoparticles. Possible mechanisms for the formation of the HAP assembly microspheres and their synergistic action are also discussed.

Key words: HAP, ZnO, Assembly sphere, Photocatalysis, Synergized action

YANG Xiao-Hong, LIU Chang, LIU Jin-Ku, ZHU Zi-Chun. Facile Synthesis of Assembly HAP Nanoribbon Spheres and the Synergized Action of Its Photocatalytic Properties[J].Acta Phys. -Chim. Sin., 2011, 27(12): 2939-2945.

References

(1) Liu, J. K.;Wu, Q. S.; Ding, Y. P. Eur. J. Inorg. Chem. 2005, 20, 4145.
(2) Zhang, D.L.; Yang, C.F.; Sun, Y.P.; Fu, H.Y.; Li, R.X.; Chen, H.; Li, X. J. Acta Phys. -Chim. Sin. 2010, 26, 2711. [张定林, 杨朝芬, 孙亚萍, 付海燕, 李瑞祥, 陈华, 李贤均. 物理化学学报, 2010, 26, 2711.]
(3) Liu, J. K.; Yang, X. H.; Tian, X. G. Powd. Technol. 2008, 184, 21.
(4) Liu, J. K.; Cao, T.J.; Lu, Y.; Luo, C. X. Mater. Technol. 2009, 24, 88.
(5) Ye, F.; Guo, H. F.; Zhang, H. J. Acta Biomater. 2010, 6, 2212.
(6) Zhang, M.; Liu, J. K.; Miao, R.; Li, G. M.; Du, Y. J. Nanoscale Res. Le tt. 2010, 5, 675.
(7) Hu, X. J.; Liu, J. K.; Qin, X. Y.; Huang, J.; Yi, Y. Nano 2009, 4, 165.
(8) Hu, X. J.; Liu, J. K.; Lu, Y.; Mu, J. Mater. Lett. 2008, 62, 3824.

