核-壳结构氧还原反应电催化剂

doi:10.3866/PKU.WHXB201609202

物理化学学报 >> 2017, Vol. 33 >> Issue (1): 9-17.doi: 10.3866/PKU.WHXB201609202

核-壳结构氧还原反应电催化剂

常乔婉,肖菲,徐源,邵敏华*

香港科技大学化学工程与生物分子工程学系,香港

收稿日期:2016-08-02 发布日期:2016-12-29
通讯作者: 邵敏华
作者简介:CHANG Qiao-Wan, received a BS in Chemical Engineering from Tianjin University and BS (Double Degree) in Finance from Nankai University in 2014.She is now undertaking an MPhil degree at the Hong Kong University of Science and Technology under the supervision of Professor SHAO Min-Hua.Her main research interests are advanced materials for fuel cells|XIAO Fei, received a BS in Materials Science and Engineering from University of Science and Technology Beijing.She is now undertaking an MPhil degree at the Hong Kong University of Science and Technology under the supervision of Professor SHAO Min-Hua.Her main research interests are electrocatalysts for oxygen reduction reaction|XU Yuan, received a BS in Chemistry from South China Normal University in 2014, and a MSc in Chemical and Biomolecular Engineering from the Hong Kong University of Science and Technology in 2015.She is now a Research Assistant at the Hong Kong University of Science and Technology under the supervision of Professor SHAO Min-Hua.Her main research interests are advanced materials for fuel cells|SHAO Min-Hua, earned his BS (1999) and MS (2002) degrees in Chemistry from Xiamen University, and a PhD degree in Materials Science and Engineering from State University of New York at Stony Brook (2006).He joined UTC Power in 2007 to lead the development of advanced catalysts and supports for PEMFC and PAFC.In 2013, he joined Ford Motor Company to conduct research on lithium-ion batteries for electrified vehicles.He then joined the Hong Kong University of Science and Technology in the Department of Chemical and Biomolecular Engineering as an Associate Professor in 2014.His research mainly focuses on electrocatalysis and advanced batteries
基金资助:
香港特别行政区研究资助局(26206115)

Core-Shell Electrocatalysts for Oxygen Reduction Reaction

Qiao-Wan CHANG,Fei XIAO,Yuan XU,Min-Hua SHAO*

Department of Chemical and Biomolecular Engineering, The Hong Kong University of Science and Technology, Hong Kong, P. R. China

Received:2016-08-02 Published:2016-12-29
Contact: Min-Hua SHAO
Supported by:
The project was supported by the Research Grant Council of the Hong Kong Special Administrative Region, China(26206115)

摘要/Abstract

摘要：

金属铂是最高效的氧还原反应催化剂而被广泛应用于质子交换膜燃料电池，但其高成本阻碍了燃料电池的商业化进程。此专论主要总结了近年来核-壳结构纳米催化剂的设计、合成及在燃料电池中的应用，讨论了多种提高核-壳结构纳米催化剂的策略包括去合金化、形貌控制、表面改性等，以及在放大制备及燃料电池测试中遇到的问题。

关键词: 核-壳结构, 质子交换膜燃料电池, 电催化, 铂合金, 钯, 形貌控制

Abstract:

The high cost of platinum in catalyst layers hinders the commercialization of proton exchange membrane fuel cells. This Account reviews recent progress on core-shell nanostructures for oxygen reduction reaction (ORR) in acidic media, which is the cathodic reaction in fuel cells. The synthesis, characterization and evaluation of different types of core-shell electrocatalysts are summarized. Various strategies to improve the performance of core-shell electrocatalysts, including dealloying, morphology control, and surface modification are presented. The issues of mass production and fuel cell performance of core-shell electrocatalysts are also discussed.

