钙钛矿材料制备中的溶剂配位效应

doi:10.3866/PKU.WHXB202008055

Abstract

Abstract:

Halide perovskites are ionic semiconductors with outstanding features, such as high defect tolerance, long carrier diffusion length, strong photoluminescence, narrow emission line width, solution processability, and low cost of fabrication. These advantages render them promising candidates for photovoltaics, lasers, displays, and photodetectors. Theoretical and experimental studies have demonstrated that the optical properties of perovskite materials can be strongly affected by their crystal size and dimension. Owing to their ionic nature and low formation energy, perovskites can be synthesized via precipitation. This process typically involves in situ transformation of the precursors with solvent evaporation and/or solvent mixing. It is well known that the physical/chemical properties of solvents play a vital role in determining the size and dimension of the resultant products. Therefore, elucidating the effects of the solvent on perovskite crystallization is crucial for improving the performance of perovskite-based devices. Moreover, the coordination effects between perovskite precursors and solvents are a dominant parameter that influence the crystallization process because the dissolution of perovskite precursors is strongly correlated with the coordination between the perovskite precursors and solvents. Herein, this minireview summarizes recent research advances in comprehending the perovskite precursor-solvent interactions with a focus on the coordination effects. In particular, we have endeavored to discuss the influence of coordination effects on the formation of polycrystalline thin films, quantum dots, and single crystals. It was found that the formation of perovskite-solvent intermediates in coordinated solvents retard the nucleation and growth of perovskite crystals; this proves beneficial for the fabrication of high-quality micrometer-sized perovskite polycrystalline films. Meanwhile, the preformed intermediates contribute to undesired impurities and defects in single crystals and quantum dots. These insights are exceedingly helpful for the crystallization control of perovskites, thus enabling better device performance and enhanced stability. Finally, the minireview discusses the challenges facing perovskite crystallization, along with a short perspective for future studies.

Key words: Perovskite, Coordination effect, Crystallization, Solvation

Zhang Xin, Dengbao Han, Xiaomei Chen, Yu Chen, Shuai Chang, Haizheng Zhong. Effects of Solvent Coordination on Perovskite Crystallization[J].Acta Phys. -Chim. Sin., 2021, 37(4): 2008055.

