金属有机骨架材料MIL-53（Al）负载钴催化剂的CO催化氧化反应性能

doi:10.3866/PKU.WHXB201401221

Abstract

Abstract:

Ametal-organic framework (MOF) material MIL-53(Al) (MIL: Materials of Institut Lavoisier) with high thermal stability was prepared by the solvothermal method, and it served as a support material for a cobalt catalyst in the CO oxidation reaction. A comparison between the catalytic performance of the MIL-53(Al) and the Al₂O₃ support material was carried out to understand the catalytic behavior of the catalysts. The catalysts were characterized by thermogravimetric-differential scanning calorimeter (TG-DSC), Fourier-transform infrared (FTIR) spectroscopy, N₂ adsorption-desorption, X-ray diffraction (XRD), transmission electron microscopy (TEM), and hydrogen temperature-programmed reduction (H₂-TPR). The TG and N₂ adsorption-desorption analyses showed that MIL-53(Al) had good stability and high surface area. XRD and TEM results indicated that the size of the Co₃O₄ nanoparticles (5.03 nm) supported on MIL-53(Al) was smaller than that (7.83 nm) on the Al₂O₃ support. The highly dispersed Co₃O₄ nanoparticles from the three-dimensional porous structure of MIL-53(Al) led to superior catalytic activity during CO oxidation. The H₂-TPR spectra showed that the reduction in temperature of the Co/MIL-53(Al) catalyst was significantly lower than that of the Co/Al₂O₃ catalyst, implying a higher catalytic activity for the Co/MIL-53(Al) catalyst. Indeed, the heterogeneous catalytic composite material Co/MIL-53(Al) catalyst exhibited much higher activity than the Co/Al₂O₃ catalyst in the CO oxidation test with 98% conversion at 160 ℃ and 100% conversion at 180 ℃. The catalytic activity and structure of the Co/MIL-53(Al) catalyst were stable during the reaction.

Key words: Metal-organic framework, Solvothermal synthesis, MIL-53(Al), Cobalt catalyst, CO catalytic oxidation

TAN Hai-Yan, WU Jin-Ping. Performance of a Metal-Organic Framework MIL-53(Al)-Supported Cobalt Catalyst in the CO Catalytic Oxidation Reaction[J]. Acta Phys. -Chim. Sin. 2014, 30(4), 715-722. doi: 10.3866/PKU.WHXB201401221

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Performance of a Metal-Organic Framework MIL-53(Al)-Supported Cobalt Catalyst in the CO Catalytic Oxidation Reaction

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