均相催化CO2/H2还原羰基化合成高值化学品研究进展

doi:10.3866/PKU.WHXB202007052

Abstract

Abstract:

The efficient utilization of the greenhouse gas CO₂ as a C1 feedstock can effectively reduce its emission and create economic value. Hence, the efficient chemical conversion of CO₂ has been receiving intense attention. Due to the extremely low energy level of the CO₂ molecule, the high energy barrier is the primary challenge for the chemical conversion of CO₂. The chemical conversion of CO₂ is mainly carried out through non-reductive transformation in industrial. Yet, the new route of chemical synthesis based on CO₂ reductive transformation is an interesting topic to expand its resource utilization. In this context, homogeneous reductive carbonylation is a hot topic for the utilization of CO₂ via reductive transformation. In this process, the metal hydride intermediate derived from the activation of the hydrogen source is crucial to the CO₂ reduction. Hydrogen, a clean source with high atom economy, can be used as a reducing agent for the reductive conversion of inert CO₂ through carbonylation, to construct C―O, C―N, and C―C bonds and to synthesize aldehyde/alcohol, carboxylic acid, ester, amide, and other chemicals. These expand the scope of CO₂ high-value utilization and show great potential application in terms of resource utilization and environmental protection. This CO₂ utilization process is thought to involve cascading catalytic reactions of CO₂ reduction and carbonylation. The catalytic systems require the corresponding catalysts to efficiently promote each step and effectively inhibit undesired side reactions. Recently, considerable progress has been made in the homogeneous reductive carbonylation of CO₂ with H₂. However, this kind of reaction is mostly of the cascade type, and hence, requires harsh conditions and noble metal catalysts. The chemoselectivity is low because of the multiple competing reactions. In addition, due to the steric hindrance and electronic effects of the substrate, there are limitations on the types of substrates that can be employed. With the development of new characterization techniques and theoretical calculations, some progress has been made in revealing the reaction mechanism and in the activation of the carbon-oxygen bonds of CO₂. Therefore, there is an urgent need to develop a more efficient catalytic system that requires mild conditions for reductive carbonylation. In this review, we provide an overview of the groundbreaking studies and the recent breakthroughs that have demonstrated the potential of metal catalysts to utilize the combination of CO₂ and H₂ as a C1 synthon, including olefin carbonylation, amine carbonylation, and alcohol/ether carbonylation, while highlighting the effect of different types of metal catalysts on the reaction. We conclude with a perspective on the future prospects of the homogeneous reductive carbonylation of CO₂ with H₂, providing readers a snapshot of this rapidly evolving field.

Key words: Carbon dioxide, Hydrogen, Reduction, Homogeneous catalysis, Carbonylation

Xuehua Zhang, Yanwei Cao, Qiongyao Chen, Chaoren Shen, Lin He. Recent Progress in Homogeneous Reductive Carbonylation of Carbon Dioxide with Hydrogen[J]. Acta Phys. -Chim. Sin. 2021, 37(5), 2007052. doi: 10.3866/PKU.WHXB202007052