(9) Guo, Y. P.; Zhu, Y.; Jia, D. C. Mater. Sci. Eng. C 2010, 30, 472.
(10) Cai, Y. R.; Pan, H. H.; Xu, X. R.; Hu,Q. H.; Li, L.; Tang, R. K. Chem. Mater. 2007, 19, 3081.
(11) Liu, Y.; Zhao, X.; Pan, Y.; Zhao, J.Z.;Wang, Z. C. Acta Phys. -Chim. Sin. 2009, 25, 1467. [刘莹, 赵旭, 潘琰, 赵敬哲, 王子忱. 物理化学学报, 2009, 25, 1467.]
(12) Liu, J. K.; Luo, C. X.; Quan, N. J. J. Nanopart. Res. 2008, 10, 531.
(13) Zhao, K. F.; Qiao, B. T.;Wang, J. H.; Zhang, Y. J.; Zhang, T. Chem. Commun. 2011, No.47, 1779.
(14) Sun, Y. P.; Fu, H. Y.; Zhang, D. L.; Li, R. X.; Chen, H.; Li, X. J. Cat. Commun. 2010, No.12, 188.
(15) Zhang, Y. J.;Wang, J. H.; Yin, J.; Zhao, K. F.; Jin, C. Z.; Huang, Y. Y.; Jiang, Z.; Zhang, T. J. Phys. Chem. C 2010, 114, 16443.
(16) Mitsionisa, A.; Vaimakisa, T.; Trapalisb, C.; Todorovab, N.; Bahnemannc, D.; Dillertc, R. Appl. Catal. B-Environ. 2011, 106, 398.
(17) Liu, Y. C.; Zhong, H.; Li, L. F.; Zhang, C. J.; Mater. Res. Bull. 2010, 45, 2036.
(18) Reddy, M. P.; Venugopal, A.; Subrahmanyam, M. Appl. Catal. B- Environ. 2007, 69, 164.
(19) Ma, N.; Zhang, Y. B.; Quan, X.; Fan, X. F.; Zhao, H. M. Water Res. 2010, 44, 6104.
(20) Nishikawa, H.; Omamiuda, K. J. Mol. Catal. A-Chem. 2002, 179, 193.
(21) Shao, F.W.; Cai, Y. R.; Yao, J. M. Chem. J. Chin. Univ. 2010, 31, 1093. [邵锋伟, 蔡玉荣, 姚菊明. 高等学校化学学报, 2010, 31, 1093.]
(22) Zhang, Y. J.; Lu, J. J. Nanotechnol. 2008, 19, 155608.
(23) Cai, Y. R.; Jin, J.; Mei, D. P.; Xia, N. X.; Yao, J. M. J. Mater. Chem. 2009, 19, 5751.
(24) Aidin, L.; Mahyar, M.; Matin, M.; Amir, K.; Saeid, Z.; Hamed, A.; Sadrnezhaad, S. K. J. Am. Ceram. Soc. 2008, 91, 3292.
(25) Liu, J. B.; Li, K.W.;Wang, H.; Zhu, M. K.; Xu, H. Y.; Yan, H. Nanotechnol. 2005, 16, 82.
(26) Pan, H. H.; Tao, J. H.; Yu, X.W.; Fu, L.; Zhang, J. L.; Zeng, X. X.; Xu, G.; Tang, R. K. J. Phys. Chem. B 2008, 112, 7162
(27) Wei, G.; Reichert, J.; Bossert, J.; Jandt, K. D. Biomacromolecules 2008, 9, 3258.
(28) Li, L. Y.; Song,W. H.; Chen, T. H. Acta Phys. -Chim. Sin. 2009, 25, 2404. [李丽颖, 宋文华, 陈铁红. 物理化学学报, 2009, 25, 2404.]
(29) Liu, J. K.; Xu, Z. Z.;Wu, Q. S. Nano 2007, 2, 97.
(30) Liu, J. K.;Wu, Q. S.; Ding, Y. P. Cryst. Growth Des. 2005, 5, 445.
(31) Huang, Z. L.; Zhang, L. M.; Liu, Y.; He, Q. J.; Chen,W. J. Synthetic Cryst. 2006, 35, 261. [黄志良, 张联盟, 刘羽, 何前军, 陈伟. 人工晶体学报, 2006, 35, 261.]
(32) Yang, X. H.; Luo, C. X.; Liu, J. K.;Wang, J. D.; Chen, L. Acta Phys. -Chim. Sin. 2009, 25, 173. [杨小红, 罗重霄, 刘金库, 王建栋, 陈磊. 物理化学学报, 2009, 25, 173.]
(33) Luo, C. X.;Wang, Y.; Liu, J. K.; Lian, J. S.; Chai, C. F. Acta Phys.-Chim. Sin. 2008, 24, 1007. [罗重霄, 王燕, 刘金库, 连加松, 柴春芳. 物理化学学报, 2008, 24, 1007.]
(34) Zhang, L.; Chen, D. R.; Jiao X. L. J. Phys. Chem. B 2006, 110, 2668.
(35) Hu, M. C.; Zhong, S. H. Chin. J. Catal. 2006, 27, 1144. [胡茂从, 钟顺和, 催化学报, 2006, 27,1144.]
(36) Yolanda, P.; Mariano, F.; Avelino, C. Catal. Commun. 2011, 12: 1071.
(37) Huang, J.;Wang, L.C.; Liu, Y. M.; Cao, Y.; He, H. Y.; Fan, K. N. App. Catal. B-Environ. 2011, 101, 560.
(38) Hu, A. M.; Lei, T.; Li, M.; Chang, C. K.; Ling, H. Q.; Mao, D. L. Appl. Catal. B-Environ. 2006, 63, 41.
(39) Mineharu, T.; Masato,W.; Naoya, Y.; Toshiya,W. J. Mol. Catal. A- Chem. 2011, 338, 18.
(40) Zhang, L.W.; Cheng, H. Y.; Zong, R. L.; Zhu, Y. F. J. Phys. Chem. C 2009, 113, 2368.

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Facile Synthesis of Assembly HAP Nanoribbon Spheres and the Synergized Action of Its Photocatalytic Properties

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