质子型离子液体N,N-二甲基乙醇胺丙酸盐的密度、粘度及电导率

doi:10.3866/PKU.WHXB201307293

Acta Phys. -Chim. Sin. ›› 2013, Vol. 29 ›› Issue (10): 2157-2161.doi: 10.3866/PKU.WHXB201307293

• THERMODYNAMICS, KINETICS, AND STRUCTURAL CHEMISTRY • Previous Articles Next Articles

Density, Viscosity and Conductivity of Protic Ionic Liquid N,N-DimethylethanolammoniumPropionate

LI Chang-Ping¹, LI Zhuo^1,3, ZOU Ben-Xue², LIU Qing-Shan², LIU Xiao-Xia²

1 College of Chemical Engineering and Environment, Dalian University, Dalian 116622, Liaoning Province, P. R. China;
2 Department of Chemistry, Northeastern University, Shenyang 110819, P. R. China;
3 Scholl of Sciences, Dalian Ocean University, Dalian 116023, Liaoning Province, P. R. China

Received:2013-05-21 Revised:2013-07-29 Published:2013-09-26
Contact: LIU Qing-Shan, LIU Xiao-Xia E-mail:liuqingshan@dicp.ac.cn;xxliu@mail.neu.edu.cn
Supported by:
The project was supported by the National Natural Science Foundation of China (21176033, 21006007, 21203193, 21273029) and Research Foundation for the Doctoral Programof Higher Education of China (20120042110024).

Abstract

Abstract:

The density, viscosity, and conductivity of protic ionic liquid (PIL) N,N-dimethylethanolammonium propionate (DMEOAP) were determined in the temperature range of 283.15-333.15 K. The influence of temperature on density, viscosity, and conductivity is discussed. The thermal expansion coefficient, molecular volume, standard molar entropy, and lattice energy of DMEOAP were calculated using empirical and semiempirical equations. The molar conductivity of DMEOAP was determined fromdensity and conductivity data. The temperature dependence of viscosity and conductivity data was fitted using the Vogel-Fulcher-Tammann (VFT) equation. The relationship between molar conductivity and viscosity was determined by the Walden rule.

Key words: Protic ionic liquid, Density, Viscosity, Conductivity

Click here to download Supporting Info material in PDF type

LI Chang-Ping, LI Zhuo, ZOU Ben-Xue, LIU Qing-Shan, LIU Xiao-Xia. Density, Viscosity and Conductivity of Protic Ionic Liquid N,N-DimethylethanolammoniumPropionate[J]. Acta Phys. -Chim. Sin. 2013, 29(10), 2157-2161. doi: 10.3866/PKU.WHXB201307293

