光催化制氢研究进展

doi:10.3866/PKU.WHXB201905068

Abstract

Abstract:

The photocatalytic hydrogen evolution reaction (PHER) has gained much attention as a promising strategy for the generation of clean energy. As opposed to conventional hydrogen evolution strategies (steam methane reforming, electrocatalytic hydrogen evolution, etc.), the PHER is an environmentally friendly and sustainable method for converting solar energy into H₂ energy. However, the PHER remains unsuitable for industrial applications because of efficiency losses in three critical steps: light absorption, carrier separation, and surface reaction. In the past four decades, the processes responsible for these efficiency losses have been extensively studied. First, light absorption is the principal factor deciding the performance of most photocatalysts, and it is closely related to band-gap structure of photocatalysts. However, most of the existing photocatalysts have a wide bandgap, indicating a narrow light absorption range, which restricts the photocatalytic efficiency. Therefore, searching for novel semiconductors with a narrow bandgap and broadening the light absorption range of known photocatalysts is an important research direction. Second, only the photogenerated electrons and holes that migrate to the photocatalyst surface can participate in the reaction with H₂O, whereas most of the photogenerated electrons and holes readily recombine with one another in the bulk phase of the photocatalysts. Hence, tremendous effort has been undertaken to shorten the charge transfer distance and enhance the electric conductivity of photocatalysts for improving the separation and transfer efficiency of photogenerated carriers. Third, the surface redox reaction is also an important process. Because water oxidation is a four-electron process, sluggish O₂ evolution is the bottleneck in photocatalytic water splitting. The unreacted holes can easily recombine with electrons. Sacrificial agents are widely used in most catalytic systems to suppress charge carrier recombination by scavenging the photogenerated holes. Moreover, the low H₂ evolution efficiency of most photocatalysts has encouraged researchers to introduce highly active sites on the photocatalyst surface. Based on the abovementioned three steps, multifarious strategies have been applied to modulate the physicochemical properties of semiconductor photocatalysts with the aim of improving the light absorption efficiency, suppressing carrier recombination, and accelerating the kinetics of surface reactions. The strategies include defect generation, localized surface plasmon resonance (LSPR), element doping, heterojunction fabrication, and cocatalyst loading. An in-depth study of these strategies provides guidance for the design of efficient photocatalysts. In this review, we focus on the mechanism and application of these strategies for optimizing light absorption, carrier separation and transport, and surface reactions. Furthermore, we provide a critical view on the promising trends toward the construction of advanced catalysts for H₂ evolution.

Key words: Photocatalysis, Hydrogen evolution, Light absorption, Carriers separation, Surface reaction

Jinbo Pan,Sheng Shen,Wei Zhou,Jie Tang,Hongzhi Ding,Jinbo Wang,Lang Chen,Chak-Tong Au,Shuang-Feng Yin. Recent Progress in Photocatalytic Hydrogen Evolution[J]. Acta Physico-Chimica Sinica 2020, 36(3), 1905068. doi: 10.3866/PKU.WHXB201905068

