钙钛矿材料制备中的溶剂配位效应

doi:10.3866/PKU.WHXB202008055

Abstract

Abstract:

Halide perovskites are ionic semiconductors with outstanding features, such as high defect tolerance, long carrier diffusion length, strong photoluminescence, narrow emission line width, solution processability, and low cost of fabrication. These advantages render them promising candidates for photovoltaics, lasers, displays, and photodetectors. Theoretical and experimental studies have demonstrated that the optical properties of perovskite materials can be strongly affected by their crystal size and dimension. Owing to their ionic nature and low formation energy, perovskites can be synthesized via precipitation. This process typically involves in situ transformation of the precursors with solvent evaporation and/or solvent mixing. It is well known that the physical/chemical properties of solvents play a vital role in determining the size and dimension of the resultant products. Therefore, elucidating the effects of the solvent on perovskite crystallization is crucial for improving the performance of perovskite-based devices. Moreover, the coordination effects between perovskite precursors and solvents are a dominant parameter that influence the crystallization process because the dissolution of perovskite precursors is strongly correlated with the coordination between the perovskite precursors and solvents. Herein, this minireview summarizes recent research advances in comprehending the perovskite precursor-solvent interactions with a focus on the coordination effects. In particular, we have endeavored to discuss the influence of coordination effects on the formation of polycrystalline thin films, quantum dots, and single crystals. It was found that the formation of perovskite-solvent intermediates in coordinated solvents retard the nucleation and growth of perovskite crystals; this proves beneficial for the fabrication of high-quality micrometer-sized perovskite polycrystalline films. Meanwhile, the preformed intermediates contribute to undesired impurities and defects in single crystals and quantum dots. These insights are exceedingly helpful for the crystallization control of perovskites, thus enabling better device performance and enhanced stability. Finally, the minireview discusses the challenges facing perovskite crystallization, along with a short perspective for future studies.

Key words: Perovskite, Coordination effect, Crystallization, Solvation

Zhang Xin, Dengbao Han, Xiaomei Chen, Yu Chen, Shuai Chang, Haizheng Zhong. Effects of Solvent Coordination on Perovskite Crystallization[J]. Acta Phys. -Chim. Sin. 2021, 37(4), 2008055. doi: 10.3866/PKU.WHXB202008055