Figures/Tables 8

Fig 1

Fig 2

Table 1

Fig 3

Fig 4

Fig 5

Fig 6

Fig 7

References 63

1	Stranks S. D. ; Snaith H. J. Nat. Nanotechnol. 2015, 10, 391. doi: 10.1038/nnano.2015.90
2	Saparov B. ; Mitzi D. B. Chem. Rev. 2016, 116, 4558. doi: 10.1021/acs.chemrev.5b00715
3	Ha S. T. ; Su R. ; Xing J. ; Zhang Q. ; Xiong Q. Chem. Sci. 2017, 8, 2522. doi: 10.1039/C6SC04474C
4	Ding L. M. ; Cheng Y. B. ; Tang J. Acta Phys. -Chim. Sin. 2018, 34, 449.
	丁黎明; 程一兵; 唐江. 物理化学学报, 2018, 34, 449. doi: 10.3866/PKU.WHXB201710121
5	Hintermayr V. A. ; Richter A. F. ; Ehrat F. ; Döblinger M. ; Vanderlinden W. ; Sichert J. A. ; Tong Y. ; Polavarapu L. ; Feldmann J. ; Urban A. S. Adv. Mater. 2016, 28, 9478. doi: 10.1002/adma.201602897
6	Zhu Z. Y. ; Yang Q. Q. ; Gao L. F. ; Zhang L. ; Shi A. Y. ; Sun C. L. ; Wang Q. ; Zhang H. L. J. Phys. Chem. Lett. 2017, 8, 1610. doi: 10.1021/acs.jpclett.7b00431
7	Tong Y. ; Bladt E. ; Aygüler M. F. ; Manzi A. ; Milowska K. Z. ; Hintermayr V. A. ; Docampo P. ; Bals S. ; UrbanA. S. ; Polavarapu L. Angew. Chem. Int. Ed. 2016, 55, 13887. doi: 10.1002/anie.201605909
8	Kojima A. ; Ikegami M. ; Teshima K. ; Miyasaka T. Chem. Lett. 2012, 41, 397. doi: 10.1246/cl.2012.397
9	Niu Y. W. ; Zhang F. ; Bai Z. ; Dong Y. ; Yang J. ; Liu R. ; Zou B. ; Li J. ; Zhong H. Z. Adv. Opt. Mater. 2015, 3, 112. doi: 10.1002/adom.201400403
10	Chang S. ; Bai Z. ; Zhong H. Z. Adv. Opt. Mater. 2018, 6, 1800380. doi: 10.1002/adom.201800380
11	Sahli F. ; Werner J. ; Kamino B. A. Nat. Mater. 2018, 17, 820. doi: 10.1038/s41563-018-0115-4
12	Yuan M. ; Quan L. N. ; Comin R. ; Walters G. ; Sabatini R. ; Voznyy O. ; Hoogland S. ; Zhao Y. ; Beauregard E. M. ; Kanjanaboos P. ; et al Nat. Nanotechnol. 2016, 11, 872. doi: 10.1038/nnano.2016.110
13	Xiao J. ; Zhang H. L. Acta Phys. -Chim. Sin. 2016, 32, 1894.
	肖娟; 张浩力. 物理化学学报, 2016, 32, 1894. doi: 10.3866/PKU.WHXB201605034
14	Han D. ; Imran M. ; Zhang M. ; Chang S. ; Wu X. G. ; Zhang X. ; Tang J. L. ; Wang M. ; Ali S. ; Li X. ; et al ACS Nano 2018, 12, 8808. doi: 10.1021/acsnano.8b05172
15	Ji H. ; Xu H. ; Jiang F. ; Bai Z. L. ; Zhong H. Z. International Conference on Display Technology 2019, 50, 411. doi: 10.1002/sdtp.13513