Figures/Tables 17

References 100

1	Zhang G. ; Lan Z. A. ; Wang X. Angew. Chem. Int. Edit. 2016, 55, 15712. doi: 10.1002/anie.201607375
2	Tee S. Y. ; Win K. Y. ; Teo W. S. ; Koh L. D. ; Liu S. ; Teng C. P. ; Han M. Y. Adv. Sci. 2017, 4, 1600337. doi: 10.1002/advs.201600337
3	Wang W. ; Xu X. ; Zhou W. ; Shao Z. Adv. Sci. 2017, 4, 1600371. doi: 10.1002/advs.201600371
4	Su T. M ; Shao Q. ; Qin Z. Z. ; Guo Z. H. ; Wu Z. L. ACS Catal. 2018, 8, 2253. doi: 10.1021/acscatal.7b03437
5	Ran J. R. ; Zhang J. ; Yu J. G. ; Jaroniec M. ; Qiao S. Z. Chem. Soc. Rev. 2014, 43, 7787. doi: 10.1039/C3CS60425J
6	Yuan Y. J. ; Chen D. ; Yu Z. T. ; Zou Z. G. J. Mater. Chem. A 2018, 6, 11606. doi: 10.1039/C8TA00671G
7	Yang J. H. ; Wang D. ; Han H. X. ; Li C. Acc. Chem. Res. 2013, 46, 1900. doi: 10.1021/ar300227e
8	Yan J. H ; Wang T. ; Wu G. J ; Dai W. L ; Guan N. J ; Li L. D ; Gong J. L. Adv. Mater. 2015, 27, 1580. doi: 10.1002/adma.201404792
9	Zhou L. ; Yu X. Q. ; Zhu J. Nano Lett. 2014, 14, 1093. doi: 10.1021/nl500008y
10	Shi R. ; Ye H. F. ; Liang F. ; Wang Z. ; Li K. ; Weng Y. ; Lin Z. S ; Wen F. F. ; Che C. M. ; Chen Y. Adv. Mater. 2018, 30, 1705941. doi: 10.1002/adma.201705941
11	Ge M. Z. ; Cai J. S. ; Iocozzia J. ; Cao C. Y. ; Huang J. Y. ; Zhang X. N ; Shen J. L. ; Wang S. C ; Zhang S. N ; Zhang K. Q. ; et al Int. J. Hydroge. Energy 2017, 42, 8418. doi: 10.1016/j.ijhydene.2016.12.052
12	He J. ; Chen L. ; Yi Z. Q. ; Ding D. ; Au C. T. ; Yin S. F. Catal. Commun. 2017, 99, 79. doi: 10.1016/j.catcom.2017.05.029
13	Wang M. ; Ju P. ; Li J. J. ; Zhao Y. ; Han X. X. ; Hao Z. M. ACS Sustain. Chem. Eng. 2017, 5, 7878. doi: 10.1021/acssuschemeng.7b01386
14	Kong L. Q. ; Yan J. Q. ; Liu S. Z. ACS Sustain. Chem. Eng. 2018, 7, 1389. doi: 10.1021/acssuschemeng.8b05117
15	Liu J. N. ; Jia Q. H. ; Long J. L. ; Wang X. X. ; Gao Z. W. ; Gu Q. Appl. Catal. B-Environ. 2018, 222, 35. doi: 10.1016/j.apcatb.2017.09.073
16	Qi K. Z. ; Xie Y. B. ; Wang R. D. ; Liu S. Y. ; Zhao Z. Appl. Surf. Sci. 2019, 466, 847. doi: 10.1016/j.apsusc.2018.10.037
17	Zhang X. Y. ; Zhang Z. Z. ; Huang H. J. ; Wang Y. ; Tong N. ; Lin J. J. ; Liu D. ; Wang X. X. Nanoscale 2018, 10, 21509. doi: 10.1039/C8NR07186A
18	Kuehnel M. F. ; Creissen C. E. ; Sahm C. D. ; Wielend D. ; Schlosser A. ; Orchard K. L. ; Reisner. E. Angew. Chem. Int. Edit. 2019, 58, 5059. doi: 10.1002/anie.201814265
19	Singh R. ; Dutta S. Fuel 2018, 220, 607. doi: 10.1016/j.fuel.2018.02.068
20	Han X. ; Xu D. Y. ; An L. ; Hou C. Y. ; Li Y. G. ; Zhang Q. H. ; Wang H. Z. Int. J. Hydrog. Energy 2018, 43, 4845. doi: 10.1016/j.ijhydene.2018.01.117
21	Gao H. Q. ; Zhang P. ; Hu J. H. ; Pan J. M. ; Fan J. J. ; Shao G. S. Appl. Surf. Sci. 2017, 391, 211. doi: 10.1016/j.apsusc.2016.06.170