Figures/Tables 8

Fig 1

Fig 2

Table 1

Fig 3

Fig 4

Fig 5

Fig 6

Fig 7

References 63

1	Stranks S. D. ; Snaith H. J. Nat. Nanotechnol. 2015, 10, 391. doi: 10.1038/nnano.2015.90
2	Saparov B. ; Mitzi D. B. Chem. Rev. 2016, 116, 4558. doi: 10.1021/acs.chemrev.5b00715
3	Ha S. T. ; Su R. ; Xing J. ; Zhang Q. ; Xiong Q. Chem. Sci. 2017, 8, 2522. doi: 10.1039/C6SC04474C
4	Ding L. M. ; Cheng Y. B. ; Tang J. Acta Phys. -Chim. Sin. 2018, 34, 449.
	丁黎明; 程一兵; 唐江. 物理化学学报, 2018, 34, 449. doi: 10.3866/PKU.WHXB201710121
5	Hintermayr V. A. ; Richter A. F. ; Ehrat F. ; Döblinger M. ; Vanderlinden W. ; Sichert J. A. ; Tong Y. ; Polavarapu L. ; Feldmann J. ; Urban A. S. Adv. Mater. 2016, 28, 9478. doi: 10.1002/adma.201602897
6	Zhu Z. Y. ; Yang Q. Q. ; Gao L. F. ; Zhang L. ; Shi A. Y. ; Sun C. L. ; Wang Q. ; Zhang H. L. J. Phys. Chem. Lett. 2017, 8, 1610. doi: 10.1021/acs.jpclett.7b00431
7	Tong Y. ; Bladt E. ; Aygüler M. F. ; Manzi A. ; Milowska K. Z. ; Hintermayr V. A. ; Docampo P. ; Bals S. ; UrbanA. S. ; Polavarapu L. Angew. Chem. Int. Ed. 2016, 55, 13887. doi: 10.1002/anie.201605909
8	Kojima A. ; Ikegami M. ; Teshima K. ; Miyasaka T. Chem. Lett. 2012, 41, 397. doi: 10.1246/cl.2012.397
9	Niu Y. W. ; Zhang F. ; Bai Z. ; Dong Y. ; Yang J. ; Liu R. ; Zou B. ; Li J. ; Zhong H. Z. Adv. Opt. Mater. 2015, 3, 112. doi: 10.1002/adom.201400403
10	Chang S. ; Bai Z. ; Zhong H. Z. Adv. Opt. Mater. 2018, 6, 1800380. doi: 10.1002/adom.201800380
11	Sahli F. ; Werner J. ; Kamino B. A. Nat. Mater. 2018, 17, 820. doi: 10.1038/s41563-018-0115-4
12	Yuan M. ; Quan L. N. ; Comin R. ; Walters G. ; Sabatini R. ; Voznyy O. ; Hoogland S. ; Zhao Y. ; Beauregard E. M. ; Kanjanaboos P. ; et al Nat. Nanotechnol. 2016, 11, 872. doi: 10.1038/nnano.2016.110
13	Xiao J. ; Zhang H. L. Acta Phys. -Chim. Sin. 2016, 32, 1894.
	肖娟; 张浩力. 物理化学学报, 2016, 32, 1894. doi: 10.3866/PKU.WHXB201605034
14	Han D. ; Imran M. ; Zhang M. ; Chang S. ; Wu X. G. ; Zhang X. ; Tang J. L. ; Wang M. ; Ali S. ; Li X. ; et al ACS Nano 2018, 12, 8808. doi: 10.1021/acsnano.8b05172
15	Ji H. ; Xu H. ; Jiang F. ; Bai Z. L. ; Zhong H. Z. International Conference on Display Technology 2019, 50, 411. doi: 10.1002/sdtp.13513
