亚相金属离子与两亲配体LB膜相互作用的研究

doi:10.3866/PKU.WHXB19980116

Acta Phys. -Chim. Sin. ›› 1998, Vol. 14 ›› Issue (01): 84-87.doi: 10.3866/PKU.WHXB19980116

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XPS Study of LB Films of Amphiphilic Ligand on Surface of the Subphase Containing Metal Ions

Ouyang Jian-Ming, Tai Zi-Hou, Tang Wen-Xia

Department of Chemistry,Jinan University,Guangzhou 510632|State Key Laboratory of Coordination Chemistry,Nanjing University,Nanjing 210093

Received:1997-03-11 Revised:1997-05-19 Published:1998-01-15
Contact: Ouyang Jian-Ming

Abstract

Abstract:

The complex formation of 2-hexadecylcarbamoyl-8-hydroxyquinoline(HHQ) monolayers at the air/water interface by reaction with metal ions from the subphase was investigated using X-ray photoelectron spectroscopy. The formation of HHQ-metal complexes leads to the appearance of new peaks assigned to the metal ions. The information on stoichimoetry provided by XPS indicated that a metal ion is coordinated by two HHQ molecules for La3+ and Cd2+ ions, but by one HHQ molecule for Mn2+ and Ni2+ ions.

Key words: X-ray photoelectron spectroscopy, Langmuir-Blodgett(LB) Films, Metal ion, Interface, 2-hexadecylcarbamoyl-8-hydroxyquinoline

Ouyang Jian-Ming, Tai Zi-Hou, Tang Wen-Xia. XPS Study of LB Films of Amphiphilic Ligand on Surface of the Subphase Containing Metal Ions[J]. Acta Phys. -Chim. Sin. 1998, 14(01), 84-87. doi: 10.3866/PKU.WHXB19980116

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XPS Study of LB Films of Amphiphilic Ligand on Surface of the Subphase Containing Metal Ions

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