22	Liu Y. Z. ; Xu X. Y. ; Zhang J. Q. ; Zhang H. Y. ; Tian W. J. ; Li X. J. ; Tade M. O. ; Sun H. Q. ; Wang S. B. Appl. Catal. B-Environ. 2018, 239, 334. doi: 10.1016/j.apcatb.2018.08.028
23	Yuan Y. J. ; Li Z. J. ; Wu S. T. ; Chen D. Q. ; Yang L. X. ; Cao D. P. ; Tu W. G. ; Yu Z. T. ; Zou Z. G. Chem. Eng. J. 2018, 350, 335. doi: 10.1016/j.cej.2018.05.172
24	Xiao M. ; Luo B. ; Wang S. C. ; Wang L. Z. J. Energy. Chem. 2018, 27, 1111. doi: 10.1016/j.jechem.2018.02.018
25	Wang X. C. ; Maeda K. ; Thomas A. ; Takanabe K. ; Xin G. ; Carlsson J. M. ; Domen K. ; Antonietti M. Nat. Mater. 2009, 8, 76. doi: 10.1038/NMAT2317
26	Zhang L. Z. ; Jing D. W. ; Guo L. J. ; Yao X. D. ACS Sustain. Chem. Eng. 2014, 2, 1446. doi: 10.1021/sc500045e
27	Zhao Y. F. ; Yang Z. Y. ; Zhang Y. X. ; Jing L. ; Guo X. ; Ke Z. ; Hu P. ; Wang G. ; Yan Y. M. ; Sun K. N. J. Phys. Chem. C 2014, 118, 14238. doi: 10.1021/jp504005x
28	Chai B. ; Peng T. Y. ; Zeng P. ; Zhang X. H. ; Liu X. J. Phys. Chem. C 2011, 115, 6149. doi: 10.1021/jp1112729
29	Chaudhari N. S. ; Bhirud A. P. ; Sonawane R. S. ; Nikam L. K. ; Warule S. S. ; Rane V. H. ; Kale B. B. Green Chem. 2011, 13, 2500. doi: 10.1039/C1GC15515F
30	Liu C. ; Chai B. ; Wang C. L. ; Yan J. T. ; Ren Z. D. Int. J. Hydrog. Energy 2018, 43, 6977. doi: 10.1016/j.ijhydene.2018.02.116
31	Li T. L. ; Cai C. D. ; Yeh T. F. ; Teng H. S. J. Alloy. Compd. 2013, 550, 326. doi: 10.1016/j.jallcom.2012.10.157
32	Xue C. ; An H. ; Yan X. Q. ; Li J. L. ; Yang B. L. ; Wei J. J. ; Yang G. D. Nano Energy 2017, 39, 513. doi: 10.1016/j.nanoen.2017.07.030
33	Yi S. S. ; Zhang X. B. ; Wulan B. R. ; Yan J. M. ; Jiang Q. Energ. Environ. Sci. 2018, 11, 3128. doi: 10.1039/C8EE02096E
34	Zheng Z. Z. ; Xie W. ; Huang B. B. ; Dai Y. Chem. Eur. J. 2018, 24, 18322. doi: 10.1002/chem.201803705
35	Kong X. C. ; Xu Y. M. ; Cui Z. D. ; Li Z. Y. ; Liang Y. ; Gao Z. H. ; Zhu S. L. ; Yang X. J. Appl. Catal. B-Environ. 2018, 230, 11. doi: 10.1016/j.apcatb.2018.02.019
36	Liu C. ; Wu P. C. ; Wu J. N. ; Hou J. ; Bai H. C. ; Liu Z. Y. Chem. Eng. J. 2019, 359, 58. doi: 10.1016/j.cej.2018.11.117
37	Yousaf A. B. ; Imran M. ; Zaidi S. J. ; Kasak P. Sci. Rep. 2017, 7, 6574. doi: 10.1038/s41598-017-06808-6
38	Wang J. P. ; Cong J. K. ; Xu H. ; Wang J. M. ; Liu H. ; Liang M. ; Gao J. K. ; Ni Q. Q. ; Yao J. M. ACS Sustain. Chem. Eng. 2017, 5, 10633. doi: 10.1021/acssuschemeng.7b02608
39	Gao H. Q. ; Zhang P. ; Zhao J. T. ; Zhang Y. S. ; Hu J. H. ; Shao G. S. Appl. Catal. B-Environ. 2017, 210, 297. doi: 10.1016/j.apcatb.2017.03.050
40	Lou Y. B. ; Zhang Y. K. ; Cheng L. ; Chen J. X. ; Zhao Y. X. ChemSusChem 2018, 11, 1505. doi: 10.1002/cssc.201800249
