二维共价有机框架作为光催化剂在有机合成中的研究进展

doi:10.1016/j.actphy.2025.100086

Abstract

Abstract:

Two-dimensional covalent organic frameworks (2D COFs) exhibit distinctive characteristics, including tunable topology, an extensive specific surface area, susceptibility to functionalization, and robust stability, making them frequently utilizedin multiphase photocatalytic applications. This article begins with an overview of the synthesis methods for 2D COFs, covering solvothermal, ionothermal, mechanochemical, microwave-assisted, sonochemical, and interfacial synthesis techniques. It provides a concise introduction to various factors influencing photocatalytic performance, such as crystallinity and stability, band structure, charge transfer capability, pore size and specific surface area, and the nature of the light source. Subsequently, the discussion shifts to summarizing and analyzing advancements in the use of 2D COFs as photocatalysts for organic small molecule conversion reactions, particularly in photocatalytic oxidation, reduction, and coupling reactions. Finally, summary and outlook are presented regarding the opportunities and challenges that 2D COFs face in photocatalytic organic transformations.

Key words: Two-dimension, Covalent organic framework, Photocatalysis, Oxidation reaction, Reduction reaction, Cross-coupling reaction

Lewang Yuan, Yaoyao Peng, Zong-Jie Guan, Yu Fang. Insights into the development of 2D covalent organic frameworks as photocatalysts in organic synthesis[J]. Acta Phys. -Chim. Sin. 2025, 41(8), 100086. doi: 10.1016/j.actphy.2025.100086

Figures/Tables 21

Table 1

Summary of photocatalytic COFs materials."

Catalysts		Synthesis method	Reaction		Ref.
Original	Renamed	Synthesis method	Reaction type	Conversion type	Ref.
COF-1	1	solvothermal	–		[25]
COF-5	2	solvothermal	–		[25]
TAPB-TaBr₂	3	solvothermal	–		[43]
CTF-1	4	ionic thermal	–		[44]
CTF-2	5	ionic thermal	–		[45]
TzPm-COF	6	microwave-assisted	Cross-coupling	C–N Cross-coupling	[46]
CONs	7	sonochemical	–		[47]
TPDA-DHBD	8	interface synthesis	–		[48]
ivCOF-O	9	solvothermal	–		[49]
vCOF-N	10	modification	–		[49]
TBC-COF	11	solvothermal	H₂O₂ Production		[50]
TBD-COF	12	solvothermal	H₂O₂ Production		[50]
BTT-BPy-PCOF	13	solvothermal/protonation	Hydrogen Evolution		[51]
Cu₃-TPA-COF	14	solvothermal	CO₂ Reduction		[52]
Cu₃-TAPB-COF	15
Cu₃-TAPT-COF	16
PTH-S-COF	17	solvothermal	H₂O₂ Production		[53]
PTH-SO-COF	18
PTH-SO₂-COF	19
LZU-190	20	solvothermal	Oxidation	Aryl Boronic Acid Oxidation	[54]
Cy-N₃-COF	21	photocatalytic			[55]
TAD-COF	22	solvothermal			[56]
PyPor-COF	23	solvothermal		Oxidation of Sulfides	[57]
COF-366 (Ni)	24	solvothermal			[58]
TpBpy-COF	25	solvothermal			[59]
TPBD-H-COF	26	solvothermal		Oxidative Coupling of Amines	[60]
TPBD-F-COF	27
TPBD-NO₂-COF	28
TPBD-CN-COF	29
TpDAF-COF	30	solvothermal			[61]
TpMFC-COF	31
TpFFC-COF	32
TpDPP-Py COFs	33	solvothermal			[62]
DPP-Py COFs	34	solvothermal			[62]
COF-JLU22	35	solvothermal	Reduction	Dehalogenation Reduction	[63]
D_TF-A_NDI-COF	36	solvothermal			[64]
COF_D5	37	solvothermal			[65]
COF_D19	38
Am-COF_D5	39	modification (NHC)
Am-COF_D19	40
COF-V_x	41	solvothermal		Nitro Reduction	[66]
COF-S_x	42	modification
Pt@COF-S_x	Pt@42
TAPP-COF	43	solvothermal			[67]
Ag₁₀@TAPP-COF	Ag@43	modification
Tsc-COF	44	solvothermal	Cross-coupling	C–C Cross-coupling	[68]
Tch-COF	45
TU-COF	46
Pd@TU-COF	Pd@46	modification	Cross-coupling	C–C Cross-coupling	[68]
AntCOF	47	solvothermal			[69]
Pd/AntCOF	Pd/47	modification			[69]
Tp-Bpy	48	solvothermal		C–N Cross-coupling	[70]
Ir@Tp-Bpy	Ir@48	modification
Ni-Ir@Tp-Bpy	Ni-Ir@48	modification
TTT-DHTD-COF	49	solvothermal			[71]
SCN	50	solvothermal		C–O Cross-coupling	[72]
NiSCN	51	modification			[72]
BPh-COF	52	solvothermal			[73]
AC-COF	53	solvothermal			[73]
Ace-COF	54	solvothermal		C–S Cross-coupling	[74]
Ace-COF-Ni	54-Ni	modification			[74]
Bpy-sp²c-COF	55	solvothermal			[75]
Ni@Bpy-sp²c-COF	Ni@55	modification			[75]
NQ-COF_E5	56	solvothermal	C-H Functionalization		[76]
NQ-COF_E5-O	57	modification (m-CPBA)	C-H Functionalization		[76]
TpAzo	58	solvothermal	C-H Borylation		[77]
TpDpp	59
TpTab	60
COF-316	61	solvothermal	C-H Activation		[78]
COF-316-COOH	62	modification
Rh-COF-316	Rh-62	modification
COF-318	63	solvothermal
COF-318-COOH	64	modification
Rh-COF-318	Rh-64	modification

Table 1

Fig 1

Fig 2

Fig 3

Fig 4

Fig 5

Fig 6

Fig 7

Fig 8

Fig 9

Fig 10

Fig 11

Fig 12

Fig 13

Fig 14

Fig 15

Fig 16

Fig 17

Fig 18

Fig 19

Fig 20

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Insights into the development of 2D covalent organic frameworks as photocatalysts in organic synthesis

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