16	Cao Y. ; Wang N. ; Tian H. ; Guo J. ; Wei Y. ; Chen H. ; Miao Y. ; Zou W. ; Pan K. ; He Y ; et al Nature 2018, 562, 249. doi: 10.1038/s41586-018-0576-2
17	Lin K. ; Xing J. ; Quan L. N. ; de Arquer F. P. G. ; Gong X. ; Lu J. ; Xie L. ; Zhao W. ; Zhang D. ; Yan C. ; et al Nature 2018, 562, 245. doi: 10.1038/s41586-018-0575-3
18	Shen Y. ; Cheng L. P. ; Li Y. Q. ; Li W. ; Chen J. D. ; Lee S. T. ; Tang J. X. Adv. Mater. 2019, 31, 1901517. doi: 10.1002/adma.201901517
19	Wang L. ; Dai G. ; Deng L. ; Zhong H. Z. Sci. China Mater. 2020, 63, 1382. doi: 10.1007/s40843-020-1336-6
20	Wei H. ; Fang Y. ; Mulligan P. ; Chuirazzi W. ; Fang H. H. ; Wang C. ; Ecker B. R. ; Gao Y. ; Loi M. A. ; Cao L. ; et al Nat. Photonics 2016, 10, 333. doi: 10.1038/nphoton.2016.41
21	Yakunin S. ; Sytnyk M. ; Kriegner D. ; Shrestha S. ; Richter M. ; Matt G. J. ; Azimi H. ; Brabec C. J. ; Stangl J. ; Kovalenko M. V. Nat. Photonics 2015, 9, 444. doi: 10.1038/nphoton.2015.82
22	Pan W. ; Wu H. ; Luo J. ; Deng Z. ; Ge C. ; Chen C. ; Jiang X. ; Yin W. J. ; Niu G. ; Zhu L. ; et al Nat. Photonics 2017, 11, 726. doi: 10.1038/s41566-017-0012-4
23	Zhu W. ; Ma W. ; Su Y. ; Chen Z. ; Chen X. ; Ma Y. ; Bai L. ; Xiao W. ; Liu T. ; Zhu H. ; et al Light-Sci. Appl. 2020, 9, 112. doi: 10.1038/s41377-020-00353-0
24	Jung M. ; Ji S. G. ; Kim G. ; Seok S. I. Chem. Soc. Rev. 2019, 48, 2011. doi: 10.1039/C8CS00656C
25	Cao X. ; Zhi L. ; Jia Y. ; Li Y. ; Zhao K. ; Cui X. ; Ci L. ; Zhuang D. ; Wei J. ACS Appl. Mater. Interfaces 2019, 11, 7639. doi: 10.1021/acsami.8b16315
26	Li W. ; Wang Z. ; Deschler F. ; Gao S. ; Friend R. H. ; Cheetham A. K. Nat. Rev. Mater. 2017, 2, 16099. doi: 10.1038/natrevmats.2016.99
27	Cho H. ; Kim Y. H. ; Wolf C. ; Lee H. D. ; Lee T. W. Adv. Mater. 2018, 30, 1704587. doi: 10.1002/adma.201704587
28	Sugimoto T. Adv. Colloid Interface Sci. 1987, 28, 65. doi: 10.1016/0001-8686(87)80009-X
29	Zhang F. ; Chen C. ; Kershaw S. V. ; Xiao C. ; Han J. ; Zou B. ; Wu X. ; Chang S. ; Dong Y. ; Rogach A. L. ; et al Chem Nano Mater 2017, 3, 303. doi: 10.1021/acsami.8b05664
30	Saidaminov M. I. ; Abdelhady A. L. ; Maculan G. ; Bakr O. M. Chem. Commun. 2015, 51, 176581. doi: 10.1039/C5CC06916E
31	Dang Y. ; Liu Y. ; Sun Y. ; Yuan D. ; Liu X. ; Lu W. ; Liu G. ; Xia H. ; Tao X. CrystEngComm 2015, 17, 665. doi: 10.1039/C4CE02106A
