物理化学学报 >> 1994, Vol. 10 >> Issue (12): 1062-1065.doi: 10.3866/PKU.WHXB19941202

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Raman-STM联用系统及其初步实验

田中群, 李五湖, 穆纪千, 毛秉伟, 陈捷光, 卓向东, 郑炜, 王铎, 颜恩柔   

  1. 厦门大学固体表面物理华学国家重点实验室化学系，厦门 361005|厦门大学科学仪器系，厦门 361005
  • 收稿日期:1994-08-20 修回日期:1994-10-13 发布日期:1994-12-15
  • 通讯作者: 田中群

A Combined System of Raman-STM and Preliminary Tests

Tian Zhong-Qun, Li Wu-Hu, Mu Ji-Qian, Mao Bing-Wei, Chen Jie-Guang, Zhuo Xiang-Dong, Zheng Wei, Wang Duo, Yan En-Rou   

  1. State Key Laboratory for Physical Chemistry of Solid Surface,Department of Chemistry,Xiamen University,Xiamen 361005|Department of Scientific Instruments,Xiamen University,Xiamen 361005
  • Received:1994-08-20 Revised:1994-10-13 Published:1994-12-15
  • Contact: Tian Zhong-Qun

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关键词: 拉曼光谱, 扫描隧道显微技术, 联用系统, 固/液界面, 电化学

Abstract:

A combined system of Raman spectroscopy and STM has been set up, which enables the two techniques to in-situ study electrochemical interfaces simultaneously, An optical fiber head carrying one excitation fiber and five collection fibers can be adjusted to approach to an advanced originally designed STM unit so that the STM tip above the sample electrode are surrounded by the sir fibers. The strong thermal interface by the laser illumination was avoided with the short acquisition time for SERS measurements by using optical multichannel analyzer. In-situ SERS spectrum of SCN- adsorbed on Ag electrode surface has been simultaneously recorded during STM imaging. The STM imaging taken before, during and after the SERS measurements have drifted from each other within 5%, which shows that the combined system is of satisfied over all stability.

Key words: Raman spectroscopy, Scanning tunneling microscopy, Combined system, Solid/Liqud interface, Electrochemistry