41	Xu G. L. ; Shen J. C. ; Chen S. M. ; Gao Y. J. ; Zhang H. B. ; Zhang J. Phys. Chem. Chem. Phys. 2018, 20, 17471. doi: 10.1039/C8CP01986J
42	Yang Y. R. ; Ye K. ; Cao D. X. ; Gao P. ; Qiu M. ; Liu L. ; Yang P. P. ACS Appl. Mater. Inter. 2018, 10, 19633. doi: 10.1021/acsami.8b02804
43	He J. ; Chen L. ; Yi Z. Q. ; Au C. T. ; Yin S. F. Ind. Eng. Chem. Res. 2016, 55, 8327. doi: 10.1021/acs.iecr.6b01511
44	Shi R. ; Ye H. F. ; Liang F. ; Wang Z. ; Li K. ; Weng Y. X. ; Lin Z. S. ; Fu W. F. ; Che C. M. ; Chen Y. J. Adv Mater. 2017, 30, 1705941. doi: 10.1002/adma.201705941
45	Chen, J.; Shen, S. H.; Guo, P. H.; Wang, M.; Wu, P.; Wang, X. X.; Guo, L. J. Appl. Catal. B-Environ. 2014, 152–153, 335. doi: 10.1016/j.apcatb.2014.01.047
46	She X. J. ; Wu J. J. ; Xu H. ; Zhong J. ; Wang Y. ; Song Y. H. ; Nie K. Q. ; Liu Y. ; Yang Y. C. ; Rodrigues M. T. et al. Adv. Energy. Mater. 2017, 7, 1700025. doi: 10.1002/aenm.201700025
47	Cui H. J. ; Li B. B. ; Li Z. Y. ; Li X. Z ; Xu S. Appl. Surf. Sci. 2018, 455, 831. doi: 10.1016/j.apsusc.2018.06.054
48	Xing J. ; Li Y. H. ; Jiang H. B. ; Wang Y. ; Yang H.G. Int. J. Hydrog. Energy 2014, 39, 1237. doi: 10.1016/j.ijhydene.2013.11.041
49	Xiao J. D. ; Han L. L. ; Luo J. ; Yu S. H. ; Jiang H. L. Angew. Chem. Int. Edit. 2017, 57, 1103. doi: 10.1002/anie.201711725
50	Bian H. ; Ji Y. J ; Yan J. Q. ; Li P. ; Li L. ; Li Y. Y. ; Liu S. Z. Small 2018, 14, 1703003. doi: 10.1002/smll.201703003
51	Qi K. Z ; Xie Y. B ; Wang R. D ; Liu S. Y. ; Zhao Z. Appl. Surf. Sci. 2019, 466, 847. doi: 10.1016/j.apsusc.2018.10.037
52	Li H. ; Li J. ; Ai Z. H. ; Jia F. L. ; Zhang L. Z. Angew. Chem. Int. Edit. 2018, 57, 122. doi: 10.1002/anie.201705628
53	Fang Z. L. ; Bueken B. ; De Vos D. E. ; Fischer R. A. Angew. Chem. Int. Edit. 2015, 54, 7234. doi: 10.1002/anie.201411540
54	Bai S. ; Zhang N. ; Gao C. ; Xiong Y. J. Nano Energy 2018, 53, 296. doi: 10.1016/j.nanoen.2018.08.058
55	Seo H. S. ; Ping Y. ; Galli G. Chem. Mater. 2018, 30, 7793. doi: 10.1021/acs.chemmater.8b03201
56	Jang J. W. ; Friedrich D. ; Müller S. ; Lamers M. ; Hempel H. ; Lardhi S. ; Cao Z. ; Harb M. ; Cavallo L. ; Heller R. et al. Adv. Energy. Mater. 2017, 7, 1701536. doi: 10.1002/aenm.201701536
57	Kong X. C. ; Xu Y. M. ; Cui Z. D. ; Li Z. ; Liang Y. Z. ; Gao Z. H. ; Zhu S. L. ; Yang X.J. Appl. Catal. B-Environ. 2018, 230, 11. doi: 10.1016/j.apcatb.2018.02.019
58	Wu Y. Q. ; Lu G. X. Phys. Chem. Chem. Phys. 2014, 16, 4165. doi: 10.1039/C3CP54461C
59	Wang, G.; Yang, Y.; Han, D.; Li, Y. Nano Today 2017, 13, 23. doi: 10.1039/C3CP54461C
60	Cronemeyer D. C. Phys. Rev. 1959, 113, 1222. doi: 10.1103/PhysRev.113.1222
61	Chen X. B. ; Liu L. ; Yu P. Y. ; Mao S. S. Science 2011, 331, 746. doi: 10.1126/science.1200448