Key words: Core-shell structure, Proton exchange membrane fuel cell, Electrocatalysis, Platinum alloy, Palladium, Shape control

常乔婉,肖菲,徐源,邵敏华. 核-壳结构氧还原反应电催化剂[J]. 物理化学学报, 2017, 33(1), 9-17. doi: 10.3866/PKU.WHXB201609202

Qiao-Wan CHANG,Fei XIAO,Yuan XU,Min-Hua SHAO. Core-Shell Electrocatalysts for Oxygen Reduction Reaction[J]. Acta Phys. -Chim. Sin. 2017, 33(1), 9-17. doi: 10.3866/PKU.WHXB201609202

链接本文: https://www.whxb.pku.edu.cn/CN/10.3866/PKU.WHXB201609202

https://www.whxb.pku.edu.cn/CN/Y2017/V33/I1/9

参考文献

1	Shao M. H. ; Chang Q.W. ; Dodelet J. P. ; Chenitz R. Chem. Rev 2016, 116 (6), 3594.
2	Nie Y. ; Li L. ; Wei Z. Chem. Soc. Rev 2015, 44 (8), 2168.
3	Shao, M. H. Electrocatalysis in Fuel Cells: a Non-and Lowplatinum Approach; Springer Science & Business Media: Heidelberg, 2013; pp 1-745.
4	Wanjala B. N. ; Fang B. ; Shan S. ; Petkov V. ; Zhu P. ; Loukrakpam R. ; Chen Y. ; Luo J. ; Yin J. ; Yang L. Chem. Mater 2012, 24 (22), 4283.
5	Choi S. I. ; Xie S. ; Shao M. H. ; Odell J. H. ; Lu N. ; Peng H.C. ; Protsailo L. ; Guerrero S. ; Park J. ; Xia X. Nano Lett 2013, 13 (7), 3420.
6	Strasser P. ; Koh S. ; Anniyev T. ; Greeley J. ; More K. ; Yu C. ; Liu Z. ; Kaya S. ; Nordlund D. ; Ogasawara H. Nat. Mater 2010, 2 (6), 454.
7	Cui C. ; Gan L. ; Li H. H. ; Yu S. H. ; Heggen M. ; Strasser P. Nano Lett 2012, 12 (11), 5885.
8	Stamenkovic V. R. ; Fowler B. ; Mun B. S. ; Wang G. ; Ross P.N. ; Lucas C. A. ; Markovi? N. M. Science 2007, 315 (5811), 493.
9	Stamenkovic V. R. ; Mun B. S. ; Arenz M. ; Mayrhofer K. J. ; Lucas C. A. ; Wang G. ; Ross P. N. ; Markovic N. M. Nat. Mater 2007, 6 (3), 241.
10	Shao M. H. J. Power Sources 2011, 196 (5), 2433.
11	Shao M. H. ; Odell J. ; Humbert M. ; Yu T. ; Xia Y. J. Phys. Chem. 2013, 117 (8), 4172.
12	Shao M. H. ; Huang T. ; Liu P. ; Zhang J. ; Sasaki K. ; Vukmirovic M. ; Adzic R. Langmuir 2006, 22 (25), 10409.
13	Shao M. H. ; Sasaki K. ; Adzic R. R. J. Am. Chem. Soc 2006, 128 (11), 3526.
14	Choi S. I. ; Shao M. H. ; Lu N. ; Ruditskiy A. ; Peng H. C. ; Park J. ; Guerrero S. ; Wang J. ; Kim M. J. ; Xia Y. ACS Nano 2014, 8 (10), 10363.
15	Zhang L. L. ; Zhu S.Q. ; Chang Q.W. ; Su D. ; Yue J. ; Du Z. ; Shao M. H. ACS Catal 2016, 6 (6), 3428.
16	Adzic R. R. Electrocatalysis 2012, 3 (3-4), 163.
17	Adzic R. R. ; Zhang J. ; Sasaki K. ; Vukmirovic M. B. ; Shao M. H. ; Wang J. ; Nilekar A. U. ; Mavrikakis M. ; Valerio J. ; Uribe F. Top. Catal 2007, 46 (3-4), 249.
