Acta Phys. -Chim. Sin. ›› 1992, Vol. 8 ›› Issue (05): 642-646.doi: 10.3866/PKU.WHXB19920513

• ARTICLE • Previous Articles     Next Articles

Crystal Structure and Thermal Analysis of Erbium Complex with Benzene Acetic Acid

Wang Zeng-Lin; Hu Ning-Hai; Niu Chun-Ji; Ni Jia-Zuan; Cui Ai-Li   

  1. Changchun Institute of Chemistry, Chinese Academy of Science, Changchun 130022; Changchun Specialized School of Metallurgy and Geology, Changchun 130021
  • Received:1991-04-12 Revised:1992-03-20 Published:1992-10-15
  • Contact: Wang Zeng-Lin

Abstract: The crystal structure of erbium (Ⅲ) complex of benzene acetic acid is reported. The complex crystallizes in the monoclinic space group P_2_1/a with a=0.9008(3) nm, b=1.4242(5) nm, c=1.8437(7) nm; β=98.80(3)°, V=2.337(1) nm~3, Z=4. The mechanism of thermal decomposition of complex has been studied by TG-DTG-DTA. The activation energy for dehydration reaction has been calculated by Freeman-Carroll method. The enthalpy change for dehydration and phase change process has been determined.

Key words: Erbium eomplex, Crystal structure, Thermal analysis