32	Yan K. ; Long M. ; Zhang T. ; Wei Z. ; Chen H. ; Yang S. ; Xu J. J. Am. Chem. Soc. 2015, 137, 4460. doi: 10.1021/jacs.5b00321
33	Wu Y. ; Islam A. ; Yang X. ; Qin C. ; Liu J. ; Zhang K. ; Peng W. ; Han L. Energy Environ. Sci. 2014, 7, 2934. doi: 10.1039/C4EE01624F
34	Yang W. S. ; Noh J. H. ; Jeon N. J. ; Kim Y. C. ; Ryu S. ; Seo J. ; Seok S. I. Science 2015, 348, 1234. doi: 10.1126/science.aaa9272
35	Lee J. W. ; Kim H. S. ; Park N. G. Acc. Chem. Res. 2016, 49, 311. doi: 10.1021/acs.accounts.5b00440
36	Stamplecoskie K. G. ; Manser J. S. ; Kamat P. V. Energy Environ. Sci. 2015, 8, 208. doi: 10.1039/C4EE02988G
37	Jo Y. ; Oh K. S. ; Kim M. ; Kim K. H. ; Lee H. ; Lee C. W. ; Kim D. S. Adv. Mater. Interfaces 2016, 3, 1500768. doi: 10.1002/admi.201500768
38	Li B. ; Binks D. ; Cao G. ; Tian J. Small 2019, 15, 1903613. doi: 10.1002/smll.201903613
39	Hamill J. C. ; Schwartz J. ; Loo Y. L. ACS Energy Lett. 2018, 3, 92. doi: 10.1021/acsenergylett.7b01057
40	Fang Y. ; Dong Q. ; Shao Y. ; Yuan Y. ; Huang J. Nat. Photonics 2015, 9, 679. doi: 10.1038/nphoton.2015.156
41	Liu Y. ; Yang Z. ; Liu S. Adv. Sci. 2018, 5, 1700471. doi: 10.1002/advs.201700471
42	Ding J. ; Yan Q. F. Sci. China Mater. 2017, 60, 1063. doi: 10.1007/s40843-017-9039-8
43	Shi D. ; Adinolfi V. ; Comin R. ; Yuan M. ; Alarousu E. ; Buin A. ; Chen Y. ; Hoogland S. ; Rothenberger A. ; Katsiev K. Science 2015, 347, 519. doi: 10.1126/science.aaa2725
44	Lu Q. R. ; Li J. ; Lian Z. P. ; Zhao H. Y. ; Dong G. F. ; Li Q. ; Wang L. D. ; Yan Q. F. Acta Phys. -Chim. Sin. 2017, 33, 249.
	吕乾睿; 李晶; 廉志鹏; 赵昊岩; 董桂芳; 李强; 王立铎; 严清峰. 物理化学学报, 2017, 33, 249. doi: 10.3866/PKU.WHXB201610142
45	Chen X. ; Zhang F. ; Ge Y. ; Shi L. ; Huang S. ; Tang J. ; Lv Z. ; Zhang L. ; Zou B. ; Zhong H. Adv. Funct. Mater. 2018, 28, 1706567. doi: 10.1002/adfm.201706567
46	Wang Y. L. ; Chang S. ; Chen X. M. ; Ren Y. D. ; Shi L. F. ; Liu Y. H. ; Zhong H. Z. Chin. J. Chem. 2019, 37, 616. doi: 10.1002/cjoc.201900071
47	Lian Z. ; Yan Q. ; Gao T. ; Ding J. ; Lv Q. ; Ning C. ; Li Q. ; Sun J. L. J. Am. Chem. Soc. 2016, 138, 9409. doi: 10.1021/jacs.6b05683
48	Han Q. ; Bae S. H. ; Sun P. ; Hsieh Y. T. ; Yang Y. ; Rim Y. S. ; Zhao H. ; Chen Q. ; Shi W. ; Li G. Adv. Mater. 2016, 28, 2253. doi: 10.1021/jacs.6b05683