References

(1) Lissner, E.; Souza, W.; Ferrera, B.; Dupont, J. ChemSusChem2009, 10, 962.
(2) Zhu, W.; Li, H.; Jiang, X.; Yan, Y.; Lu, J.; Xia, J. Energy Fuels2007, 21, 2514. doi: 10.1021/ef700310r
(3) Wang, S. Q.; Zhou, L.; Su, W.; Sun, Y.; Zhou, Y. P. AIChE J.2009, 55, 1872. doi: 10.1002/aic.v55:7
(4) http://www.epa.gov/otaq/fuels/dieselfuels/index.htm, accessedMarch 2012.
(5) http://www.dieselnet.com/standards/eu/fuel.php, accessedMarch 2012.
(6) Song, C. S. Catalysis Today 2003, 86, 211. doi: 10.1016/S0920-5861(03)00412-7
(7) Prashant, S.; Carlos, A. Green Chem. 2010, 12, 1139. doi: 10.1039/c002113j
(8) Rantwijk, F. V. R.; Sheldon, A. Chem. Rev. 2007, 107,2757. doi: 10.1021/cr050946x
(9) Greaves, T. L. C.; Drummond, J. Chem. Rev. 2008, 108,206. doi: 10.1021/cr068040u
(10) Hapiot, P.; Lagrost, C. Chem. Rev. 2008, 108, 2238. doi: 10.1021/cr0680686
(11) Jessop, P. G.; Subramaniam, B. Chem. Rev. 2007, 107,2666. doi: 10.1021/cr040199o
(12) Rogers, R. D.; Seddon, K. R. Science 2003, 302, 792. doi: 10.1126/science.1090313
(13) Weingartner, H. Angew. Chem. Int. Edit. 2008, 47, 654.
(14) Chi, Y. S.; Zhang, Z. D.; Li, C. P.; Liu, Q. S.; Yan, P. F.; Welz-Biermann, U. Green Chem. 2011, 13, 666. doi: 10.1039/c0gc00864h
(15) Ueki, T.; Watanabe, M.; Yoshida, R. Angew. Chem. Int. Edit.2012, 51, 11991. doi: 10.1002/anie.201205061
(16) Peppel, T.; Roth, D. C.; Fumino, K.; Paschek, D.; Köckerling,M.; Ludwig, R. Angew. Chem. Int. Edit. 2011, 50, 6661. doi: 10.1002/anie.v50.29
(17) Li, Z.; Li, C. P.; Chi, Y. S.; Wang, A. L.; Zhang, Z. D.; Li, H. X.;Liu, Q. S. Welz-Biermann, U. Energy and Fuels 2012, 26 (6),3723. doi: 10.1021/ef3005064
(18) King, A. W.; Asikkala, J.; Mutikainen, I.; Järvi, P.; Kilpeläinen,I. Angew. Chem. Int. Edit. 2011, 123, 6425. doi: 10.1002/ange.201100274
(19) Liu, Q. S.; Yang, M.; Yan, P. F.; Liu, X. M.; Tan, Z. C.; Welz-Biermann, U. J. Chem. Eng. Data 2010, 55, 4928. doi: 10.1021/je100507n
(20) Liu, Q. S.; Yan, P. F.; Yang, M.; Tan, Z. C.; Li, C. P.; Welz-Biermann, U. Acta Phys. -Chim. Sin. 2011, 27, 2762. [刘青山,颜佩芳,杨淼,谭志诚, 李长平, Welz-Biermann, U.物理化学学报, 2011, 27, 2762.] doi: 10.3866/PKU.WHXB20112762
(21) Glasser, L. Thermochimica Acta 2004, 421, 87. doi: 10.1016/j.tca.2004.03.015
(22) Lide, D. R. Handbook of Chemistry and Physics, 82nd ed.; CRCPress: Boca Raton, FL, 2001-2002.
(23) Vila, J.; Ginés, P.; Pico, J. M.; Franjo, C.; Jiménez, E.; Varela, L.M.; Cabeza, O. Fluid Phase Equilibria 2006, 242, 141. doi: 10.1016/j.fluid.2006.01.022
(24) Schreiner, C.; Zugmann, S.; Hartl, R.; Gores, H. J. J. Chem. Eng. Data 2010, 55, 1784. doi: 10.1021/je900878j
(25) Belieres, J. P.; Angell, C. A. J. Phys. Chem. B 2007, 111,4926. doi: 10.1021/jp067589u

