Cu-Cr-O体系复合氧化物的合成、结构非完整性与催化性能

doi:10.3866/PKU.WHXB19980218

Acta Phys. -Chim. Sin. ›› 1998, Vol. 14 ›› Issue (02): 185-187.doi: 10.3866/PKU.WHXB19980218

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Studies on the Synthesis,Structural Imperfection and catalytic Properties of Cu-Cr-O Composite Oxides

Meng Xiao-Ping, Luo Ning, Wang Ying-Xia, Li Neng, Lin Bing-Xiong, Zhao Tong-Fu

Institute of Physical Chemistry,Peking University,Beijing 100871|Beijing Petro-Chemical College,Beijing 102600

Received:1997-05-26 Revised:1997-09-22 Published:1998-02-15
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Abstract

Abstract:

A series of samples in Cu-Cr-O composite oxide system were synthesized by citrate complexation method. The catalytic activities of samples were evaluated using CO oxidation as test reaction, and structural imperfection was determined by XRD analysis. The results indicate that two phases coexisting under the preparative conditions result in structural imperfection of the samples, which leads to enhanced activities of Cu-Cr-O composite oxides. The catalytic activity for CO oxidation reaction increases with Cu3+ contents in the samples.

Key words: Spinel, Delafossite, CO catalytic oxidation, Structural imperfection

Meng Xiao-Ping, Luo Ning, Wang Ying-Xia, Li Neng, Lin Bing-Xiong, Zhao Tong-Fu. Studies on the Synthesis,Structural Imperfection and catalytic Properties of Cu-Cr-O Composite Oxides[J]. Acta Phys. -Chim. Sin. 1998, 14(02), 185-187. doi: 10.3866/PKU.WHXB19980218

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Studies on the Synthesis,Structural Imperfection and catalytic Properties of Cu-Cr-O Composite Oxides

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