62	Zheng J. Y. ; Lyu Y. H. ; Xie C. ; Wang R. L. ; Tao L. ; Wu H. B. ; Zhou H. J. ; Jiang S. P. ; Wang S. Y. Adv. Mater. 2018, 30, 1801773. doi: 10.1002/adma.201801773
63	Wang P. ; Huang B. B. ; Qin X. Y. ; Zhang X. Y. ; Dai Y. ; Wei J. Y. ; Whangbo M. H. Angew. Chem. Int. Ed. 2008, 47, 7931. doi: 10.1002/anie.200802483
64	Pan J. B. ; Liu J. J. ; Ma H. C. ; Zuo S. L. ; Khan U. A. ; Yu Y. C. ; Li B. S. New. J. Chem. 2018, 42, 7293. doi: 10.1039/C8NJ00394G
65	Agrawal A. ; Cho S. H. ; Zandi O. ; Ghosh S. ; Johns R. W. ; Milliron D. J. Chem. Rev. 2018, 118, 3121. doi: 10.1021/acs.chemrev.7b00613
66	Du X. H. ; Li Y. ; Yin H. ; Xiang Q. J. Acta Phys. -Chim. Sin. 2018, 34, 414. doi: 10.3866/PKU.WHXB201708283
	杜新华; 李阳; 殷辉; 向全军. 物理化学学报, 2018, 34, 414. doi: 10.3866/PKU.WHXB201708283
67	Gao H. Q. ; Zhang P. ; Zhao J. T. ; Zhang Y. S. ; Hu J. H. ; Shao G. S. Appl. Catal. B-Environ. 2017, 210, 297. doi: 10.1016/j.apcatb.2017.03.050
68	Wang J. P. ; Cong J. K. ; Xu H. ; Wang J. ; Liu H. ; Liang M. ; Gao J. K. ; Ni Q. Q. ; Yao J. M. ACS Sustain. Chem. Eng. 2017, 5, 10633. doi: 10.1021/acssuschemeng.7b02608
69	Zhang Z. Y. ; Liu Y. ; Fang Y. R. ; Cao B. S. ; Huang J. D. ; Liu K. C. ; Dong B. Adv. Sci. 2018, 5, 1800748. doi: 10.1002/advs.201800748
70	Chilkalwar A. A. ; Rayalu S. S. J. Phys. Chem. C 2018, 122, 26307. doi: 10.1021/acs.jpcc.8b05480
71	Li D. D. ; Yu S. H. ; Jiang H. L. Adv. Mater. 2018, 30, 1707377. doi: 10.1002/adma.201707377
72	Lim W. Y. ; Wu H. ; Lim Y. F. ; Ho G. W. J. Mater. Chem. A 2018, 6, 11416. doi: 10.1039/C8TA02763C
73	Wang Z. L. ; Qi Y. ; Ding C. M. ; Fan D. Y. ; Liu G. J. ; Zhao Y. L. ; Li C. Chem. Sci. 2016, 7, 4391. doi: 10.1039/C6SC00245E
74	Pradhan N. ; Das Adhikari S. ; Nag A. ; Sarma D. D. Angew. Chem. Int. Edit. 2017, 56, 7038. doi: 10.1002/anie.201611526
75	Jiang L. B. ; Yuan X. Z. ; Pan Y. ; Liang J. ; Zeng G. M. ; Wu Z. B. ; Wang H. Appl. Catal. B-Environ. 2017, 217, 388. doi: 10.1016/j.apcatb.2017.06.003
76	Cheng R. L. ; Jin X. X. ; Fan X. Q. ; Wang M. ; Tian J. J. ; Zhang L. X. ; Shi J. L. Acta Phys. -Chim. Sin. 2017, 33, 1436. doi: 10.3866/PKU.WHXB201704076
	程若霖; 金锡雄; 樊向前; 王敏; 田建建; 张玲霞; 施剑林. 物理化学学报, 2017, 33, 1436. doi: 10.3866/PKU.WHXB201704076
77	Li Z. ; Kong C. ; Lu G. X. J. Phys. Chem. 2015, 120, 56. doi: 10.1021/acs.jpcc.5b09469
78	Chen Z. ; Fan T. T. ; Yu X. ; Wu Q. L. ; Zhu Q. H. ; Zhang L. Z. ; Li J. H. ; Fang W. P. ; Yi X. D. J. Mater. Chem. 2018, 6, 15310. doi: 10.1039/C8TA03303J
79	Li X. ; Liu P. W. ; Mao Y. ; Xing M. Y. ; Zhang J. L. Appl. Catal. B-Environ. 2015, 164, 352. doi: 10.1016/j.apcatb.2014.09.053
80	Zhu Y. P. ; Ren T. Z. ; Yuan Z. Y. ACS Appl. Mater. Inter. 2015, 7, 16850. doi: 10.1021/acsami.5b04947