18	Zhang G. ; Shao Z. G. ; Lu W. ; Xie F. ; Xiao H. ; Qin X. ; Yi B. Appl. Catal. B 2013, 132, 183.
19	Akinpelu A. ; Merzougui B. ; Bukola S. ; Azad A. M. ; Basheer R. A. ; Swain G. M. ; Chang Q.W. ; Shao M. H. Electrochim. Acta 2015, 161, 305.
20	Jaouen F. ; Proietti E. ; Lefèvre M. ; Chenitz R. ; Dodelet J. P. ; Wu G. ; Chung H. T. ; Johnston C. M. ; Zelenay P. Energy Environ. Sci 2011, 4 (1), 114.
21	Wu G. ; More K. L. ; Johnston C. M. ; Zelenay P. Science 2011, 332 (6028), 443.
22	Lefèvre M. ; Proietti E. ; Jaouen F. ; Dodelet J. P. Science 2009, 324 (5923), 71.
23	Proietti E. ; Jaouen F. ; Lefèvre M. ; Larouche N. ; Tian J. ; Herranz J. ; Dodelet J. P. Nat. Commun 2011, 2, 416.
24	Zhang J. ; Vukmirovic M. B. ; Xu Y. ; Mavrikakis M. ; Adzic R. R. Angew. Chem. Int. Ed 2005, 44 (14), 2132.
25	Rodriguez J. Surf. Sci. Rep 1996, 24 (7), 223.
26	Brankovic S. ; Wang J. ; Adzic R. Surf. Sci 2001, 474 (1), L173.
27	Hammer B. ; N?rskov J. K. Adv. Catal 2000, 45, 71.
28	Shao M. H. ; Odell J. H. ; Peles A. ; Su D. Chem. Commun 2014, 50 (17), 2173.
29	Calle-Vallejo F. ; Koper M. T. ; Bandarenka A. S. Chem. Soc. Rev 2013, 42 (12), 5210.
30	Oezaslan M. ; Hasché F. D. R. ; Strasser P. J. Phys. Chem. Lett 2013, 4 (19), 3273.
31	Zhang J. ; Sasaki K. ; Sutter E. ; Adzic R. Science 2007, 315 (5809), 220.
32	Zhou W. P. ; Sasaki K. ; Su D. ; Zhu Y. ; Wang J. X. ; Adzic R.R. J. Phys. Chem. C 2010, 114 (19), 8950.
33	Xu Y. ; Ruban A. V. ; Mavrikakis M. J. Am. Chem. Soc 2004, 126 (14), 4717.
34	Zhang J. ; Mo Y. ; Vukmirovic M. ; Klie R. ; Sasaki K. ; Adzic R. J. Phys. Chem. B 2004, 108 (30), 10955.
35	Zhang L. ; Iyyamperumal R. ; Yancey D. F. ; Crooks R. M. ; Henkelman G. ACS Nano 2013, 7 (10), 9168.
36	Karan H. I. ; Sasaki K. ; Kuttiyiel K. ; Farberow C. A. ; Mavrikakis M. ; Adzic R. R. ACS Catal 2012, 2 (5), 817.
37	Brankovic S. ; McBreen J. ; Adzic R. J. Electroanal. Chem 2001, 503 (1), 99.
38	Shao M. H. ; Peles A. ; Shoemaker K. ; Gummalla M. ; Njoki P.N. ; Luo J. ; Zhong C. J. J. Phys. Chem. Lett 2010, 2 (2), 67.
39	Iijima Y. ; Kondo T. ; Takahashi Y. ; Bando Y. ; Todoroki N. ; Wadayama T. J. Electrochem. Soc 2013, 160 (8), F898.
40	Cai Y. ; Adzic R. R. Adv. Phys. Chem 2011, 530397
41	Shao M. H. ; Smith B. H. ; Guerrero S. ; Protsailo L. ; Su D. ; Kaneko K. ; Odell J. H. ; Humbert M. P. ; Sasaki K. ; Marzullo J. Phys. Chem. Chem. Phys 2013, 15 (36), 15078.