Figures/Tables 29

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References 102

1	Dowell N. M. ; Fennell P. S. ; Shah N. ; Maitland G. C. Nat. Clim. Change 2017, 7, 243. doi: 10.1038/nclimate3231
2	Xu Y. Y. ; Ramanathan V. ; Victor D. G. Nature 2018, 564, 30. doi: 10.1038/d41586-018-07586-5
3	Thomas J. M. ; Harris K. D. M. Energy Environ. Sci. 2016, 9, 687. doi: 10.1039/c5ee03461b
4	Artz J. ; Müller T. E. ; Thenert K. ; Kleinekorte J. ; Raoul M. ; Sternberg A. ; Bardow A. ; Leitner W. Chem. Rev. 2018, 118, 434. doi: 10.1021/acs.chemrev.7b00435
5	Zhou Y. ; Han N. ; Li Y. Acta Phys. -Chim. Sin. 2020, 36, 2001041.
	周远; 韩娜; 李彦光. 物理化学学报, 2020, 36, 2001041. doi: 10.3866/PKU.WHXB202001041
6	North M. ; Pasquale R. ; Young C. Green Chem. 2010, 12, 1514. doi: 10.1039/C0GC00065E
7	Lindsey A. S. ; Jeskey H. Chem. Rev. 1957, 57, 583. doi: 10.1021/cr50016a001
8	Otto A. ; Grube T. ; Schiebahn S. ; Stolten D. Energy Environ. Sci. 2015, 8, 3283. doi: 10.1039/C5EE02591E
9	Aresta M. ; Dibenedetto A. ; Angelini A. Chem. Rev. 2013, 114, 1709. doi: 10.1021/cr4002758
10	Martin C. ; Fiorani G. ; Kleij A. W. ACS Catal. 2015, 5, 1353. doi: 10.1021/cs5018997
11	Li Y. ; Wang Z. ; Liu Q. Chin. J. Org. Chem. 2017, 37, 1978. doi: 10.6023/cjoc201702038
12	Liu Q. ; Wu L. ; Jackstell R. ; Beller M. Nat. Commun. 2015, 6, 5933. doi: 10.1038/ncomms6933
13	Klankermayer J. ; Wesselbaum S. ; Beydoun K. ; Leitner W. Angew. Chem. Int. Ed. 2016, 55, 7296. doi: 10.1002/ange.201507458
14	Aresta M. ; Dibenedetto A. ; Angelini A. Chem. Rev. 2014, 114, 1709. doi: 10.1021/cr4002758
15	Wang L. ; Sun W. ; Liu C. Chin. J. Chem. 2018, 36, 353. doi: 10.1002/cjoc.201700746
16	Sakakura T. ; Choi J. ; Yasuda H. Chem. Rev. 2007, 107, 2365. doi: 10.1021/cr068357u
17	Wu L. ; Liu Q. ; Jackstell R. ; Beller M. Angew. Chem. Int. Ed. 2014, 53, 6310. doi: 10.1002/anie.201400793
18	Dabral S. ; Schaub T. Adv. Synth. Catal. 2019, 361, 223. doi: 10.1002/adsc.201801215
19	Liu X. ; Li X. ; He L. Eur. J. Org. Chem. 2019, 14, 2437. doi: 10.1002/ejoc.201801833
20	Dong K. ; Razzaq R. ; Hu Y. ; Ding K. Top. Curr. Chem. 2017, 375, 23. doi: 10.1007/s41061-017-0107-x
21	Zhou W. ; Guo J. ; Shen S ; Pan J. ; Tang J. ; Chen L. ; Au C. ; Yin S. Acta Phys. -Chim. Sin. 2020, 36, 1906048.
	周威; 郭君康; 申升; 潘金波; 唐杰; 陈浪; 区泽堂; 尹双凤. 物理化学学报, 2020, 36, 1906048. doi: 10.3866/PKU.WHXB201906048
22	Franke R. ; Selent D. ; Börner A. Chem. Rev. 2012, 112, 5675. doi: 10.1021/cr3001803
23	Vilches-Herrera M. ; Domke L. ; Börner A. ACS Catal. 2014, 4, 1706. doi: 10.1021/cs500273d
24	Pospech J. ; Fleischer I. ; Frank R. ; Buchholz S. ; Beller M. Angew. Chem. Int. Ed. 2013, 52, 2852. doi: 10.1002/anie.201208330
25	Cornils B. ; Herrmann W. A. ; Rasch M. Angew. Chem. Int. Ed. 1994, 33, 2144. doi: 10.1002/anie.199423481
26	Yang J. ; Liu J. W. ; Helfried H. ; Franke R. ; Jackstell R. ; Beller M. Science 2019, 366, 1514. doi: 10.1126/science.aaz1293
27	Hood D. ; Johnson R. ; Carpenter A. ; Younker J. ; Vinyard D. ; Stanley G. Science 2020, 367, 542. doi: 10.1126/science.aaw7742