81	Li H. J. ; Tu W. G. ; Zhou Y. ; Zou Z. G. Adv. Sci. 2016, 3, 1500389. doi: 10.1002/advs.201500389
82	Xu Q. L. ; Zhang L. Y. ; Yu J. G. ; Wageh S. ; Al-Ghamdi A. A. ; Jaroniec M. Mater. Today 2018, 21, 1042. doi: 10.1016/j.mattod.2018.04.008
83	Zhou P. ; Yu J. ; Jaroniec M. Adv. Mater. 2014, 26, 4920. doi: 10.1002/adma.201400288
84	Pan J. B. ; Liu J. J. ; Ma H. C. ; Zuo S. L. ; Khan U. A. ; Yu Y. C. ; Li B. S. Appl. Surf. Sci. 2018, 444, 177. doi: 10.1016/j.apsusc.2018.01.189
85	Li H. J. ; Tu W. G. ; Zhou Y. ; Zou Z. G. Adv. Sci. 2016, 3, 1500389. doi: 10.1002/advs.201500389
86	Fu J. W. ; Xu Q. L. ; Low J. X. ; Jiang C. J. ; Yu J. G. Appl. Catal. B-Environ. 2019, 243, 556. doi: 10.1016/j.apcatb.2018.11.011
87	Yu W. L. ; Zhang S. ; Chen J. X. ; Xia P. F. ; Richter M. H. ; Chen L. F. ; Xu W. ; Jin J. P. ; Chen S. L. ; Peng T. Y. J. Mater. Chem. A 2018, 6, 15668. doi: 10.1039/C8TA02922A
88	Fei Y. ; Li H. F. ; Yu H. T. ; Chen S. ; Xie Q. Appl. Catal. B-Environ. 2018, 227, 258. doi: 10.1016/j.apcatb.2017.12.020
89	Yu Z. B. ; Xie Y. P. ; Liu G. ; Lu G. Q. ; Ma X. L. ; Cheng H. M. J. Mater. Chem. A 2013, 1, 2773. doi: 10.1039/C3TA01476B
90	Tada H. ; Mitsui T. ; Kiyonaga T. ; Akita T. ; Tanaka K. Nat. Mater. 2006, 5, 782. doi: 10.1038/nmat1734
91	Li, W. B.; Feng, C.; Dai, S. Y.; Yue, J. G.; Hua, F. X.; Hou, H. Appl. Catal. B-Environ. 2015, 168–169, 465. doi: 10.1016/j.apcatb.2015.01.012
92	Xiao M. ; Luo B. ; Wang S. C. ; Wang L. Z. J. Energy. Chem. 2018, 27, 1111. doi: 10.1016/j.jechem.2018.02.018
93	Fu J. W. ; Bie C. B. ; Cheng B. ; Jiang C. J. ; Yu J. G. ACS Sustain. Chem. Eng. 2018, 6, 2767. doi: 10.1021/acssuschemeng.7b04461
94	Kuehnel M. F. ; Creissen C. E. ; Sahm C. D. ; Wielend D. ; Schlosser A. ; Orchard K. L. ; Reisner. E. Angew. Chem. Int. Edit. 2019, 58, 5059. doi: 10.1002/anie.201814265
95	Yuan Y. J. ; Chen D. ; Zhong J. ; Yang L. X. ; Wang J. ; Liu M. J. ; Tu W. G. ; Yu Z.T. ; Zou Z. G. J. Mater. Chem. A 2017, 5, 15771. doi: 10.1039/C7TA04410K
96	Xue F. ; Liu M. C. ; Cheng C. ; Deng J. K. ; Shi J. W. ChemCatChem 2018, 10, 5441. doi: 10.1002/cctc.201801510
97	Seh Z. W. ; Kibsgaard J. ; Dickens C. F. ; Chorkendorff I. ; Norskov J. K. ; Jaramillo T. F. Science 2017, 355, 1. doi: 10.1126/science.aad4998
98	Zhu Y. Q. ; Wang T. ; Xu T. ; Li Y. X. ; Wang C. Y. Appl. Surf. Sci. 2019, 464, 36. doi: 10.1016/j.apsusc.2018.09.061
99	Zhang C. ; Wu Z. J. ; Liu J. J. ; Piao L. Y. Acta Phys. -Chim. Sin. 2017, 33, 1492. doi: 10.3866/PKU.WHXB201704141
	张驰; 吴志娇; 刘建军; 朴玲玉. 物理化学学报, 2017, 33, 1492. doi: 10.3866/PKU.WHXB201704141
100	Hou Y. D. ; Laursen A. B. ; Zhang J. S. ; Zhang G. G. ; Zhu Y. S. ; Wang X. C. ; Dahl S. ; Chorkendorff I. Angew. Chem. Int. Edit. 2013, 52, 3621. doi: 10.1002/anie.201210294