16	Cao Y. ; Wang N. ; Tian H. ; Guo J. ; Wei Y. ; Chen H. ; Miao Y. ; Zou W. ; Pan K. ; He Y ; et al Nature 2018, 562, 249. doi: 10.1038/s41586-018-0576-2
17	Lin K. ; Xing J. ; Quan L. N. ; de Arquer F. P. G. ; Gong X. ; Lu J. ; Xie L. ; Zhao W. ; Zhang D. ; Yan C. ; et al Nature 2018, 562, 245. doi: 10.1038/s41586-018-0575-3
18	Shen Y. ; Cheng L. P. ; Li Y. Q. ; Li W. ; Chen J. D. ; Lee S. T. ; Tang J. X. Adv. Mater. 2019, 31, 1901517. doi: 10.1002/adma.201901517
19	Wang L. ; Dai G. ; Deng L. ; Zhong H. Z. Sci. China Mater. 2020, 63, 1382. doi: 10.1007/s40843-020-1336-6
20	Wei H. ; Fang Y. ; Mulligan P. ; Chuirazzi W. ; Fang H. H. ; Wang C. ; Ecker B. R. ; Gao Y. ; Loi M. A. ; Cao L. ; et al Nat. Photonics 2016, 10, 333. doi: 10.1038/nphoton.2016.41
21	Yakunin S. ; Sytnyk M. ; Kriegner D. ; Shrestha S. ; Richter M. ; Matt G. J. ; Azimi H. ; Brabec C. J. ; Stangl J. ; Kovalenko M. V. Nat. Photonics 2015, 9, 444. doi: 10.1038/nphoton.2015.82
22	Pan W. ; Wu H. ; Luo J. ; Deng Z. ; Ge C. ; Chen C. ; Jiang X. ; Yin W. J. ; Niu G. ; Zhu L. ; et al Nat. Photonics 2017, 11, 726. doi: 10.1038/s41566-017-0012-4
23	Zhu W. ; Ma W. ; Su Y. ; Chen Z. ; Chen X. ; Ma Y. ; Bai L. ; Xiao W. ; Liu T. ; Zhu H. ; et al Light-Sci. Appl. 2020, 9, 112. doi: 10.1038/s41377-020-00353-0
24	Jung M. ; Ji S. G. ; Kim G. ; Seok S. I. Chem. Soc. Rev. 2019, 48, 2011. doi: 10.1039/C8CS00656C
25	Cao X. ; Zhi L. ; Jia Y. ; Li Y. ; Zhao K. ; Cui X. ; Ci L. ; Zhuang D. ; Wei J. ACS Appl. Mater. Interfaces 2019, 11, 7639. doi: 10.1021/acsami.8b16315
26	Li W. ; Wang Z. ; Deschler F. ; Gao S. ; Friend R. H. ; Cheetham A. K. Nat. Rev. Mater. 2017, 2, 16099. doi: 10.1038/natrevmats.2016.99
27	Cho H. ; Kim Y. H. ; Wolf C. ; Lee H. D. ; Lee T. W. Adv. Mater. 2018, 30, 1704587. doi: 10.1002/adma.201704587
28	Sugimoto T. Adv. Colloid Interface Sci. 1987, 28, 65. doi: 10.1016/0001-8686(87)80009-X
29	Zhang F. ; Chen C. ; Kershaw S. V. ; Xiao C. ; Han J. ; Zou B. ; Wu X. ; Chang S. ; Dong Y. ; Rogach A. L. ; et al Chem Nano Mater 2017, 3, 303. doi: 10.1021/acsami.8b05664
30	Saidaminov M. I. ; Abdelhady A. L. ; Maculan G. ; Bakr O. M. Chem. Commun. 2015, 51, 176581. doi: 10.1039/C5CC06916E
31	Dang Y. ; Liu Y. ; Sun Y. ; Yuan D. ; Liu X. ; Lu W. ; Liu G. ; Xia H. ; Tao X. CrystEngComm 2015, 17, 665. doi: 10.1039/C4CE02106A