28	Wang W. ; Wang S. ; Ma X. ; Gong. J. Chem. Soc. Rev. 2011, 40, 3703. doi: 10.1039/C1CS15008A
29	Laine R. M. ; Rinker R. G. ; Ford P. C. J. Am. Chem. Soc. 1977, 99, 252. doi: 10.1021/ja00443a049
30	Tominaga K. ; Sasaki Y. ; Kawai M. ; Watanabe T. ; Saito M. J. Chem. Soc., Chem. Commun. 1993, 629. doi: 10.1039/C39930000629
31	Tominaga K. ; Sasaki Y. ; Saito M. ; Hagihara K. ; Watanabe T. J. Mol. Catal. 1994, 89, 51. doi: 10.1016/0304-5102(93)E0287-Q
32	Koinuma H. ; Yoshida Y. ; Hirai H. Chem. Lett. 1975, 4, 1223. doi: 10.1246/cl.1975.1223
33	Cheng C. ; Hendriksen D. E. ; Eisenberg R. J. Am. Chem. Soc. 1977, 99, 2791. doi: 10.1021/ja00450a062
34	Tominaga K. ; Sasaki Y. ; Watanabe T. ; Saito M. J. Chem. Soc., Chem. Commun. 1995, 1489. doi: 10.1039/C39950001489
35	Tsuchiya K. ; Huang J. D. ; Tominaga K. ACS Catal. 2013, 3, 2865. doi: 10.1021/cs400809k
36	Yasuda T. ; Uchiage E. ; Fujitani T. ; Tominaga. K. ; Nishida M. Appl. Catal. B: Environ. 2018, 232, 299. doi: 10.1016/j.apcatb.2018.03.057
37	Tominaga K. ; Sasaki Y. Catal. Commun. 2000, 1, 1. doi: 10.1016/S1566-7367(00)00006-6
38	Tominaga K. ; Sasaki Y. J. Mol. Catal. A: Chem. 2004, 220, 159. doi: 10.1016/j.molcata.2004.06.009
39	Tominaga K. Catal. Today 2006, 115, 70. doi: 10.1016/j.cattod.2006.02.019
40	Jääskeläinen S. ; Haukka M. Appl. Catal. A: Gen. 2003, 247, 9. doi: 10.1016/S0926-860X(03)00063-2
41	Kontkanen M. ; Oresmaa L. ; Moreno M. A. ; Jänis J. ; Laurila E. ; Haukka M. Appl. Catal. A: Gen. 2009, 365, 130. doi: 10.1016/j.apcata.2009.06.006
42	Liu Q. ; Wu L. ; Fleischer I. ; Selent D. ; Franke R. ; Beller M. Chem. Eur. J. 2014, 20, 6888. doi: 10.1002/chem.201400358
43	Ali M. ; Gual A. ; Ebeling G. ; Dupont J. ChemCatChem 2014, 6, 2224. doi: 10.1002/cctc.201402226
44	Ren X. ; Zheng Z. ; Zhang L. ; Wang Z. ; Xia C. ; Ding K. Angew. Chem. Int. Ed. 2017, 56, 310. doi: 10.1002/ange.201608628
45	Zhang X. ; Tian X. ; Shen C. ; Xia C. ; He L. ChemCatChem 2019, 11, 1986. doi: 10.1002/cctc.201802091
46	Srivastava V. K. ; Eilbracht P. Catal. Commun. 2009, 10, 1791. doi: 10.1016/j.catcom.2009.05.019
47	Ali M. ; Gual A. ; Ebeling G. ; Dupont J. ChemSusChem 2016, 9, 2129. doi: 10.1002/cssc.201600385
48	Uhe D. A. ; Hölscher M. ; Leitner W. Chem. Eur. J. 2012, 18, 170. doi: 10.1002/chem.201102785
49	Ostapowicz T. G. ; Schmitz M. ; Krystof M. ; Klankermayer J. ; Leitner W. Angew. Chem. Int. Ed. 2013, 52, 12119. doi: 10.1002/anie.201304529
50	Simonato J. P. J Mol. Catal. A: Chem. 2003, 197, 61. doi: 10.1016/S1381-1169(02)00676-3
51	Wu L. ; Liu Q. ; Fleischer I. ; Jackstell R. ; Beller M. Nat. Commun. 2014, 5, 3091. doi: 10.1038/ncomms4091
52	Zhang X. ; Shen C. ; Xia C. ; Tian X. ; He L. Green Chem. 2018, 20, 5533. doi: 10.1039/c8gc02289e
53	Haynes P. ; Slaugh L. H. ; Kohnle J. F. Tetrahedron Lett. 1970, 11, 365. doi: 10.1016/0040-4039(70)80086-7
54	Kiyoshi K. ; Heng P. ; Nobuyuki S. ; Yoshimasa T. Chem. Lett. 1977, 6, 1495. doi: 10.1246/cl.1977.1495