49	Nayak P. K. ; Moore D. T. ; Wenger B. ; Nayak S. ; Haghighirad A. A. ; Fineberg A. ; Noel N. K. ; Reid O. G. ; Rumbles G. ; Kukura P ; et al Nat. Commun. 2016, 7, 13303. doi: 10.1038/ncomms13303
50	Zhang F. ; Zhong H. Z. ; Chen C. ; Wu X. G. ; Hu X. ; Huang H. ; Han J. ; Zou B. ; Dong Y. ACS Nano 2015, 9, 4533. doi: 10.1021/acsnano.5b01154
51	Protesescu L. ; Yakunin S. ; Bodnarchuk M. I. ; Krieg F. ; Caputo R. ; Hendon C. H. ; Yang R. X. ; Walsh A. ; Kovalenko M. V. Nano Lett. 2015, 15, 3692. doi: 10.1021/nl5048779
52	Zhang F. ; Huang S. ; Wang P. ; Chen X. ; Zhao S. ; Dong Y. ; Zhong H. Chem. Mater. 2017, 29, 3793. doi: 10.1021/acs.chemmater.7b01100
53	Liu M. ; Zhao J. ; Luo Z. ; Sun Z. ; Pan N. ; Ding H. ; Wang X. Chem. Mater. 2018, 30, 5846. doi: 10.1021/acs.chemmater.8b00537
54	Li L. ; Chen Y. ; Liu Z. ; Chen Q. ; Wang X. ; Zhou H. Adv. Mater. 2016, 28, 9862. doi: 10.1002/adma.201603021
55	Wharf I. ; Gramstad T. ; Makhija R. ; Onyszchuk M. Can. J. Chem. 1976, 54, 3430. doi: 10.1139/v76-493
56	Miyamae H. ; Numahata Y. ; Nagata M. Chem. Lett. 1980, 9, 663. doi: 10.1246/cl.1980.663
57	Jeon N. J. ; Noh J. H. ; Kim Y. C. ; Yang W. S. ; Ryu S. ; Seok S. I. Nat. Mater. 2014, 13, 897. doi: 10.1038/nmat4014
58	Rong Y. ; Tang Z. ; Zhao Y. ; Zhong X. ; Venkatesan S. ; Graham H. ; Patton M. ; Jing Y. ; Guloy A. M. ; Yao Y. Nanoscale 2015, 7 (24), 10595. doi: 10.1039/C5NR02866C
59	Lee J. W. ; Dai Z. ; Lee C. ; Lee H. M. ; Han T. H. ; De Marco N. ; Lin O. ; Choi C. S. ; Dunn B. ; Koh J. J. Am. Chem. Soc. 2018, 140, 6317. doi: 10.1021/jacs.8b01037
60	Zhang X. ; Han D. ; Wang C. ; Muhammad I. ; Zhang F. ; Shmshad A. ; Xue X. ; Ji W. ; Chang S. ; Zhong H. Adv. Opt. Mater. 2019, 7, 1900774. doi: 10.1002/adom.201900774
61	Chao L. ; Niu T. ; Gu H. ; Yang Y. ; Wei Q. ; Xia Y. ; Hui W. ; Zuo S. ; Zhu Z. ; Pei C. ; et al Research 2020, 2616345. doi: 10.34133/2020/2616345
62	Chao L. ; Xia Y. ; Li B. ; Xing G. ; Chen Y. ; Huang W. Chem 2019, 5, 995. doi: 10.1016/j.chempr.2019.02.025
63	Lin Y. H. ; Sakai N. ; Da P. ; Wu J. ; Sansom H. C. ; Ramadan A. J. ; Mahesh S. ; Liu J. ; Oliver R. D. J. ; Lim J. ; et al Science 2020, 369, 96. doi: 10.1126/science.aba1628

