Er2(PhCH2COO)6·4H2O的结构及热分析

doi:10.3866/PKU.WHXB19920513

Acta Phys. -Chim. Sin. ›› 1992, Vol. 8 ›› Issue (05): 642-646.doi: 10.3866/PKU.WHXB19920513

• ARTICLE • Previous Articles Next Articles

Crystal Structure and Thermal Analysis of Erbium Complex with Benzene Acetic Acid

Wang Zeng-Lin; Hu Ning-Hai; Niu Chun-Ji; Ni Jia-Zuan; Cui Ai-Li

Changchun Institute of Chemistry, Chinese Academy of Science, Changchun 130022; Changchun Specialized School of Metallurgy and Geology, Changchun 130021

Received:1991-04-12 Revised:1992-03-20 Published:1992-10-15
Contact:

Abstract

Abstract: The crystal structure of erbium (Ⅲ) complex of benzene acetic acid is reported. The complex crystallizes in the monoclinic space group P_2_1/a with a=0.9008(3) nm, b=1.4242(5) nm, c=1.8437(7) nm; β=98.80(3)°, V=2.337(1) nm~3, Z=4. The mechanism of thermal decomposition of complex has been studied by TG-DTG-DTA. The activation energy for dehydration reaction has been calculated by Freeman-Carroll method. The enthalpy change for dehydration and phase change process has been determined.

Key words: Erbium eomplex, Crystal structure, Thermal analysis

Wang Zeng-Lin; Hu Ning-Hai; Niu Chun-Ji; Ni Jia-Zuan; Cui Ai-Li. Crystal Structure and Thermal Analysis of Erbium Complex with Benzene Acetic Acid[J]. Acta Phys. -Chim. Sin. 1992, 8(05), 642-646. doi: 10.3866/PKU.WHXB19920513

[1]	Yuyao Wang, Zhitao Cao, Zeyu Du, Xinxin Cao, Shuquan Liang. Research Progress of Iron-based Polyanionic Cathode Materials for Sodium-Ion Batteries [J]. Acta Phys. -Chim. Sin., 2025, 41(4): 100035-.
[2]	Chenyue Huang, Hongfei Zheng, Ning Qin, Canpei Wang, Liguang Wang, Jun Lu. Single-Crystal Nickel-Rich Cathode Materials: Challenges and Strategies [J]. Acta Phys. -Chim. Sin., 2024, 40(9): 2308051-.
[3]	Xianhong Chen, Pengchao Ruan, Xianwen Wu, Shuquan Liang, Jiang Zhou. Crystal Structures, Reaction Mechanisms, and Optimization Strategies of MnO₂ Cathode for Aqueous Rechargeable Zinc Batteries [J]. Acta Phys. -Chim. Sin., 2022, 38(11): 2111003-.
[4]	Zijun Jing, Chen Tan Khai, Teng He, Yang Yu, Qijun Pei, Jintao Wang, Hui Wu, Ping Chen. Synthesis, Characterization, and Crystal Structure of Lithium Pyrrolide [J]. Acta Phys. -Chim. Sin., 2021, 37(11): 2009039-.
[5]	Mengxue Zhou, Ning Ren, Jianjun Zhang. Crystal Structure, Thermal Decomposition Mechanism and Properties of Lanthanide Supramolecular Complexes Based on 2, 4, 6-Trimethylbenzoic Acid and 5, 5'-Dimethyl-2, 2'-bipyridine [J]. Acta Phys. -Chim. Sin., 2021, 37(10): 2004071-.
[6]	Ning Ren,Fang Wang,Jianjun Zhang,Xinfang Zheng. Progress in Thermal Analysis Kinetics [J]. Acta Physico-Chimica Sinica, 2020, 36(6): 1905062-.
[7]	Jian Li,Cong Lin,Jianhua Lin,Junliang Sun. Application of Combining X-ray Diffraction and Electron Crystallography for Determination of Complex Inorganic Crystal Structure [J]. Acta Physico-Chimica Sinica, 2020, 36(1): 1907052-.
[8]	An XIE,Zhi WANG,Qiaoyu WU,Liping CHENG,Genggeng LUO,Di SUN. [Ag₂₅(SC₆H₄Prⁱ)₁₈(dppp)₆](CF₃SO₃)₇·CH₃CN (HSC₆H₄Prⁱ = 4-t-isopropylthiophenol, and dppp = 1, 3-bis(diphenyphosphino)propane) Cluster Containing a Sandwich-like Skeleton: Structural Characterization and Optical Properties [J]. Acta Phys. -Chim. Sin., 2018, 34(7): 776-780.
[9]	Youkun ZHENG,Hui JIANG,Xuemei WANG. Multiple Strategies for Controlled Synthesis of Atomically Precise Alloy Nanoclusters [J]. Acta Phys. -Chim. Sin., 2018, 34(7): 740-754.
[10]	Xue HAN,Jin YANG,Yingying LIU,Jianfang MA. Syntheses and Luminescent Properties of Coordination Polymers Based on 1, 2, 4-Triazole-Substituted Resorcin[4]arene [J]. Acta Phys. -Chim. Sin., 2018, 34(5): 476-482.
[11]	Shun-Sheng ZHAO,Lan-Lan LI,Xiang-Rong LIU,Zuo-Cheng DING,Zai-Wen YANG. Crystal Structure, Thermal Decomposition and Interaction with CT-DNA of Three 2-Hydroxy-1-naphthaldehyde Acyl Hydrazones [J]. Acta Phys. -Chim. Sin., 2017, 33(2): 356-363.
[12]	Shi CAO,Li-Li ZENG,Jing XIE,Shi-Gang WAN,Dan Li,Hui ZHANG. Supramolecular Helical Chirality of Schiff Base Copper(Ⅱ) Complexes and Their Chiroptical Spectroscopy [J]. Acta Phys. -Chim. Sin., 2017, 33(12): 2480-2490.
[13]	Xiao-Di ZHENG,Yan-Li ZHU,Rui DONG,Qing-Jie JIAO. Effect of Alkyl Imidazole Ionic Liquids C_nmimCl (n=4, 6, 8) on CL-20 Recrystallization [J]. Acta Phys. -Chim. Sin., 2016, 32(8): 1950-1959.
[14]	Heng ZHANG,Hui-Mei YU,Chao-He XU,Ming-Hui ZHANG,Xiu-Hong PAN,Yan-Feng GAO. A Study of Graphene Oxidation Using Thermal Analysis-Mass Spectrometry Combined with Pulse Thermal Analysis [J]. Acta Phys. -Chim. Sin., 2016, 32(7): 1634-1638.
[15]	Jian-Xia HUO,Su-Wei SONG,Cheng-Wei JIN,Ning REN,Li-Na GENG,Jian-Jun ZHANG. Synthesis, Characterization, Thermal Decomposition Mechanism and Properties of the [Eu(4-MOBA)₃(terpy)(H₂O)]₂ Complex [J]. Acta Phys. -Chim. Sin., 2016, 32(4): 901-906.

Crystal Structure and Thermal Analysis of Erbium Complex with Benzene Acetic Acid

PDF

Like

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Metrics

Recommended 0