32	Yan K. ; Long M. ; Zhang T. ; Wei Z. ; Chen H. ; Yang S. ; Xu J. J. Am. Chem. Soc. 2015, 137, 4460. doi: 10.1021/jacs.5b00321
33	Wu Y. ; Islam A. ; Yang X. ; Qin C. ; Liu J. ; Zhang K. ; Peng W. ; Han L. Energy Environ. Sci. 2014, 7, 2934. doi: 10.1039/C4EE01624F
34	Yang W. S. ; Noh J. H. ; Jeon N. J. ; Kim Y. C. ; Ryu S. ; Seo J. ; Seok S. I. Science 2015, 348, 1234. doi: 10.1126/science.aaa9272
35	Lee J. W. ; Kim H. S. ; Park N. G. Acc. Chem. Res. 2016, 49, 311. doi: 10.1021/acs.accounts.5b00440
36	Stamplecoskie K. G. ; Manser J. S. ; Kamat P. V. Energy Environ. Sci. 2015, 8, 208. doi: 10.1039/C4EE02988G
37	Jo Y. ; Oh K. S. ; Kim M. ; Kim K. H. ; Lee H. ; Lee C. W. ; Kim D. S. Adv. Mater. Interfaces 2016, 3, 1500768. doi: 10.1002/admi.201500768
38	Li B. ; Binks D. ; Cao G. ; Tian J. Small 2019, 15, 1903613. doi: 10.1002/smll.201903613
39	Hamill J. C. ; Schwartz J. ; Loo Y. L. ACS Energy Lett. 2018, 3, 92. doi: 10.1021/acsenergylett.7b01057
40	Fang Y. ; Dong Q. ; Shao Y. ; Yuan Y. ; Huang J. Nat. Photonics 2015, 9, 679. doi: 10.1038/nphoton.2015.156
41	Liu Y. ; Yang Z. ; Liu S. Adv. Sci. 2018, 5, 1700471. doi: 10.1002/advs.201700471
42	Ding J. ; Yan Q. F. Sci. China Mater. 2017, 60, 1063. doi: 10.1007/s40843-017-9039-8
43	Shi D. ; Adinolfi V. ; Comin R. ; Yuan M. ; Alarousu E. ; Buin A. ; Chen Y. ; Hoogland S. ; Rothenberger A. ; Katsiev K. Science 2015, 347, 519. doi: 10.1126/science.aaa2725
44	Lu Q. R. ; Li J. ; Lian Z. P. ; Zhao H. Y. ; Dong G. F. ; Li Q. ; Wang L. D. ; Yan Q. F. Acta Phys. -Chim. Sin. 2017, 33, 249.
	吕乾睿; 李晶; 廉志鹏; 赵昊岩; 董桂芳; 李强; 王立铎; 严清峰. 物理化学学报, 2017, 33, 249. doi: 10.3866/PKU.WHXB201610142
45	Chen X. ; Zhang F. ; Ge Y. ; Shi L. ; Huang S. ; Tang J. ; Lv Z. ; Zhang L. ; Zou B. ; Zhong H. Adv. Funct. Mater. 2018, 28, 1706567. doi: 10.1002/adfm.201706567
46	Wang Y. L. ; Chang S. ; Chen X. M. ; Ren Y. D. ; Shi L. F. ; Liu Y. H. ; Zhong H. Z. Chin. J. Chem. 2019, 37, 616. doi: 10.1002/cjoc.201900071
47	Lian Z. ; Yan Q. ; Gao T. ; Ding J. ; Lv Q. ; Ning C. ; Li Q. ; Sun J. L. J. Am. Chem. Soc. 2016, 138, 9409. doi: 10.1021/jacs.6b05683
48	Han Q. ; Bae S. H. ; Sun P. ; Hsieh Y. T. ; Yang Y. ; Rim Y. S. ; Zhao H. ; Chen Q. ; Shi W. ; Li G. Adv. Mater. 2016, 28, 2253. doi: 10.1021/jacs.6b05683
