大肠杆菌为模板制备Au@TiO2催化剂及其CO氧化反应活性

doi:10.3866/PKU.WHXB20100909

Abstract

Abstract:

Many microorganisms can adsorb metal ions strongly and even reduce them to their metal states. We studied the adsorption of gold nanoparticles on Escherichia coil (DH5α) to form Au@DH5α. Titanium tetrabutoxide was added to Au@DH5αto prepare Au@DH5α-Ti(OH)₄ by hydrolysis. The DH5αtemplate was removed by calcination in air to obtain the Au@TiO₂ catalyst. These materials were characterized by N₂ adsorption, X-ray diffraction (XRD), UV-Vis diffuse reflectance spectroscopy (UV-Vis DRS), thermogravimetry-differential thermal analysis (TG-DTA), and transmission electron microscopy (TEM). The results show that the gold catalyst maintains a rod-like structure similar to DH5αand the porous structure of the titanium oxide prepared using DH5αas a biological template can prevent the aggregation of gold nanoparticles to some extent. With higher amounts of DH5αdosage, smaller gold nanoparticles were obtained and the surface plasmon absorption of gold nanoparticles shifted toward shorter wavelengths. The obtained gold catalyst has a larger surface area than the catalyst prepared by the impregnation method. However, this increases the coke content of the catalyst. Catalytic activity was evaluated by the CO oxidation reaction. We found that with a DH5αdosage of 100 or 150 mL, the obtained gold catalyst can convert CO to CO₂ completely at 80 ℃.

Key words: Titaniumoxide, Escherichia coil, Template agent, Gold catalyst, CO oxidation

LIU Yu-Liang, YOU Cui-Rong, LI Yang, HE Tao, ZHANG Xiang-Qin, SUO Zhang-Huai. Preparation of Au@TiO₂ Catalyst Using Escherichia Coil as the Template and Its Oxidation Reaction Activity toward CO[J]. Acta Phys. -Chim. Sin. 2010, 26(09), 2455-2460. doi: 10.3866/PKU.WHXB20100909

References

1. Hutchings, G. J. J. Catal., 1985, 96(1): 292
2. Haruta, M.; Kobayashi, T.; Sano, H.; Yamada, N. Chem. Lett.,1987, 16: 405
3. Bond, G. C.; Thompson, D. T. Gold Bull., 2000, 33(2): 41
4. Corti, C. W.; Holliday, R. J.; Thompson, D. T. Top. Catal., 2007,44(1-2): 331
5. Corti, C. W.; Holliday, R. J.; Thompson, D. T. Appl. Catal. A,2005, 291(1-2): 253
6. Baron, R.; Willner, B.; Willner, I. Chem. Commun., 2007, (4): 323
7. Horovitz, O.; Tomoaia, G.; Mocanu, A.; Yupsanis, T.; Tomoaia-Cotisel, M. Gold Bull., 2007, 40(3): 213
8. Yang, F.; Guo, Z. J.; Bai, Y.; Huang, Z.; Zheng,W. J.Photographic Sci. Photochem., 2006, 24(2): 118 [杨芳,郭振江,白燕,黄峙,郑文杰.感光科学与光化学, 2006, 24(2):118]
9. Jin, M. S.; Yuan, H. Q.; Jing, J. R.; Suo, Z. H.; Sun, L. Chem. J.Chin. Univ., 2009, 30(6): 1183 [金明善,原慧卿,荆济荣, 索掌怀, 孙力.高等学校化学学报, 2009, 30(6): 1183]
10. Huang, H. Z.; Yuan, Q.; Yang, X. R. J. Colloid Interface Sci.,2005, 282(1): 26
11. Liu, K. Z.; Shi, L. L.; Jin, M. S.; Suo, Z. H. J. Mol. Catal. (China),2009, 23(5): 436 [刘克增, 石玲玲,金明善,索掌怀.分子催化,2009, 23(5): 436]
12. Gericke, M.; Pinches, A. Gold Bull., 2006, 39(1): 22
13. Chen, X. C.; Hu, S. P.; Shen, C. F.; Dou, C. M.; Shi, J. Y.; Chen, Y.X. Bioresour. Technol., 2009, 100(1): 330
14. Agnihotri, M.; Joshi, S.; Kumar, A. R.; Zinjarde, S.; Kulkarni, S.Mater. Lett., 2009, 63(15): 1231
15. Sugunan, A.; Melin, P.; Schnurer, J.; Hilborn, J. G.; Joydeep, D.Adv. Mater., 2007, 19(1): 77
16. Liu, Y. Y.; Fu, J. K.; Hu, R. Z.; Yao, B. X.; Weng, S. Z. ActaMicrobiol. Sin., 1999, 39(3): 260 [刘月英, 傅锦坤,胡荣宗,姚炳新,翁绳周.微生物学报, 1999, 39(3): 260]
17. Kuo, W. S.; Wu, C. M.; Yang, Z. S.; Chen, S. Y.; Chen, C. Y.;Huang, C. C.; Li, W. M.; Sun, C. K.; Yeh, C. S. Chem. Commun.,2008, (37): 4430
18. Fu, J. K.; Liu, Y. Y.; Hu, R. Z.; Zegn, J. L.; Xu, P. P.; Lin, Z. Y.;Yao, B. X.;Weng, S. Z. Acta Phys. -Chim. Sin., 1998, 14(9): 769[傅锦坤,刘月英, 胡荣宗, 曾金龙,许翩翩,林种玉, 姚炳新,翁绳周. 物理化学学报, 1998, 14(9): 769]
19. Kumara, M. T.; Tripp, B. C.; Muralidharan, S. Chem. Mater.,2007, 19(8): 2056
20. Kumara, M. T.; Muralidharan, S.; Tripp, B. C. J. Nanosci.Nanotechnol., 2007, 7(7): 2260
21. Nomura, T.; Morimoto, Y.; Tokumoto, H.; Konishi, Y. Mater.Lett., 2008, 62(21-22): 3727
22. Nomura, T.; Morimoto, Y.; Ishikawa, M.; Tokumoto, H.; Konishi,Y. Adv. Powder Technol., 2010, 21(1): 8
23. Suo, Z. H.; Weng, Y. G.; Jin, M. S.; L俟, A. H.; Xu, J. G.; An, L. D.Chin. J. Catal., 2005, 26(11): 1022 [索掌怀,翁永根,金明善,吕爱花,徐金光, 安立敦.催化学报, 2005, 26(11): 1022]
24. Zanella, R.; Giorgio, S.; Shin, C. H.; Henry, C. R.; Louis, C.J. Catal., 2004, 222(2): 357
25. Link, S.; El-Sayed, M. A. J. Phys. Chem. B, 1999, 103(21): 4212
26. Moreau, F.; Bond, G. C.; Taylor, A. O. J. Catal., 2005, 231(1):105
27. Delannoy, L.; El Hassan, N.; Musi, A.; Le To, N. N.; Krafft, J. M.;Louis, C. J. Phys. Chem. B, 2006, 110(45): 22471
28. Bore, M. T.; Mokhonoana, M. P.; Ward, T. L.; Coville, N. J.;Datye, A. K. Microporous Mesoporous Mat., 2006, 95(1-3): 118

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Preparation of Au@TiO₂ Catalyst Using Escherichia Coil as the Template and Its Oxidation Reaction Activity toward CO

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Preparation of Au@TiO2 Catalyst Using Escherichia Coil as the Template and Its Oxidation Reaction Activity toward CO

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Preparation of Au@TiO₂ Catalyst Using Escherichia Coil as the Template and Its Oxidation Reaction Activity toward CO