Strategy	Photocatalyst	Sacrificial agent	Light source	H₂ evolution rate/(μmol·h⁻¹·g⁻¹)	Ref.
Ov	Vo-γ-Ga₂O₃	CH₃OH	125 W mercury lamp	25600	17
Ov	Vo-TiO₂	–	300 W Xenon lamp, AM 1.5	160	35
Ov/HF	C@TiO₂₋_x/g-C₃N₄	triethanolamine	300 W xenon lamp, λ > 420 nm	417.24	36
Ov/HF	Zn_0.3Cd_0.7S/WO_3–x	Na₂S/Na₂SO₃	300 W xenon lamp, λ > 420 nm	3521	37
LSPR	Ag/g-C₃N₄	triethanolamine	300 W xenon lamp, λ > 420 nm	625	38
LSPR/HF	TiO₂/WO₃/Au	CH₃OH	300 W Xenon lamp	3476.8	39
LSPR/HF	Cu@Cu₂O/ZnO	Na₂S/Na₂SO₃	300 W Xenon lamp	1472.2	40
ED	O-doped C₃N₄	TEOA	300 W xenon lamp, λ > 420 nm	1690	41
ED	F-TiO₂	CH₃OH	300 W xenon lamp, λ > 405 nm	18270	42
ED	P-doped CdS	–	90W LED, λ > 420 nm	231	43
HF	WS₂/CdS	lactic acid	300 W xenon lamp, λ > 420 nm	61100	44
HF	Cu₂O/C₃N₄	TEOA	300 W xenon lamp, λ > 420 nm	241.3	45
HF	α-Fe₂O₃/g-C₃N₄	TEOA	300 W xenon lamp, λ > 400 nm	31400	46
HF	CdS/CdWO₄	Na₂S/Na₂SO₃	300 W xenon lamp, λ > 420 nm	2400	47
CL	Pt/TiO₂ nanotubes	glycerol	Solar light	173.3	48
CL/LSPR	Pt@MIL-125/Au	TEOA	300 W xenon lamp, λ > 380 nm	1743	49
CL	MoS₂/Co-C₃N₄	TEOA	200 W xenon lamp, λ > 400 nm	1990	50
CL	Ni-P/g-C₃N₄	TEOA	350 W xenon lamp	1051	51