Solvent	PbI₂	MAI	MAPbI₃
Methanol	×	√
Ethanol	×	√
Toluene	×	×	×
N-hexane	×	×	×
Tetrahydrofuran		√
N, N dimethylformamide	√	√	√
acetone		√
Chloroform	×	×	×
Dichloromethane	×	×	×
Isopropanol	×	√
Acetonitrile	×	√	√
√ soluble, × insoluble, partially soluble.

[1]	Rong Hu, Liyun Wei, Jinglin Xian, Guangyu Fang, Zhiao Wu, Miao Fan, Jiayue Guo, Qingxiang Li, Kaisi Liu, Huiyu Jiang, Weilin Xu, Jun Wan, Yonggang Yao. Microwave Shock Process for Rapid Synthesis of 2D Porous La_0.2Sr_0.8CoO₃ Perovskite as an Efficient Oxygen Evolution Reaction Catalyst [J]. Acta Phys. -Chim. Sin., 2023, 39(9): 2212025-0.
[2]	Qiuju Liang, Yinxia Chang, Chaowei Liang, Haolei Zhu, Zibin Guo, Jiangang Liu. Application of Crystallization Kinetics Strategy in Morphology Control of Solar Cells based on Nonfullerene Blends [J]. Acta Phys. -Chim. Sin., 2023, 39(7): 2212006-0.
[3]	Shuai Yang, Yuxin Xu, Zikun Hao, Shengjian Qin, Runpeng Zhang, Yu Han, Liwei Du, Ziyi Zhu, Anning Du, Xin Chen, Hao Wu, Bingbing Qiao, Jian Li, Yi Wang, Bingchen Sun, Rongrong Yan, Jinjin Zhao. Recent Advances in High-Efficiency Perovskite for Medical Sensors [J]. Acta Phys. -Chim. Sin., 2023, 39(5): 2211025-0.
[4]	Yongtao Wen, Jing Li, Xiaofeng Gao, Congcong Tian, Hao Zhu, Guomu Yu, Xiaoli Zhang, Hyesung Park, Fuzhi Huang. Two-Step Sequential Blade-Coating Large-Area FA-Based Perovskite Thin Film via a Controlled PbI₂ Microstructure [J]. Acta Phys. -Chim. Sin., 2023, 39(2): 2203048-0.
[5]	Yae Qi, Yongyao Xia. Electrolyte Regulation Strategies for Improving the Electrochemical Performance of Aqueous Zinc-Ion Battery Cathodes [J]. Acta Phys. -Chim. Sin., 2023, 39(2): 2205045-0.
[6]	Bihao Zhuang, Zicong Jin, Dehua Tian, Suiyi Zhu, Linqian Zeng, Jiandong Fan, Zaizhu Lou, Wenzhe Li. Halogen Regulation for Enhanced Luminescence in Emerging (4-HBA)SbX₅∙H₂O Perovskite-Like Single Crystals [J]. Acta Phys. -Chim. Sin., 2023, 39(1): 2209007-0.
[7]	Yue Lu, Yang Ge, Manling Sui. Degradation Mechanism of CH₃NH₃PbI₃-based Perovskite Solar Cells under Ultraviolet Illumination [J]. Acta Phys. -Chim. Sin., 2022, 38(5): 2007088-.
[8]	Feiyu Lin, Ying Yang, Congtan Zhu, Tian Chen, Shupeng Ma, Yuan Luo, Liu Zhu, Xueyi Guo. Fabrication of Stable CsPbI₂Br Perovskite Solar Cells in the Humid Air [J]. Acta Phys. -Chim. Sin., 2022, 38(4): 2005007-.
[9]	Wusong Zha, Lianping Zhang, Long Wen, Jiachen Kang, Qun Luo, Qin Chen, Shangfeng Yang, Chang-Qi Ma. Controllable Formation of PbI₂ and PbI₂(DMSO) Nano Domains in Perovskite Films through Precursor Solvent Engineering [J]. Acta Phys. -Chim. Sin., 2022, 38(3): 2003022-.
[10]	Zixu He, Yawei Chen, Fanyang Huang, Yulin Jie, Xinpeng Li, Ruiguo Cao, Shuhong Jiao. Fluorinated Solvents for Lithium Metal Batteries [J]. Acta Phys. -Chim. Sin., 2022, 38(11): 2205005-.
[11]	Yan Li, Xingsheng Hu, Jingwei Huang, Lei Wang, Houde She, Qizhao Wang. Development of Iron-Based Heterogeneous Cocatalysts for Photoelectrochemical Water Oxidation [J]. Acta Phys. -Chim. Sin., 2021, 37(8): 2009022-.
[12]	Zejian Wang, Jiajia Hong, Sue-Faye Ng, Wen Liu, Junjie Huang, Pengfei Chen, Wee-Jun Ong. Recent Progress of Perovskite Oxide in Emerging Photocatalysis Landscape: Water Splitting, CO₂ Reduction, and N₂ Fixation [J]. Acta Phys. -Chim. Sin., 2021, 37(6): 2011033-.
[13]	Jionghua Wu, Yiming Li, Jiangjian Shi, Huijue Wu, Yanhong Luo, Dongmei Li, Qingbo Meng. UV Photodetectors Based on High Quality CsPbCl₃ Film Prepared by a Two-Step Diffusion Method [J]. Acta Phys. -Chim. Sin., 2021, 37(4): 2004041-.
[14]	Peiquan Song, Liqiang Xie, Lina Shen, Kaikai Liu, Yuming Liang, Kebin Lin, Jianxun Lu, Chengbo Tian, Zhanhua Wei. Stable Perovskite Solar Cells Using Compact Tin Oxide Layer Deposited through Electrophoresis [J]. Acta Phys. -Chim. Sin., 2021, 37(4): 2004038-.
[15]	Haomiao Li, Hua Dong, Jingrui Li, Zhaoxin Wu. Recent Advances in Tin-Based Perovskite Solar Cells [J]. Acta Phys. -Chim. Sin., 2021, 37(4): 2007006-.

Effects of Solvent Coordination on Perovskite Crystallization

RichHTML

PDF

Like

Knowledge

Abstract

Cite this article

share this article

Figures/Tables 8

References 63

Related Articles 15

Metrics

Recommended 0