物理化学学报 >> 2008, Vol. 24 >> Issue (07): 1127-1131.doi: 10.1016/S1872-1508(08)60046-7

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以ZrO2-TiO2为载体的整体式锰基催化剂应用于低温NH3-SCR反应

林涛; 张秋林; 李伟; 龚茂初; 幸怡汛; 陈耀强   

  1. 四川大学绿色化学与技术教育部重点实验室, 成都 610064
  • 收稿日期:2008-02-18 修回日期:2008-04-23 发布日期:2008-07-04
  • 通讯作者: 陈耀强 E-mail:nic7501@email.scu.edu.cn

Monolith Manganese-Based Catalyst Supported on ZrO2-TiO2 for NH3-SCR Reaction at Low Temperature

LIN Tao; ZHANG Qiu-Lin; LI Wei; GONG Mao-Chu; XING Yi-Xun; CHEN Yao-Qiang   

  1. Key Laboratory of Green Chemistry &Technology of the Ministry of Education, Sichuan University, Chengdu 610064, P. R. China
  • Received:2008-02-18 Revised:2008-04-23 Published:2008-07-04
  • Contact: CHEN Yao-Qiang E-mail:nic7501@email.scu.edu.cn

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摘要：

以MnO2为活性组分, Fe2O3为助剂, 制备了以TiO2及ZrO2-TiO2为载体的整体式催化剂. 考察了它们在不同温度焙烧后应用于富氧条件下, NH3选择性催化还原(NH3-SCR)氮氧化物的低温反应性能和高温稳定性. 用X射线衍射(XRD)实验、比表面积测定(BET)、储氧性能测定(OSC)及程序升温还原(H2-TPR)等方法对催化剂进行了表征. 结果表明, 以ZrO2-TiO2为载体的催化剂具有很好的高温热稳定性, 并具有较高的比表面积和储氧能力, 同时具有较强的氧化能力. 催化剂的活性测试结果表明, 以ZrO2-TiO2为载体的整体式锰基催化剂明显地提高了NH3-SCR反应的低温活性, 具有良好的应用前景.

关键词: ZrO2-TiO2, 低温NH3-SCR, NO, NH3, 整体式催化剂

Abstract:

Monolith catalysts were prepared using TiO2 and ZrO2-TiO2 as supports with MnO2 as active component and Fe2O3 as promoter. The catalytic activities at low temperature and stability at high temperature for selective catalytic reduction of NOx with NH3 (NH3-SCR) in the presence of excessive O2were studied after the catalysts calcined at different temperatures. The catalystswere characterized by X-ray diffraction (XRD), specific surface area measurements (BET), oxygen storage capacity (OSC), and temperature programmed reduction (H2-TPR). The results indicated that the catalyst supported on ZrO2-TiO2 had excellent stability at high temperature, and possessed high specific surface area and oxygen storage capacity, and had strong redox property. The results of the catalytic activities indicated that the monolith manganese-based catalyst using ZrO2-TiO2 as support had evidently improved the activity of NH3-SCR reaction at low temperature, and it showed great potential for practical application.

Key words: ZrO2-TiO2, Low-temperature NH3-SCR, NO, NH3, Monolith catalyst