55	Schreiner S. ; Yu J. Y. ; Vaska L. Inorg. Chim. Acta 1988, 147, 139. doi: 10.1016/S0020-1693(00)83362-9
56	Schreiner S. ; Yu J. Y. ; Vaska L. J. Chem. Soc. Chem. Commun. 1988, 602 doi: 10.1039/C39880000602
57	Jessop P. G. ; Hsiao Y. ; Ikariya T. ; Noyori R. J. Am. Chem. Soc. 1994, 116, 8851. doi: 10.1021/ja00098a072
58	Johanssona T. ; Stawinski J. Chem. Commum. 2001, 24, 2654. doi: 10.1039/B108857M
59	Kröcher O. ; Köppel R. A. ; Baiker A. Chem. Commun. 1997, 453 doi: 10.1039/A608150I
60	Federsel C. ; Boddien A. ; Jackstell R. ; Jennerjahn R. ; Dyson P. J. ; Scopelliti R. ; Laurenczy G. ; Beller M. Angew. Chem. Int. Ed. 2010, 49, 9777. doi: 10.1002/anie.201004263
61	Ziebart C. ; Federsel C. ; Anbarasan P. ; Jackstell R. ; Baumann W. ; Spannenberg A. ; Beller M. J. Am. Chem. Soc. 2012, 134, 20701. doi: 10.1021/ja307924a
62	Federsel C. ; Ziebart C. ; Jackstell R. ; Baumann W. ; Beller M. Chem. Eur. J. 2012, 18, 72. doi: 10.1002/chem.201101343
63	Zhang L. ; Han Z. ; Zhao X. ; Wang Z. ; Ding K. Angew. Chem. Int. Ed. 2015, 54, 6186. doi: 10.1002/anie.201500939
64	Munshi P. ; Heldebrant D. ; McKoon E. ; Kelly P. ; Tai C. ; Jessop P. Tetrahedron Lett. 2003, 44, 2725. doi: 10.1016/S0040-4039(03)00384-8
65	Daw P. ; Chakraborty S. ; Leitus G. ; Diskin-Posner Y. ; Ben-David Y. ; Milstein D. ACS Catal. 2017, 7, 2500. doi: 10.1021/acscatal.7b00116
66	Liu H. ; Mei Q. ; Xu Q. ; Song J. ; Liu H. ; Han B. Green Chem. 2017, 19, 196. doi: 10.1039/C6GC02243J
67	Ke Z. ; Yang Z. ; Liu Z. ; Yu B. ; Zhao Y. ; Guo S. ; Wu Y. ; Liu Z. Org. Lett. 2018, 20, 6622. doi: 10.1021/acs.orglett.8b02384
68	Dubey A. ; Nencini L. ; Fayzullin R. R. ; Nervi C. ; Khusnutdinova J. R. ACS Catal. 2017, 7, 3864. doi: 10.1021/acscatal.7b00943
69	Jayarathne U. ; Hazari N. ; Bernskoetter W. H. ACS Catal. 2018, 8, 1338. doi: 10.1021/acscatal.7b03834
70	Schönherr H. ; Cernak T. Angew. Chem. Int. Ed. 2013, 52, 12256. doi: 10.1002/anie.201303207
71	Clarke H. T. ; Gillespie H. B. ; Weisshaus S. Z. J. Am. Chem. Soc. 1933, 55, 4571. doi: 10.1021/ja01338a041
72	Gredig S. V. ; Koeppel R. A. ; Baiker A. J. Chem. Soc. Chem. Commun. 1995, 73 doi: 10.1039/C39950000073
73	Li Y. ; Cui X. ; Dong K. ; Junge K. ; Beller M. ACS Catal. 2017, 7, 1077. doi: 10.1021/acscatal.6b02715
74	Beydoun K. ; Stein T. ; Klankermayer J. ; Leitner W. Angew. Chem. Int. Ed. 2013, 52, 9554. doi: 10.1002/anie.201304656
75	Bianchini C. ; Meli A. ; Peruzzini M. ; Vizza F. ; Zanobini F. Coord. Chem. Rev. 1992, 120, 193. doi: 10.1016/0010-8545(92)80051-R
76	Li Y. ; Sorribes I. ; Yan T. ; Junge K. ; Beller M. Angew. Chem. Int. Ed. 2013, 52, 12156. doi: 10.1002/anie.201306850
77	Beydoun K. ; Thenert K. ; Streng E. S. ; Brosinski S. ; Leitner W. ; Klankermayer J. ChemCatChem 2016, 8, 135. doi: 10.1002/cctc.201501116
78	Yu Bo. ; Zhang H. ; Zhao Y. ; Chen S. ; Xu J. ; Huang C. ; Liu Z. Green Chem. 2013, 15, 95. doi: 10.1039/C2GC36517K
79	Ke Z. ; Yu B. ; Wang H. ; Xiang J. ; Han J. ; Wu Y. ; Liu Z. ; Yang P. ; Liu Z. Green Chem. 2019, 21, 1695. doi: 10.1039/C9GC00095J
