范德华S型异质结赋予快速电荷转移助力光催化活性提升

doi:10.1016/j.actphy.2025.100211

摘要/Abstract

摘要：

合理设计高效梯型(S型)异质结已成为当前光催化领域的一项重要突破，在推动环境友好型生态修复与能源转化技术的发展方面具有巨大潜力。然而，传统S型异质结普遍存在晶格失配问题，导致界面内建电场削弱，从而限制了光生载流子的有效分离。为克服这一瓶颈，本研究提出了一种创新的原位沉积策略，在Bi₂O₂S-BiOBr复合体系中成功构建了范德华S型异质结。该策略有效缓解了晶格失配，实现了紧密的界面结合，从而形成强效内建电场，显著促进了载流子的高效迁移与分离。Bi₂O₂S-BiOBr复合材料光吸收范围超过700 nm，并在氙灯照射下对环丙沙星(CIP)展现出优异的光催化降解性能。其中，20%Bi₂O₂S-BiOBr在15 min内即可实现93%的CIP去除率，显著优于所有对比样品。这种显著的性能提升源于范德华S型异质结中光生载流子高效分离与传输效率。本研究为范德华S型异质结的理性设计提供了新的思路与理论支撑。

关键词: S型异质结, 范德华力, 光催化降解, 电荷分离, Bi₂O₂S-BiOBr复合材料

Abstract:

The rational design of efficient step-scheme (S-scheme) heterojunctions is a significant breakthrough in photocatalysis, holding great potential to enhance eco-friendly environmental restoration and energy conversion technologies. However, conventional S-scheme heterojunctions frequently suffer from lattice mismatch issues, which severely compromise the efficacy of built-in electric fields in charge separation. To address this limitation, we developed an innovative in situ deposition strategy to construct van der Waals S-scheme heterojunctions within Bi₂O₂S-BiOBr composites. This approach effectively mitigates lattice mismatch and ensures intimate interfacial contact, enabling the formation of a strong internal electric field that facilitates efficient carrier migration. The Bi₂O₂S-BiOBr composites exhibit an extended light absorption range exceeding 700 nm, allowing for broad-spectrum photocatalytic activity. Under Xenon lamp irradiation, the Bi₂O₂S-BiOBr composites demonstrated outstanding photocatalytic efficiency in the degradation of ciprofloxacin (CIP). Notably, the 20%Bi₂O₂S-BiOBr composite achieved 93% CIP removal within 15 min, outperforming all other tested composites. The notable enhancement in performance stems from the van der Waals S-scheme heterojunction, which facilitates highly efficient separation of photogenerated carriers. This work provides valuable insights for the strategic design of advanced van der Waals heterostructures with S-scheme charge transfer mechanisms.

Key words: S-scheme heterojunction, Van der Waals, Photocatalytic degradation, Charge separation, Bi₂O₂S-BiOBr composite

许凯强, 于佳, 夏伟, 张建军, 韩生. 范德华S型异质结赋予快速电荷转移助力光催化活性提升[J]. 物理化学学报, 2026, 42(7), 100211. doi: 10.1016/j.actphy.2025.100211

Kaiqiang Xu, Jia Yu, Wei Xia, Jianjun Zhang, Sheng Han. Rapid charge transfer endowed by van der Waals S-scheme heterojunction for boosting photocatalytic activity[J]. Acta Phys. -Chim. Sin. 2026, 42(7), 100211. doi: 10.1016/j.actphy.2025.100211

链接本文: https://www.whxb.pku.edu.cn/CN/10.1016/j.actphy.2025.100211

https://www.whxb.pku.edu.cn/CN/Y2026/V42/I7/100211

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Heterojunction photocatalyst	CIP (mg L⁻¹)	Removal rate	Ref.
BiOBr/Bi₂MoO₆	10	94% at 120 min	[70]
MnO₂/BiOBr	20	77.3% at 60 min	[71]
WS₂/BiOBr	20	92% at 100 min	[72]
CN QDs/BiOBr	10	70% at 90 min	[73]
BiOBr/Bi₂WO₆	10	90% at 120 min	[74]
BiOBr/Cu₂S	10	79.2% at 90 min	[55]
Ni-MOF/BiOBr	20	92.8% at 120 min	[75]
Bi₂O₂CO₃/BiOBr	10	96% at 120 min	[76]
PDI/BiOBr	20	85.3% at 90 min	[77]
Bi₂O₂S/BiOBr	20	93% at 15 min	This work

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