[1]	Chengbo Zhang, Xiaoping Tao, Wenchao Jiang, Junxue Guo, Pengfei Zhang, Can Li, Rengui Li. Microwave-Assisted Synthesis of Bismuth Chromate Crystals for Photogenerated Charge Separation [J]. Acta Phys. -Chim. Sin., 2024, 40(1): 2303034-.
[2]	Kezhen Lai, Fengyan Li, Ning Li, Yangqin Gao, Lei Ge. Identification of Charge Transfer Pathways in Metal-Organic Framework- Derived Ni-CNT/ZnIn₂S₄ Heterojunctions for Photocatalytic Hydrogen Evolution [J]. Acta Phys. -Chim. Sin., 2024, 40(1): 2304018-.
[3]	Qianwei Song, Guanchao He, Huilong Fei. Photothermal Catalytic Conversion Based on Single Atom Catalysts: Fundamentals and Applications [J]. Acta Phys. -Chim. Sin., 2023, 39(9): 2212038-0.
[4]	Xinhe Wu, Guoqiang Chen, Juan Wang, Jinmao Li, Guohong Wang. Review on S-Scheme Heterojunctions for Photocatalytic Hydrogen Evolution [J]. Acta Phys. -Chim. Sin., 2023, 39(6): 2212016-0.
[5]	Keyu Zhang, Yunfeng Li, Shidan Yuan, Luohong Zhang, Qian Wang. Review of S-Scheme Heterojunction Photocatalyst for H₂O₂ Production [J]. Acta Phys. -Chim. Sin., 2023, 39(6): 2212010-.
[6]	Zhen Li, Wen Liu, Chunxu Chen, Tingting Ma, Jinfeng Zhang, Zhenghua Wang. Transforming the Charge Transfer Mechanism in the In₂O₃/CdSe-DETA Nanocomposite from Type-I to S-Scheme to Improve Photocatalytic Activity and Stability During Hydrogen Production [J]. Acta Phys. -Chim. Sin., 2023, 39(6): 2208030-.
[7]	Zhongliao Wang, Jing Wang, Jinfeng Zhang, Kai Dai. Overall Utilization of Photoexcited Charges for Simultaneous Photocatalytic Redox Reactions [J]. Acta Phys. -Chim. Sin., 2023, 39(6): 2209037-.
[8]	Zhongqi Zan, Xibao Li, Xiaoming Gao, Juntong Huang, Yidan Luo, Lu Han. 0D/2D Carbon Nitride Quantum Dots (CNQDs)/BiOBr S-Scheme Heterojunction for Robust Photocatalytic Degradation and H₂O₂ Production [J]. Acta Phys. -Chim. Sin., 2023, 39(6): 2209016-.
[9]	Wenjie Zhou, Qihang Jing, Jiaxin Li, Yingzhi Chen, Guodong Hao, Lu-Ning Wang. Organic Photocatalysts for Solar Water Splitting: Molecular- and Aggregate-Level Modifications [J]. Acta Phys. -Chim. Sin., 2023, 39(5): 2211010-0.
[10]	Erjun Lu, Junqian Tao, Can Yang, Yidong Hou, Jinshui Zhang, Xinchen Wang, Xianzhi Fu. Carbon-Encapsulated Pd/TiO₂ for Photocatalytic H₂ Evolution Integrated with Photodehydrogenative Coupling of Amines to Imines [J]. Acta Phys. -Chim. Sin., 2023, 39(4): 2211029-0.
[11]	Yonggang Lei, Tianyu Zhao, Kim Hoong Ng, Yingzhen Zhang, Xuerui Zang, Xiao Li, Weilong Cai, Jianying Huang, Jun Hu, Yuekun Lai. Metallic Tungsten Carbide Coupled with Liquid-Phase Dye Photosensitizer for Efficient Photocatalytic Hydrogen Production [J]. Acta Phys. -Chim. Sin., 2023, 39(4): 2206006-0.
[12]	Siran Xu, Qi Wu, Bang-An Lu, Tang Tang, Jia-Nan Zhang, Jin-Song Hu. Recent Advances and Future Prospects on Industrial Catalysts for Green Hydrogen Production in Alkaline Media [J]. Acta Phys. -Chim. Sin., 2023, 39(2): 2209001-0.
[13]	Jing Kong, Jingui Zhang, Sufen Zhang, Juqun Xi, Ming Shen. Performance Improvement and Antibacterial Mechanism of BiOI/ZnO Nanocomposites as Antibacterial Agent under Visible Light [J]. Acta Phys. -Chim. Sin., 2023, 39(12): 2212039-.
[14]	Zheng-Min Wang, Qing-Ling Hong, Xiao-Hui Wang, Hao Huang, Yu Chen, Shu-Ni Li. RuP Nanoparticles Anchored on N-doped Graphene Aerogels for Hydrazine Oxidation-Boosted Hydrogen Production [J]. Acta Phys. -Chim. Sin., 2023, 39(12): 2303028-.
[15]	Shuyi Zheng, Jia Wu, Ke Wang, Mengchen Hu, Huan Wen, Shibin Yin. Electronic Modulation of Ni-Mo-O Porous Nanorods by Co Doping for Selective Oxidation of 5-Hydroxymethylfurfural Coupled with Hydrogen Evolution [J]. Acta Phys. -Chim. Sin., 2023, 39(12): 2301032-.

Recent Progress in Photocatalytic Hydrogen Evolution

RichHTML

PDF

Like

Knowledge

Abstract

Cite this article

share this article

Figures/Tables 17

References 100

Related Articles 15

Metrics

Recommended 0