42	Gong K. ; Choi Y. ; Vukmirovic M. B. ; Liu P. ; Ma C. ; Su D. ; Adzic R. R. Z. Phys. Chem 2012, 226 (9-10), 1025.
43	Xiao L. ; Zhuang L. ; Liu Y. ; Lu J. J. Am. Chem. Soc 2008, 131 (2), 602.
44	Shao M. H. ; He G. ; Peles A. ; Odell J. H. ; Zeng J. ; Su D. ; Tao J. ; Yu T. ; Zhu Y. ; Xia Y. Chem. Commun 2013, 49 (79), 9030.
45	Xing Y. ; Cai Y. ; Vukmirovic M. B. ; Zhou W. P. ; Karan H. ; Wang J. X. ; Adzic R. R. J. Phys. Chem. Lett 2010, 1 (21), 3238.
46	Yang L. ; Vukmirovic M. B. ; Su D. ; Sasaki K. ; Herron J. A. ; Mavrikakis M. ; Liao S. ; Adzic R. R. J. Phys. Chem. C 2013, 117 (4), 1748.
47	Shao M. H. ; Peles A. ; Odell J. J. Phys. Chem. C 2014, 118 (32), 18505.
48	Shao M. H. ; Shoemaker K. ; Peles A. ; Protsail L. J. Am. Chem. Soc 2010, 132, 9253.
49	Peles A. ; Shao M. H. ; Protsailo L. Catalysts 2015, 5 (3), 1193.
50	Humbert M. P. ; Smith B. H. ; Wang Q. ; Ehrlich S. N. ; Shao M. H. Electrocatalysis 2013, 3 (3-4), 298.
51	Thambidurai C. ; Gebregziabiher D. K. ; Liang X. ; Zhang Q. ; Ivanova V. ; Haumesser P. H. ; Stickney J. L. J. Electrochem. Soc 2010, 157 (8), D466.
52	Khateeb S. ; Guerreo S. ; Su D. ; Darling R. M. ; Protsailo L.V. ; Shao M. H. J. Electrochem. Soc 2016, 163 (7), F708.
53	Zhu S. Q. ; J. Y. ; Qin X. P. ; Wei Z. ; Liang Z. D. ; Adzic R. R. ; Brankovic S. ; Du Z. ; Shao M. H. J. Electrochem. Soc 2016, 163 (12), D3040.
54	Long N. V. ; Ohtaki M. ; Hien T. D. ; Randy J. ; Nogami M. Electrochim. Acta 2011, 56 (25), 9133.
55	Chen Y. ; Liang Z. ; Yang F. ; Liu Y. ; Chen S. J. Phys. Chem. C 2011, 115 (49), 24073.
56	Du B. ; Zaluzhna O. ; Tong Y. J. Phys. Chem. Chem. Phys 2011, 13 (24), 11568.
57	Atienza D. O. ; Allison T. C. ; Tong Y. J. J. Phys. Chem. C 2012, 116 (50), 26480.
58	Jung N. ; Chung Y. H. ; Chung D. Y. ; Choi K. H. ; Park H. Y. ; Ryu J. ; Lee S. Y. ; Kim M. ; Sung Y. E. ; Yoo S. J. Phys. Chem. Chem. Phys 2013, 15 (40), 17079.
59	Chen Y. ; Shi J. J. Fuel Cell Sci. Technol 2015, 12 (2), 021005.
60	Xie S. ; Choi S. I. ; Lu N. ; Roling L. T. ; Herron J. A. ; Zhang L. ; Park J. ; Wang J. ; Kim M. J. ; Xie Z. Nano Lett 2014, 14 (6), 3570.
61	Park J. ; Zhang L. ; Choi S. I. ; Roling L. T. ; Lu N. ; Herron J.A. ; Xie S. ; Wang J. ; Kim M. J. ; Mavrikakis M. ACS Nano 2015, 9 (3), 2635.
62	Peng Z. ; Yang H. J. Am. Chem. Soc 2009, 131 (22), 7542.
63	Alia S. M. ; Jensen K. O. ; Pivovar B. S. ; Yan Y. ACS Catal 2012, 2 (5), 858.