80	Qian Q. ; Cui M. ; Zhang J. ; Xiang J. ; Song J. ; Yang G. ; Han B. Green Chem. 2018, 20, 206. doi: 10.1039/C7GC02807E
81	Wang Y. ; Zhang J. ; Qian Q. ; Bediako B. ; Cui M. ; Yang G. ; Yan J. ; Han B. Green Chem. 2019, 21, 589. doi: 10.1039/c8gc03320j
82	Bediako B. ; Qian Q. ; Zhang J. ; Wang Y. ; Shen X. ; Shi J. ; Cui M. ; Yang G. ; Wang Z. ; Tong S. ; et al Green Chem. 2019, 21, 4152. doi: 10.1039/C9GC01185D
83	Zhang J. ; Qian Q. ; Cui M. ; Chen C. ; Liu S. ; Han B. Green Chem. 2017, 19, 4396. doi: 10.1039/C7GC01887H
84	Qian Q. ; Zhang J. ; Cui M. ; Han B. Nat. Commun. 2016, 7, 11481. doi: 10.1038/ncomms11481
85	Tominaga K. ; Sasaki Y. ; Watanabe T. ; Saito M. Stud. Surf. Sci. Catal. 1998, 114, 49. doi: 10.1016/S0167-2991(98)80804-5
86	Darensbourg D. J. ; Groetsch G. ; Wiegreffe P. ; Rheingold A. L. Inorg. Chem. 1987, 26, 3827. doi: 10.1021/ic00269a043
87	Cui M. ; Qian Q. ; Zhang J. ; Chen C. ; Han B. Green Chem. 2017, 19, 3558. doi: 10.1039/C7GC01391D
88	Wang Y. ; Qian Q. ; Zhang J. ; Bediako B. ; Wang Z. ; Liu H. ; Han B. Nat. Commun. 2019, 10, 5395. doi: 10.1038/s41467-019-13463-0
89	Liu Z. Acta Phys. -Chim. Sin. 2020, 36, 1912045.
	刘志敏. 物理化学学报, 2020, 36, 1912045. doi: 10.3866/PKU.WHXB201912045
90	Gao Y. ; Liu S. ; Zhao Z. ; Tao H. ; Sun Z. Acta Phys. -Chim. Sin. 2018, 34, 858.
	高云楠; 刘世桢; 赵振清; 陶亨聪; 孙振宇. 物理化学学报, 2018, 34, 858. doi: 10.3866/PKU.WHXB201802061
91	Nieskens D. ; Ferrari D. ; Liu Y. ; Kolonko R. Catal. Commum 2011, 14, 111. doi: 10.1016/j.catcom.2011.07.020
92	Li S. ; Guo H. ; Luo C. ; Zhang H. ; Xiong L. ; Chen X. ; Ma L. Catal. Lett. 2013, 143, 345. doi: 10.1007/s10562-013-0977-7
93	Qian Q. ; Cui M. ; He Z. ; Wu C. ; Zhu Q. ; Zhang Z. ; Ma J. ; Yang G. ; Zhang J. ; Han B. Chem. Sci. 2015, 6, 5685. doi: 10.1039/C5SC02000J
94	Cui M. ; Qian Q. ; He Z. ; Zhang Z. ; Ma J. ; Wu T. ; Yang G. ; Han B. Chem. Sci. 2016, 7, 5205. doi: 10.1039/C6SC01314G
95	Veibel S. ; Nielsen J. I. Tetrahedron 1967, 23, 1723. doi: 10.1016/S0040-4020(01)82571-0
96	Thomas C. ; Süss-Fink G. Coord. Chem. Rev. 2003, 243, 125. doi: 10.1016/S0010-8545(03)00051-1
97	Fukuoka A. ; Gotoh N. ; Kobayashi N. ; Hirano M. ; Komiya S. Chem. Lett. 1995, 24, 567. doi: 10.1246/cl.1995.567
98	Maeda C. ; Miyazaki Y. ; Ema T. Catal. Sci. Technol. 2014, 4, 1482. doi: 10.1039/C3CY00993A
99	Li Y. ; Yan T. ; Junge K. ; Beller M. Angew. Chem. Int. Ed. 2014, 53, 10476. doi: 10.1002/anie.201405779
100	Shen X. ; Xin Y. ; Liu H. ; Han B. ChemSusChem 2020, (13) doi: 10.1002/cssc.202001025
101	Zhang J. ; Qian Q. ; Wang Y. ; Bediako B. ; Yan J. ; Han B. Chem. Sci. 2019, 10, 10640. doi: 10.1039/c9sc03386f
102	Shen X. ; Meng Q. ; Dong M. ; Xiang J. ; Li S. ; Liu H. ; Han B. ChemSusChem 2019, 12, 514. doi: 10.1002/cssc.201902404

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Recent Progress in Homogeneous Reductive Carbonylation of Carbon Dioxide with Hydrogen

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