物理化学学报 >> 2010, Vol. 26 >> Issue (07): 1801-1810.doi: 10.3866/PKU.WHXB20100719

结构化学 上一篇    下一篇

多酸亚胺衍生物的可控组装

伍平凡, 张进, 魏永革   

  1. 湖北工业大学化学与环境工程学院, 武汉 430068
    清华大学化学系, 北京 100084
  • 收稿日期:2010-02-08 修回日期:2010-03-23 发布日期:2010-07-02
  • 通讯作者: 魏永革 E-mail:yonggewei@mail.tsinghua.edu.cn

Controlled Assembly of Organoimido Derivatized Polyoxometalates

WU Ping-Fan, ZHANG Jin, WEI Yong-Ge   

  1. School of Chemical and Environmental Engineering, Hubei University of Technology, Wuhan 430068, P. R. China
    Department of Chemistry, Tsinghua University, Beijing 100084, P. R. China
  • Received:2010-02-08 Revised:2010-03-23 Published:2010-07-02
  • Contact: WEI Yong-Ge E-mail:yonggewei@mail.tsinghua.edu.cn

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摘要：

介绍了课题组与合作单位根据分子工程学的思想, 采用自主发展的多酸亚胺化方法, 借用经典的有机合成反应来设计、合成多酸基(POM)有机-无机杂化纳米分子材料的最新进展.

关键词: 多酸, 多酸有机衍生物, 分子组装, 亚胺化, 碳-碳偶联

Abstract:

Recent advances in hybrid molecular materials based organoimido-substituted polyoxometalates (POMs) are reviewed. Related imidoylation and C-C coupling reactions developed in our group are highlighted.

Key words: Polyoxometalates, Organically-derivatized polyoxometalates, Molecular assembly, Imidoylation, Carbon-carbon coupling