49	Nayak P. K. ; Moore D. T. ; Wenger B. ; Nayak S. ; Haghighirad A. A. ; Fineberg A. ; Noel N. K. ; Reid O. G. ; Rumbles G. ; Kukura P ; et al Nat. Commun. 2016, 7, 13303. doi: 10.1038/ncomms13303
50	Zhang F. ; Zhong H. Z. ; Chen C. ; Wu X. G. ; Hu X. ; Huang H. ; Han J. ; Zou B. ; Dong Y. ACS Nano 2015, 9, 4533. doi: 10.1021/acsnano.5b01154
51	Protesescu L. ; Yakunin S. ; Bodnarchuk M. I. ; Krieg F. ; Caputo R. ; Hendon C. H. ; Yang R. X. ; Walsh A. ; Kovalenko M. V. Nano Lett. 2015, 15, 3692. doi: 10.1021/nl5048779
52	Zhang F. ; Huang S. ; Wang P. ; Chen X. ; Zhao S. ; Dong Y. ; Zhong H. Chem. Mater. 2017, 29, 3793. doi: 10.1021/acs.chemmater.7b01100
53	Liu M. ; Zhao J. ; Luo Z. ; Sun Z. ; Pan N. ; Ding H. ; Wang X. Chem. Mater. 2018, 30, 5846. doi: 10.1021/acs.chemmater.8b00537
54	Li L. ; Chen Y. ; Liu Z. ; Chen Q. ; Wang X. ; Zhou H. Adv. Mater. 2016, 28, 9862. doi: 10.1002/adma.201603021
55	Wharf I. ; Gramstad T. ; Makhija R. ; Onyszchuk M. Can. J. Chem. 1976, 54, 3430. doi: 10.1139/v76-493
56	Miyamae H. ; Numahata Y. ; Nagata M. Chem. Lett. 1980, 9, 663. doi: 10.1246/cl.1980.663
57	Jeon N. J. ; Noh J. H. ; Kim Y. C. ; Yang W. S. ; Ryu S. ; Seok S. I. Nat. Mater. 2014, 13, 897. doi: 10.1038/nmat4014
58	Rong Y. ; Tang Z. ; Zhao Y. ; Zhong X. ; Venkatesan S. ; Graham H. ; Patton M. ; Jing Y. ; Guloy A. M. ; Yao Y. Nanoscale 2015, 7 (24), 10595. doi: 10.1039/C5NR02866C
59	Lee J. W. ; Dai Z. ; Lee C. ; Lee H. M. ; Han T. H. ; De Marco N. ; Lin O. ; Choi C. S. ; Dunn B. ; Koh J. J. Am. Chem. Soc. 2018, 140, 6317. doi: 10.1021/jacs.8b01037
60	Zhang X. ; Han D. ; Wang C. ; Muhammad I. ; Zhang F. ; Shmshad A. ; Xue X. ; Ji W. ; Chang S. ; Zhong H. Adv. Opt. Mater. 2019, 7, 1900774. doi: 10.1002/adom.201900774
61	Chao L. ; Niu T. ; Gu H. ; Yang Y. ; Wei Q. ; Xia Y. ; Hui W. ; Zuo S. ; Zhu Z. ; Pei C. ; et al Research 2020, 2616345. doi: 10.34133/2020/2616345
62	Chao L. ; Xia Y. ; Li B. ; Xing G. ; Chen Y. ; Huang W. Chem 2019, 5, 995. doi: 10.1016/j.chempr.2019.02.025
63	Lin Y. H. ; Sakai N. ; Da P. ; Wu J. ; Sansom H. C. ; Ramadan A. J. ; Mahesh S. ; Liu J. ; Oliver R. D. J. ; Lim J. ; et al Science 2020, 369, 96. doi: 10.1126/science.aba1628