64	Liu X. ; Eileen H. Y. ; Scott K. Appl. Catal. B 2015, 162, 593.
65	Zhang L. ; Roling L. T. ; Wang X. ; Vara M. ; Chi M. ; Liu J. ; Choi S. I. ; Park J. ; Herron J. A. ; Xie Z. Science 2015, 349 (6246), 412.
66	Choi R. ; Choi S. I. ; Choi C. H. ; Nam K. M. ; Woo S. I. ; Park J. T. ; Han S.W. Chem. Eur. J. 2013, 19 (25), 8190.
67	Zhang Y. ; Hsieh Y. C. ; Volkov V. ; Su D. ; An W. ; Si R. ; Zhu Y. ; Liu P. ; Wang J. X. ; Adzic R. R. ACS Catal 2014, 4 (3), 738.
68	Zhang G. ; Shao Z. G. ; Lu W. ; Xiao H. ; Xie F. ; Qin X. ; Li J. ; Liu F. ; Yi B. J. Phys. Chem. C 2013, 117 (26), 13413.
69	Liu L. ; Samjeske G. ; Nagamatsu S. I. ; Sekizawa O. ; Nagasawa K. ; Takao S. ; Imaizumi Y. ; Yamamoto T. ; Uruga T. ; Iwasawa Y. J. Phys. Chem. C 2012, 116 (44), 23453.
70	Anderson R. M. ; Zhang L. ; Loussaert J. A. ; Frenkel A. I. ; Henkelman G. ; Crooks R. M. ACS Nano 2013, 7 (10), 9345.
71	Wang Y. J. ; Zhao N. ; Fang B. ; Li H. ; Bi X. T. ; Wang H. Chem. Rev 2015, 115 (9), 3433.
72	Hwang S. J. ; Kim S. K. ; Lee J. G. ; Lee S. C. ; Jang J. H. ; Kim P. ; Lim T. H. ; Sung Y. E. ; Yoo S. J. J. Am. Chem. Soc 2012, 134 (48), 19508.
73	Guo S. ; Zhang S. ; Su D. ; Sun S. J. Am. Chem. Soc 2013, 135 (37), 13879.
74	Wang C. ; Van der Vliet D. ; More K. L. ; Zaluzec N. J. ; Peng S. ; Sun S. ; Daimon H. ; Wang G. ; Greeley J. ; Pearson J. Nano Lett 2010, 11 (3), 919.
75	Wu J. ; Gross A. ; Yang H. Nano Lett 2011, 11 (2), 798.
76	Carpenter M. K. ; Moylan T. E. ; Kukreja R. S. ; Atwan M. H. ; Tessema M. M. J. Am. Chem. Soc 2012, 134 (20), 8535.
77	Cui C. ; Ahmadi M. ; Behafarid F. ; Gan L. ; Neumann M. ; Heggen M. ; Cuenya B. R. ; Strasser P. Farad. Discuss 2013, 162, 91.
78	Zhang C. ; Hwang S. Y. ; Trout A. ; Peng Z. J. Am. Chem. Soc 2014, 136 (22), 7805.
79	Huang X. ; Zhao Z. ; Cao L. ; Chen Y. ; Zhu E. ; Lin Z. ; Li M. ; Yan A. ; Zettl A. ; Wang Y. M. Science 2015, 348 (6240), 1230.
80	Wu Y. ; Cai S. ; Wang D. ; He W. ; Li Y. J. Am. Chem. Soc 2012, 134 (21), 8975.
81	Sasaki K. ; Naohara H. ; Cai Y. ; Choi Y. M. ; Liu P. ; Vukmirovic M. B. ; Wang J. X. ; Adzic R. R. Angew. Chem. Int. Ed 2010, 49 (46), 8602.
82	Kongkanand A. ; Subramanian N. P. ; Yu Y. ; Liu Z. ; Igarashi H. ; Muller D. A. ACS Catal 2016, 6 (3), 1578.

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核-壳结构氧还原反应电催化剂

Core-Shell Electrocatalysts for Oxygen Reduction Reaction

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