物理化学学报 >> 1995, Vol. 11 >> Issue (11): 1004-1007.doi: 10.3866/PKU.WHXB19951109

研究论文 上一篇    下一篇

C2H3Cl分子团簇内部离子-分子反应产生C4H5Cl+的研究

盛六四,齐飞,高辉,罗志勇,张允武   

  1. 中国科学技术大学合肥国家同步辐射实验室，合肥 230026
  • 收稿日期:1995-01-04 修回日期:1995-04-25 发布日期:1995-11-15
  • 通讯作者: 张允武

Studies of C4H5Cl+ by Interamolecular Ion-Molecule Reactions within Cluster (C2H3Cl)2

Sheng Liu-Si,Qi Fei,Gao Hui,Luo Zhi-Yong,Zhang Yun-Wu   

  1. University of Science and Technology of China,National Synchrotron Radiation Laboratory,Hefei 230026
  • Received:1995-01-04 Revised:1995-04-25 Published:1995-11-15
  • Contact: Zhang Yun-Wu

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摘要：

用同步辐射对（C2H3Cl）分子团簇进行了光电离研究，发现该团簇内部发生了离子－分子化学反应，生成了十分稳定的反应产物C4H5Cl＋，不再是var der Waals弱键络合物．本文对反应机理进行了初步探讨

关键词: 离子-分子反应, 同步辐射, 光电离, 团簇, 氯乙烯

Abstract:

 Photoionization of (C2H3Cl)2 molecular clusters has been studied using synchrotron radiation. The "Intramolecular" ion-molecule reactions within ionized clusters has been observed. The reaction product C4H5Cl+ is very stable and it is not van der Waals weakly bond complex. The reaction mechanism has been discussed preliminarily.

Key words: Ion-molecules, Synchrotron radiation, Photoionization, Cluster, Vinylchloride