Solvent	PbI₂	MAI	MAPbI₃
Methanol	×	√
Ethanol	×	√
Toluene	×	×	×
N-hexane	×	×	×
Tetrahydrofuran		√
N, N dimethylformamide	√	√	√
acetone		√
Chloroform	×	×	×
Dichloromethane	×	×	×
Isopropanol	×	√
Acetonitrile	×	√	√
√ soluble, × insoluble, partially soluble.

[1]	Binbin Liu, Yang Chen, Tianci Jia, Chen Chen, Zhanghao Wu, Yuhui Liu, Yuhang Zhai, Tianshu Ma, Changlei Wang. Hydroxyl-functionalized molecular engineering mitigates 2D phase barriers for efficient wide-bandgap and all-perovskite tandem solar cells [J]. Acta Phys. -Chim. Sin., 2026, 42(1): 100128-.
[2]	Ying Liang, Yuheng Deng, Shilv Yu, Jiahao Cheng, Jiawei Song, Jun Yao, Yichen Yang, Wanlei Zhang, Wenjing Zhou, Xin Zhang, Wenjian Shen, Guijie Liang, Bin Li, Yong Peng, Run Hu, Wangnan Li. Machine learning-guided antireflection coatings architectures and interface modification for synergistically optimizing efficient and stable perovskite solar cells [J]. Acta Phys. -Chim. Sin., 2025, 41(9): 100098-.
[3]	Qianli Ma, Tianbing Song, Tianle He, Xirong Zhang, Huanming Xiong. Sulfur-doped carbon dots: a novel bifunctional electrolyte additive for high-performance aqueous zinc-ion batteries [J]. Acta Phys. -Chim. Sin., 2025, 41(9): 100106-.
[4]	Mingxuan Qi, Lanyu Jin, Honghe Yao, Zipeng Xu, Teng Cheng, Qi Chen, Cheng Zhu, Yang Bai. Recent progress on electrical failure and stability of perovskite solar cells under reverse bias [J]. Acta Phys. -Chim. Sin., 2025, 41(8): 100088-.
[5]	Jian Li, Yu Zhang, Rongrong Yan, Kaiyuan Sun, Xiaoqing Liu, Zishang Liang, Yinan Jiao, Hui Bu, Xin Chen, Jinjin Zhao, Jianlin Shi. Highly Efficient, Targeted, and Traceable Perovskite Nanocrystals for Photoelectrocatalytic Oncotherapy [J]. Acta Phys. -Chim. Sin., 2025, 41(5): 100042-.
[6]	Yao Ma, Xin Zhao, Hongxu Chen, Wei Wei, Liang Shen. Progress and Perspective of Perovskite Thin Single Crystal Photodetectors [J]. Acta Phys. -Chim. Sin., 2025, 41(4): 100030-.
[7]	Pengyu Dong, Yue Jiang, Zhengchi Yang, Licheng Liu, Gu Li, Xinyang Wen, Zhen Wang, Xinbo Shi, Guofu Zhou, Jun-Ming Liu, Jinwei Gao. NbSe₂ Nanosheets Improved the Buried Interface for Perovskite Solar Cells [J]. Acta Phys. -Chim. Sin., 2025, 41(3): 100029-.
[8]	Rui Yang, Hui Li, Qingfei Meng, Wenjie Li, Jiliang Wu, Yongjin Fang, Chi Huang, Yuliang Cao. Influence of PC-based Electrolyte on High-Rate Performance in Li/CrO_x Primary Battery [J]. Acta Phys. -Chim. Sin., 2024, 40(9): 2308053-.
[9]	Kexin Yan, Zhaoqi Ye, Lingtao Kong, He Li, Xue Yang, Yahong Zhang, Hongbin Zhang, Yi Tang. Seed-Induced Synthesis of Disc-Cluster Zeolite L Mesocrystals with Ultrashort c-Axis: Morphology Control, Decoupled Mechanism, and Enhanced Adsorption [J]. Acta Phys. -Chim. Sin., 2024, 40(9): 2308019-.
[10]	Yameen Ahmed, Xiangxiang Feng, Yuanji Gao, Yang Ding, Caoyu Long, Mustafa Haider, Hengyue Li, Zhuan Li, Shicheng Huang, Makhsud I. Saidaminov, Junliang Yang. Interface Modification by Ionic Liquid for Efficient and Stable FAPbI₃ Perovskite Solar Cells [J]. Acta Phys. -Chim. Sin., 2024, 40(6): 2303057-.
[11]	Weicheng Feng, Jingcheng Yu, Yilan Yang, Yige Guo, Geng Zou, Xiaoju Liu, Zhou Chen, Kun Dong, Yuefeng Song, Guoxiong Wang, Xinhe Bao. Regulating the High Entropy Component of Double Perovskite for High-Temperature Oxygen Evolution Reaction [J]. Acta Phys. -Chim. Sin., 2024, 40(6): 2306013-.
[12]	Rui Li, Huan Liu, Yinan Jiao, Shengjian Qin, Jie Meng, Jiayu Song, Rongrong Yan, Hang Su, Hengbin Chen, Zixuan Shang, Jinjin Zhao. Emerging Irreversible and Reversible Ion Migrations in Perovskites [J]. Acta Phys. -Chim. Sin., 2024, 40(11): 2311011-.
[13]	Muhammad Faizan, Guoqi Zhao, Tianxu Zhang, Xiaoyu Wang, Xin He, Lijun Zhang. Elastic and Thermoelectric Properties of Vacancy Ordered Double Perovskites A₂BX₆: A DFT Study [J]. Acta Phys. -Chim. Sin., 2024, 40(1): 2303004-.
[14]	Rong Hu, Liyun Wei, Jinglin Xian, Guangyu Fang, Zhiao Wu, Miao Fan, Jiayue Guo, Qingxiang Li, Kaisi Liu, Huiyu Jiang, Weilin Xu, Jun Wan, Yonggang Yao. Microwave Shock Process for Rapid Synthesis of 2D Porous La_0.2Sr_0.8CoO₃ Perovskite as an Efficient Oxygen Evolution Reaction Catalyst [J]. Acta Phys. -Chim. Sin., 2023, 39(9): 2212025-0.
[15]	Qiuju Liang, Yinxia Chang, Chaowei Liang, Haolei Zhu, Zibin Guo, Jiangang Liu. Application of Crystallization Kinetics Strategy in Morphology Control of Solar Cells based on Nonfullerene Blends [J]. Acta Phys. -Chim. Sin., 2023, 39(7): 2212006-0.

Effects of Solvent Coordination on Perovskite Crystallization

RichHTML

PDF

Like

Knowledge

Abstract

Cite this article

share this article

Figures/Tables 8

References 63

Related Articles 15

Metrics

Recommended 0