[1]	Yuehan Cao, Rui Guo, Minzhi Ma, Zeai Huang, Ying Zhou. Effects of Electron Density Variation of Active Sites in CO₂ Activation and Photoreduction: A Review [J]. Acta Phys. -Chim. Sin., 2024, 40(1): 2303029-.
[2]	Hanyu Xu, Xuedan Song, Qing Zhang, Chang Yu, Jieshan Qiu. Mechanistic Insights into Water-Mediated CO₂ Electrochemical Reduction Reactions on Cu@C₂N Catalysts: A Theoretical Study [J]. Acta Phys. -Chim. Sin., 2024, 40(1): 2303040-.
[3]	Heran Wang, Kai Chen, Shuo Fu, Haoxuan Wang, Jiaxuan Yuan, Xingyi Hu, Wenjuan Xu, Baoxiu Mi. Isomeric Bisbenzophenothiazines: Synthesis, Theoretical Calculations, and Photophysical Properties [J]. Acta Phys. -Chim. Sin., 2024, 40(1): 2303047-.
[4]	Cheng Luo, Qing Long, Bei Cheng, Bicheng Zhu, Linxi Wang. A DFT Study on S-Scheme Heterojunction Consisting of Pt Single Atom Loaded G-C₃N₄ and BiOCl for Photocatalytic CO₂ Reduction [J]. Acta Phys. -Chim. Sin., 2023, 39(6): 2212026-.
[5]	Yingying Zhu, Yong Wang, Miao Xu, Yongmin Wu, Weiping Tang, Di Zhu, Yu-Shi He, Zi-Feng Ma, Linsen Li. Tracking Pressure Changes and Morphology Evolution of Lithium Metal Anodes [J]. Acta Phys. -Chim. Sin., 2023, 39(1): 2110040-0.
[6]	Kunjie Wu, Yongyi Zhang, Zhenzhong Yong, Qingwen Li. Continuous Preparation and Performance Enhancement Techniques of Carbon Nanotube Fibers [J]. Acta Phys. -Chim. Sin., 2022, 38(9): 2106034-.
[7]	Ruoning Li, Xue Zhang, Na Xue, Jie Li, Tianhao Wu, Zhen Xu, Yifan Wang, Na Li, Hao Tang, Shimin Hou, Yongfeng Wang. Hierarchical Self-Assembly of Ag-Coordinated Motifs on Ag(111) [J]. Acta Phys. -Chim. Sin., 2022, 38(8): 2011060-.
[8]	Guangtao Cong, Yi-Chun Lu. Strategies to Improve the Energy Density of Non-Aqueous Organic Redox Flow Batteries [J]. Acta Phys. -Chim. Sin., 2022, 38(6): 2106008-.
[9]	Haoran Lu, Yaqing Wei, Run Long. Charge Localization Induced by Nanopore Defects in Monolayer Black Phosphorus for Suppressing Nonradiative Electron-Hole Recombination through Time-Domain Simulation [J]. Acta Phys. -Chim. Sin., 2022, 38(5): 2006064-.
[10]	Yishun Yang, Min Zhou, Yanxia Xing. Symmetry-Dependent Transport Properties of γ-Graphyne-based Molecular Magnetic Tunnel Junctions [J]. Acta Phys. -Chim. Sin., 2022, 38(4): 2003004-.
[11]	Xinrun Yu, Jun Ma, Chunbo Mou, Guanglei Cui. Percolation Structure Design of Organic-inorganic Composite Electrolyte with High Lithium-Ion Conductivity [J]. Acta Phys. -Chim. Sin., 2022, 38(3): 1912061-.
[12]	Houfu Song, Feiyu Kang. Recent Progress on Thermal Conduction of Graphene [J]. Acta Phys. -Chim. Sin., 2022, 38(1): 2101013-.
[13]	Runlin Fan, Yuhang Peng, Hao Tian, Junsheng Zheng, Pingwen Ming, Cunman Zhang. Graphite-Filled Composite Bipolar Plates for Fuel Cells: Material, Structure, and Performance [J]. Acta Phys. -Chim. Sin., 2021, 37(9): 2009095-.
[14]	Mengting Li, Xingqun Zheng, Li Li, Zidong Wei. Research Progress of Hydrogen Oxidation and Hydrogen Evolution Reaction Mechanism in Alkaline Media [J]. Acta Phys. -Chim. Sin., 2021, 37(9): 2007054-.
[15]	Xingang Fei, Haiyan Tan, Bei Cheng, Bicheng Zhu, Liuyang Zhang. 2D/2D Black Phosphorus/g-C₃N₄ S-Scheme Heterojunction Photocatalysts for CO₂ Reduction Investigated using DFT Calculations [J]. Acta Phys. -Chim. Sin., 2021, 37(6): 2010027-.

Density, Viscosity and Conductivity of Protic Ionic Liquid N,N-DimethylethanolammoniumPropionate

PDF

Like

Knowledge

Abstract

Supporting Info

Cite this article

share this article

References

Related Articles 15

Metrics

Recommended 0