纳米银粒子在氨基注入氧化铟锡玻璃基体表面的高密度吸附

doi:10.3866/PKU.WHXB20111135

物理化学学报 >> 2011, Vol. 27 >> Issue (11): 2671-2676.doi: 10.3866/PKU.WHXB20111135

纳米银粒子在氨基注入氧化铟锡玻璃基体表面的高密度吸附

李硕琦², 刘璐³, 田辉凤², 胡劲波^1,2

1. 北京师范大学射线束技术与材料改性教育部重点实验室, 北京 100875;
2. 北京师范大学化学学院, 北京 100875;
3. 北京大学化学与分子工程学院, 北京 100871

收稿日期:2011-08-01 修回日期:2011-09-06 发布日期:2011-10-27
通讯作者: 胡劲波 E-mail:hujingbo@bnu.edu.cn
基金资助:
国家自然科学基金(20211130505)和中央高校基本科研业务费专项资金资助

High Density Attachment of Silver Nanoparticles onto an NH₂⁺ Ion Implanted Indium Tin Oxide Glass Substrate

LI Shuo-Qi², LIU Lu³, TIAN Hui-Feng², HU Jing-Bo^1,2

1. Key Laboratory of Beam Technology and Material Modification of Ministry of Education, Beijing Normal University, Beijing 100875, P. R. China;
2. College of Chemistry, Beijing Normal University, Beijing 100875, P. R. China;
3. College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P. R. China

Received:2011-08-01 Revised:2011-09-06 Published:2011-10-27
Contact: HU Jing-Bo E-mail:hujingbo@bnu.edu.cn
Supported by:
The project was supported by the National Natural Science Foundation of China (20211130505) and Fundamental Research Funds for the Central Universities of China.

摘要/Abstract

摘要： 本文研究了纳米银(AgNPs)在氨基注入氧化铟锡(ITO)薄膜表面的吸附. 通过氨基注入的方法得到了氨基功能化的ITO表面(NH₂/ITO), 并将纳米银直接吸附在NH₂/ITO上得到纳米银修饰NH₂/ITO基体(AgNPs/NH₂/ITO). 使用傅里叶红外光谱、X射线光电子能谱、原子力显微镜、扫描电镜、紫外可见光谱和电化学方法对AgNPs/NH₂/ITO制备过程进行了表征. 结果显示纳米银可在NH₂/ITO表面高密度地吸附, 并且纳米银有良好的电化学活性. 这种不借助于有机连接分子吸附纳米银的方法为制备纳米银修饰材料提供了新的选择.

关键词: 离子注入, 组装, 纳米银, 氧化铟锡

Abstract: An effective approach to attach silver nanoparticles (AgNPs) directly onto an indium tin oxide (ITO) surface with high density was reported. An NH₂⁺ ion implanted ITO (NH₂/ITO) film was prepared and the AgNPs were adsorbed onto the surface of the obtained NH₂/ITO film resulting in an AgNPs-attached NH₂/ITO (AgNPs/NH₂/ITO) substrate. Characterization of stepwise changes in the ITO, NH₂/ITO, and AgNPs/NH₂/ITO surfaces were carried out using Fourier transform infrared (FT-IR) spectrometry, X-ray photoelectron spectroscopy (XPS), atomic force microscopy (AFM), scanning electron microscopy (SEM), ultravioletvisible (UV-Vis) spectroscopy, and electrochemical methods. Cyclic voltammtric voltammetry results indicate that the immobilized AgNPs on the NH₂/ITO electrode gave excellent electrochemical properties, implying facile electrochemical communication between the AgNPs and the ITO substrate through theby implanted amino groups. Thus, the AgNPs/NH₂/ITO surfaces are promising as new functional interfaces because AgNPs can be attached to surfaces without the use of organic binding molecules.

Key words: Ion implantation, Assembly, Silver nanoparticle, Indium tin oxide

李硕琦, 刘璐, 田辉凤, 胡劲波. 纳米银粒子在氨基注入氧化铟锡玻璃基体表面的高密度吸附[J]. 物理化学学报, 2011, 27(11), 2671-2676. doi: 10.3866/PKU.WHXB20111135

LI Shuo-Qi, LIU Lu, TIAN Hui-Feng, HU Jing-Bo. High Density Attachment of Silver Nanoparticles onto an NH₂⁺ Ion Implanted Indium Tin Oxide Glass Substrate[J]. Acta Phys. -Chim. Sin. 2011, 27(11), 2671-2676. doi: 10.3866/PKU.WHXB20111135

链接本文: https://www.whxb.pku.edu.cn/CN/10.3866/PKU.WHXB20111135

https://www.whxb.pku.edu.cn/CN/Y2011/V27/I11/2671

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纳米银粒子在氨基注入氧化铟锡玻璃基体表面的高密度吸附

High Density Attachment of Silver Nanoparticles onto an NH₂⁺ Ion Implanted Indium Tin Oxide Glass Substrate

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High Density Attachment of Silver Nanoparticles onto an NH2+ Ion Implanted Indium Tin Oxide Glass Substrate

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